全文获取类型
收费全文 | 626篇 |
免费 | 25篇 |
国内免费 | 7篇 |
专业分类
化学 | 496篇 |
晶体学 | 3篇 |
力学 | 23篇 |
数学 | 75篇 |
物理学 | 61篇 |
出版年
2023年 | 3篇 |
2022年 | 16篇 |
2021年 | 13篇 |
2020年 | 16篇 |
2019年 | 17篇 |
2018年 | 6篇 |
2017年 | 12篇 |
2016年 | 25篇 |
2015年 | 19篇 |
2014年 | 16篇 |
2013年 | 35篇 |
2012年 | 28篇 |
2011年 | 54篇 |
2010年 | 29篇 |
2009年 | 35篇 |
2008年 | 47篇 |
2007年 | 39篇 |
2006年 | 35篇 |
2005年 | 18篇 |
2004年 | 26篇 |
2003年 | 23篇 |
2002年 | 12篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 12篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1975年 | 4篇 |
1971年 | 2篇 |
1969年 | 2篇 |
1967年 | 3篇 |
1943年 | 2篇 |
排序方式: 共有658条查询结果,搜索用时 15 毫秒
51.
Marion Collinet-Fressancourt Nathalie Azaroual Jean-Marie Aubry Véronique Nardello-Rataj 《Tetrahedron letters》2010,51(50):6531-6534
The kinetic booster effect of dimethylsulfoxide on the chemical generation of singlet oxygen, 1O2, from the disproportionation of hydrogen peroxide catalyzed by molybdate ions in methanol has been evidenced by detection of the IR luminescence of 1O2 at 1270 nm and by 95Mo NMR spectroscopy. DMSO interacts rapidly, through a direct oxygen transfer with the stable tetraperoxomolybdate , leading to DMSO2 and to the unstable triperoxomolybdate , which releases 1O2. The procedure was applied to accelerate the dark singlet oxygenation of β-citronellol and α-terpinene. 相似文献
52.
53.
Frédérick Adam Didier Thiébaut Fabrice Bertoncini Marion Courtiade Marie-Claire Hennion 《Journal of chromatography. A》2010,1217(8):1386-1394
This paper reports the conditions of online hyphenation of supercritical fluid chromatography (SFC) with twin comprehensive two-dimensional gas chromatography (twin-GC × GC) for detailed characterization of middle distillates; this is essential for a better understanding of reactions involved in refining processes. In this configuration, saturated and unsaturated compounds that have been fractionated by SFC are transferred on two different GC × GC columns sets (twin-GC × GC) placed in the same GC oven. Cryogenic focusing is used for transfer of fractions into the first dimension columns before simultaneous GC × GC analysis of both saturated and unsaturated fractions. The benefits of SFC–twin-GC × GC are demonstrated for the extended alkane, iso-alkane, alkene, naphthenes and aromatics analysis (so-called PIONA analysis) of diesel samples which can be achieved in one single injection. For that purpose, saturated and unsaturated compounds have been separated by SFC using a silver loaded silica column prior to GC × GC analysis. Alkenes and naphthenes are quantitatively recovered in the unsaturated and saturated fractions, respectively, allowing their identification in various diesel samples. Thus, resolution between each class of compounds is significantly improved compared to a single GC × GC run, and for the first time, an extended PIONA analysis of diesel samples is presented. 相似文献
54.
Andrea Retzbach Joachim Marschall Marion Rahnke Lukas Otto Michaela Maier 《Journal of nanoparticle research》2011,13(12):6231-6244
In this article, we report data from an online questionnaire study with 587 respondents, representative for the adult U.S.
population in terms of age, gender, and level of education. The aim of this study was to assess how interest in science and
knowledge as well as beliefs about science are associated with risk and benefit perceptions of nanotechnology. The findings
suggest that the U.S. public is still rather unfamiliar with nanotechnology. Those who have some knowledge mainly have gotten
it from TV and the Internet. The content of current media reports is perceived as fairly positive. Knowledge of scientific
methods is unrelated to benefit and risk perceptions, at least when other predictors are controlled. In contrast, positive
beliefs about science (e.g., its impact on economy or health) and more sophisticated epistemological beliefs about the nature
of scientific knowledge are moderately linked to more positive perceptions of nanotechnology. The only exception is the perception
of scientific uncertainty: This is associated with less positive evaluations. Finally, higher engagement with science is associated
with higher risk perceptions. These findings show that laypersons who are engaged with science and who are aware of the inherent
uncertainty of scientific evidence might perceive nanotechnology in a somewhat more differentiated way, contrary to how it
is portrayed in the media today. 相似文献
55.
56.
Characterization and functionalization of cellulose microbeads for extracorporeal blood purification
Marion Ettenauer Fritz Loth Katrin Thümmler Steffen Fischer Viktoria Weber Dieter Falkenhagen 《Cellulose (London, England)》2011,18(5):1257-1263
In the frame of this work, cellulose microbeads with an average particle size of 2.3 μm were characterized with respect to
porosity using a batch solute exclusion method and two groups of model substances, namely proteins and polystyrene sulfonates.
The pores of the microbeads were almost completely accessible to proteins with Stokes radii below 2.5 nm. More than 60% of
the pores were accessible to albumin, which is relevant for the application in blood purification, since many target substances
are albumin bound. Activation of the microbeads with increasing amounts of sodium metaperiodate yielded matrices with dialdehyde
contents between 100 and 1,000 μmol/g. The activated beads were well suited for the covalent attachment of functional ligands,
such as antibodies. Immobilization of antibodies against the pro-inflammatory cytokine TNF-α resulted in efficient TNF-α adsorbents
which possess application potential in extracorporeal blood purification, e.g. for the modulation of cytokine levels as supportive
therapy for sepsis and other inflammatory disorders. 相似文献
57.
Marion Scheepers 《Order》1990,7(1):41-64
We introduce a partition relation which is an alternate for measuring how badly the ordinary partition relation fails, we develop its corresponding partition calculus and we determine its status for various typical partially ordered sets. 相似文献
58.
59.
60.