Modal-Hamiltonian Interpretation of Quantum Mechanics and Casimir Operators: The Road Toward Quantum Field Theory

The general aim of this paper is to extend the Modal-Hamiltonian interpretation of quantum mechanics to the case of relativistic quantum mechanics with gauge U(1) fields. In this case we propose that the actual-valued observables are the Casimir operators of the Poincaré group and of the group U(1) of the internal symmetry of the theory. Moreover, we also show that the magnitudes that acquire actual values in the relativistic and in the non-relativistic cases are correctly related through the adequate limit.     

Dysregulation of chemo-cytokine production in schizophrenic patients versus healthy controls

Background  

The exact cause of schizophrenia is not known, although several aetiological theories have been proposed for the disease, including developmental or neurodegenerative processes, neurotransmitter abnormalities, viral infection and immune dysfunction or autoimmune mechanisms. Growing evidence suggests that specific cytokines and chemokines play a role in signalling the brain to produce neurochemical, neuroendocrine, neuroimmune and behavioural changes. A relationship between inflammation and schizophrenia was supported by abnormal cytokines production, abnormal concentrations of cytokines and cytokine receptors in the blood and cerebrospinal fluid in schizophrenia. Since the neuropathology of schizophrenia has recently been reported to be closely associated with microglial activation we aimed to determined whether spontaneous or LPS-induced peripheral blood mononuclear cell chemokines and cytokines production is dysregulated in schizophrenic patients compared to healthy subjects. We enrolled 51 untreated first-episode schizophrenics (SC) and 40 healthy subjects (HC) and the levels of MCP-1, MIP-1α, IL-8, IL-18, IFN-γ and RANTES were determined by Elisa method in cell-free supernatants of PBMC cultures.     

Study on Planar Whispering Gallery Dielectric Resonators. I. General Properties

Several basic properties of homogeneous planar Whispering Gallery dielectric resonators are investigated through a general approach. In particular the values for the minimum and maximum allowed radius, defined by irradiation and dielectric losses, respectively, are obtained in terms of the complex dielectric constant of the involved media. The same approach is employed in the analysis of the limit allowed frequencies of a fixed family of mode, leading to the definition of the ideal frequency band. The role of the transverse mode is then discussed, and the effective frequency band is introduced and determined both in simple disc and circular ring resonators. The extension of the effective band is limited at least by a factor 3, in terms of decades, in comparison to the extension of the ideal one; this limitation, due to the presence of transverse modes, can be overcome using suitable designed nonhomogeneous resonators, as discussed in a following companion paper.     

Determination of Pb,Zr, Ti,Sr, Cr,Nb and La in lead zirconate titanate ceramics by particle‐induced X‐ray emission

A particle‐induced X‐ray emission (PIXE) technique has been used in the determination of the principal components Pb, Zr and Ti and the substituting elements Sr, Cr, Nb and La in lead zirconate titanate ceramics. In general, precision of analysis was concentration dependent from each element under study. For Pb, precision varied between 0.13% and 0.16%, at higher concentration of 59.32–64.5%. It was around 6–9% for Sr, Cr and Nb at concentrations of 1% or lower. Particular attention was devoted to the estimation of the analysis trueness. With this purpose, three methods were applied: (1) comparison of PIXE and inductively coupled plasma optical emission spectrometry concentrations, (2) recovery study and (3) comparison with a laboratory standard. Trueness of analysis was around 100 ± 10% for the evaluated elements Pb, Zr, Ti, Sr and Cr. The expected stoichiometry and elemental composition homogeneity of a wide group of produced ceramics were confirmed by the PIXE technique. Copyright © 2012 John Wiley & Sons, Ltd.     

Gold chloride cluster ions generated by vacuum laser ablation

In this work, a simple way for study the possibility of formation a vapor cluster species of tetrachloroauric acid (HAuCl₄), using the laser ablation in the absence of a buffer or reactive atmosphere, and without a postablation supersonic expansion on a commercial matrix assisted laser desorption/ionization time-of-flight mass spectrometer, is reported. Tetrachloroauric acid is known as precursor for the synthesis of gold nanostructures and the complex salts; therefore it is an important task to discover and quantify the species arising from HAuCl₄, in order to understand their role in the gold assisted reactions. Mass spectrum of HAuCl₄ in a reflector negative-ion mode contains the hydrated mono- and dinuclear gold clusters in the m/z range 286–436, and gold chloride clusters in the m/z range 447–795. In the first part of spectrum, m/z range 286–436, the hydrated gold cluster species of type Au _n ^? (H₂O)_m (n?=?1–2; m?=?1, 2, 5, 7, 8) and [Au_n(OH)_k]^?(H₂O)_m (n?=?1–2; k?=?1–2; m?=?1, 4–8) were found. Besides that, there are gold chloride clusters with general formula [AuH_r(HCl)₂]^?(H₂O)_m (m?=?1–5; 8–9; r?=?0–2) in this part of spectrum. In the second part of spectrum, the m/z range 447–795, only gold chloride clusters were obtained. Their general formulae can be written as [AuCl_t(HCl)_v]^?(H₂O)_m (t?=?1–4; v?=?5–8; m?=?2–4, 6–8) and [Au_n(HCl)_v]^?(H₂O)_m (n?=?1–2, v?=?4–5, m?=?1–2, 5, 7). The analysis of concentration effects on the LDI mass spectra of gold clusters reveals that the relative intensities of signals for the mono- and dinuclear Au clusters increase with decreasing the concentration of water HAuCl₄ solutions.     

The speaker''s formant in male voices

Spectral analysis of vowels during connected speech can be performed using the spectral intensity distribution within critical bands corresponding to a natural scale on the basilar membrane. Normalization of the spectra provides the opportunity to make objective comparisons independent from the recording level. An increasing envelope peak between 3,150 and 3,700 Hz has been confirmed statistically for a combination of seven vowels in three groups of male speakers with hoarse, normal, and professional voices. Each vowel is also analyzed individually. The local energy maximum is called “the speaker's formant” and can be found in the region of the fourth formant. The steepness of the spectral slope (i.e. the rate of decline) becomes less pronounced when the sonority or the intensity of the voice increases. The speaker's formant is connected with the sonorous quality of the voice. It increases gradually and is approximately 10 dB higher in professional male voices than in normal male voices at neutral loudness (60 dB at 0.3 min). The peak intensity becomes stronger (30 dB above normal voices) when the overall speaking loudness is increased to 80 dB. Shouting increases the spectral energy of the adjacent critical bands but not the speaker's formant itself.     

Synthesis and structural characterization of mixed aluminum-gallium-offretites

A new synthesis procedure is reported for the preparation of mixed Al,Ga-offretites over the entire solid solution range 0 ≤ Ga/(Ga + Al) ≤ 1. The resulting materials are characterized by X-ray powder diffraction, adsorption microcalorimetry and multinuclear solid state NMR. The ²⁹Si MAS-NMR data are consistent with statistical occupancy of the T₁ and T₂ sites by aluminum and gallium, and also show no positive evidence for preferential siting effects between both framework metals. Isotropic chemical shifts and nuclear electric quadrupolar coupling constants for ²⁷Al and ⁷¹Ga have been obtained from a field-dependent analysis of the center of gravity in the MAS-NMR spectra. H-Al, Ga-offretites produced by ammonium exchange and subsequent calcination reveal evidence of partial demetallation of the framework with formation of extra-lattice metal species.     

A landscape of time asymmetry

This is a conceptual overview on a polemical subject: the problem of time asymmetry. It is proved that time asymmetry can be considered as a global generalized symmetry breaking, produced by a choice of a physically admissible state space, in a global Gel'fand triplet. The well-known physics of irreversible process can be studied using this mathematical structure and all the arrows of time can be explained and coordinated. But the deeper problems of time definition and time arrow in quantum gravity remain outside of this landscape.