Cross-linked natural IntegroPectin films from citrus biowaste with intrinsic antimicrobial activity

Cellulose - Pectin recovered via hydrodynamic cavitation (IntegroPectin) from lemon and grapefruit agri-food waste intrinsically containing antimicrobial bioactive substances (flavonoids, phenolic...     

The Use of the Levenberg–Marquardt and Variable Projection Curve-Fitting Algorithm in Intravoxel Incoherent Motion Method for DW-MRI Data Analysis

The objective of this study was to evaluate the performances of different algorithms for diffusion parameters estimation in intravoxel incoherent motion method for diffusion-weighted magnetic resonance imaging (DW-MRI) data analysis. Traditionally, the method of non-linear least squares analysis by means of Levenberg–Marquardt algorithms has been used to estimate the parameters obtained from exponential decay data. In this study, we evaluated the Variable Projection curve-fitting algorithm and the performance of two non-linear regression methods when single and multiple starting points were used. Analysis was done on simulation data to which different amounts of Gaussian noise had been added. The performance of two non-linear regression methods was compared using the residual sum of squares and the number of failures in data fitting. We conclude that the VarPro algorithm is superior to the LM algorithm for curve fitting in intravoxel incoherent motion method for DW-MRI data analysis.     

Narrowband solid state vuv coherent source for laser cooling of antihydrogen

We describe the design and performance of a solid-state pulsed source of narrowband (< 100 MHz) Lyman-α radiation designed for the purpose of laser cooling magnetically trapped antihydrogen. Our source utilizes an injection seeded Ti:Sapphire amplifier cavity to generate intense radiation at 729.4 nm, which is then sent through a frequency doubling stage and a frequency tripling stage to generate 121.56 nm light. Although the pulse energy at 121.56 nm is currently limited to 12 nJ with a repetition rate of 10 Hz, we expect to obtain greater than 0.1 μJ per pulse at 10 Hz by further optimizing the alignment of the pulse amplifier and the efficiency of the frequency tripling stage. Such a power will be sufficient for cooling a trapped antihydrogen atom from 500 mK to 20mK.     

Counterion influence on the N–I–N halogen bond

A detailed investigation of the influence of counterions on the [N–I–N]⁺ halogen bond in solution, in the solid state and in silico is presented. Translational diffusion coefficients indicate close attachment of counterions to the cationic, three-center halogen bond in dichloromethane solution. Isotopic perturbation of equilibrium NMR studies performed on isotopologue mixtures of regioselectively deuterated and nondeuterated analogues of the model system showed that the counterion is incapable of altering the symmetry of the [N–I–N]⁺ halogen bond. This symmetry remains even in the presence of an unfavorable geometric restraint. A high preference for the symmetric geometry was found also in the solid state by single crystal X-ray crystallography. Molecular systems encompassing weakly coordinating counterions behave similarly to the corresponding silver(i) centered coordination complexes. In contrast, systems possessing moderately or strongly coordinating anions show a distinctly different behavior. Such silver(i) complexes are converted into multi-coordinate geometries with strong Ag–O bonds, whereas the iodine centered systems remain linear and lack direct charge transfer interaction with the counterion, as verified by ¹⁵N NMR and DFT computation. This suggests that the [N–I–N]⁺ halogen bond may not be satisfactorily described in terms of a pure coordination bond typical of transition metal complexes, but as a secondary bond with a substantial charge-transfer character.     

Facile Formation of Redox‐Active Totally Organic Nanoparticles in Water by In Situ Reduction of Organic Precursors Stabilized through Aromatic–Aromatic Interactions by Aromatic Polyelectrolytes

The formation of redox‐active, totally organic nanoparticles in water is achieved following a strategy similar to that used to form metal nanoparticles. It is based on two fundamental concepts: i) complexation through aromatic–aromatic interactions of a water‐soluble precursor aromatic molecule with polyelectrolytes bearing complementary charged aromatic rings, and ii) reduction of the precursor molecule to achieve stabilized nanoparticles. Thus, formazan nanoparticles are synthesized by reduction of a tetrazolium salt with ascorbic acid using polyelectrolytes bearing benzene sulfonate residues of high linear aromatic density, but cannot be formed in the presence of nonaromatic polyelectrolytes. The red colored nanoparticles are efficiently encapsulated in calcium alginate beads, showing macroscopic homogeneity. Bleaching kinetics with chlorine show linear rates on the order of tenths of milli­meters per minute. A linear behavior of the dependence of the rate of bleaching on the chlorine concentration is found, showing the potential of the nanoparticles for chlorine sensing.

     

Stability,buckling, and postbuckling of elastic structures

Summary This paper is the continuation of a research on the stability and postbuckling behaviour of elastic structures; in the first Part [n. 4, Vol. X, 1975 of this Journal], the potential energy of elastic tridimensional bodies has been defined in a suitable configuration space, and its properties of regularity have been studied. According to the program given in the previous Paper, we examine now the potential energy functional for some monodimensional and bidimensional structural models. Then the Part II of this research is developed so that the Liapunov stability of the equilibrium configuration of continuous elastic structures is analyzed by means of suitable energy criteria.

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Sommario Questo lavoro costituisce il proseguimento di uno studio sulle stabilità e comportamento postcritico delle strutture elastiche; nel precedente lavoro, pubblicato sul n. 4, vol. X, 1975 di questa rivista, è stato esaminato il problema della definizione dell'energia potenziale di un corpo elastico tridimensionale in un opportuno spazio funzionale delle configurazioni, e sono state esaminate le proprietà di regolarità di questo funzionale. Proseguendo il programma formulato nel lavoro precedente, viene ora innanzitutto completato lo studio del funzionale energia potenziale con riferimento a modelli strutturali mono e bidimensionali. Viene poi sviluppata la Parte II e cioè l'analisi della stabilità secondo Liapunov di una configurazione di equilibrio attraverso opportune formulazioni dei criteri dell'energia.

     

Post processing of solution and flux for the nodal mimetic finite difference method

We develop and analyze a post processing technique for the family of low‐order mimetic discretizations based on vertex unknowns for the numerical treatment of diffusion problems on unstructured polygonal and polyhedral meshes. The post processing works in two steps. First, from the nodal degrees of freedom, we reconstruct an elemental‐based vector field that approximates the gradient of the exact solution. Second, we solve a local problem for each mesh vertex associated with a scheme degree of freedom to determine a post processed normal flux that is conservative and divergence preserving. Theoretical results and numerical experiments for two‐dimensional (2D) and 3D benchmark problems show optimal convergence rates. © 2014 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 336–363, 2015     

Indifference pricing for CRRA utilities

We study utility indifference pricing of claim streams with intertemporal consumption and constant relative risk aversion utilities. We derive explicit formulas for the derivatives of the utility indifference price with respect to claims and wealth. The elegant structure of these formulas is a reflection of surprising algebraic identities for the derivatives of the optimal consumption stream. Namely, the partial derivative of the optimal consumption stream with respect to the endowment is always a projection. Furthermore, it is an orthogonal projection with respect to a natural “economic inner product”. These algebraic identities generate cancellations between the terms entering derivatives of the indifference price and allow us to prove sharp global bounds for the indifference price that become exact when the claims to wealth ratio is large and risk aversion is between one and two. For general risk aversion, we show that, in the large claims to wealth ratio limit, the asymptotic expansion of the indifference price is given in terms of fractional powers of the wealth, depending on risk aversion. When risk aversion is equal to one, the fractional power depends on the underlying claim.