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981.
Statistical evaluation of an analytical GC/MS method for the determination of long chain fatty acids
In-depth evaluation of an analytical method to detect and quantify long chain fatty acids (C8-C16) at trace level concentrations (25-1000 μg/l) is presented. The method requires derivatization of the acids with methanolic boron trifluoride, separation, and detection by gas chromatography-mass spectrometry. The calibration experiments passed all the tested performance criteria such as linearity, homoscedasticity, and ruggedness. The detection limits and related quantities were computed by applying the method detection limit, and the calibration line approximation. The values obtained by applying the latter approach were more reliable and consistent with the actual statistical theory of detection decisions and yielded the following concentrations: C8, 87.6 μg/l; C10, 45.2 μg/l; C11, 39.9 μg/l; C12, 37.7 μg/l; C14, 41.4 μg/l and C16, 40.6 μg/l. Two different gas-liquid chromatographic columns were tested and similar results achieved, which shows the ruggedness of the method. 相似文献
982.
Campo J García-Valverde M Marcaccini S Rojo MJ Torroba T 《Organic & biomolecular chemistry》2006,4(5):757-765
Fast and convenient approaches to the indole nucleus from isocyanides are reviewed as a means for the tailored preparation of conveniently functionalized indoles by using the unique reactivity of isocyanides in one-pot multicomponent and cascade reactions. 相似文献
983.
Regular arrays of ca. micron sized droplets on a gold electrode surface can block diffusion to the electrode surface of one metal ion (which binds with the material in the droplet) whilst having no significant effect on another (which does not), so allowing interference effects in electroanalysis to be eliminated. 相似文献
984.
The adsorption/desorption equilibria of water vapor in a carbon molecular sieve (CMS) membrane and a commercial CMS adsorbent were determined, exhibiting S-shaped, type V isotherms. The fits of several models found in the literature to the experimental data were evaluated. The results obtained led to the development of a new model accounting for both adsorption and desorption and essentially based on the work of Lagorsse et al. (2005) [15]. Furthermore, the adsorption kinetics was also assessed for both materials and well described by a linear driving force model. The existence of hydrophilic groups responsible for water vapor adsorption in such carbonaceous materials has been related to the surface chemistry by means of X-ray microanalysis and by thermogravimetry. It was concluded from X-ray microanalyses that the carbon membrane presents a lower C/O ratio and is thus more sensitive towards water vapor exposure, as evidenced by the measured water adsorption at lower relative pressures. It was also observed that the diffusion rates are higher for the CMS membrane than for the CMS adsorbent. 相似文献
985.
In this work, the contact problem between an elastic body and a rigid obstacle is studied, including the development of material damage which results from internal compression or tension. The variational problem is formulated as a first-kind variational inequality for the displacements coupled with a parabolic partial differential equation for the damage field. The existence of a unique local weak solution is stated. Then, a fully discrete scheme is introduced using the finite element method to approximate the spatial variable and an Euler scheme to discretize the time derivatives. Error estimates are derived on the approximate solutions, from which the linear convergence of the algorithm is deduced under suitable regularity conditions. Finally, three two-dimensional numerical simulations are performed to demonstrate the accuracy and the behaviour of the scheme. 相似文献
986.
987.
We investigate the effect of superconducting and excitonic interactions, as well as their competition, on Dirac electrons on a bipartite planar lattice. It is shown that, at half-filling, Cooper pairs and excitons coexist if the superconducting and excitonic coupling parameters are equal and above a threshold corresponding to a quantum critical point. In the case where only the excitonic interaction is present, we obtain a critical chemical potential, as a function of the interaction strength. Conversely, if only the superconducting interaction is considered, we show that the superconducting gap displays a characteristic dome as charge carriers are doped into the system. We also show that, as the chemical potential increases, superconductivity tends to suppress the excitonic order parameter. 相似文献
988.
Leau Sorina Alexandra Lete Cecilia Marin Mariana del Campo Francisco Javier Diaconu Ioana Lupu Stelian 《Journal of Solid State Electrochemistry》2023,27(7):1755-1766
Journal of Solid State Electrochemistry - The development and analytical applications of electrochemical sensors based on antimony tin oxide (ATO)–Prussian blue (PB) screen-printed electrode... 相似文献
989.
Livia Campo 《Mathematische Nachrichten》2023,296(3):957-979
We classify Sarkisov links from index 1 Fano 3-folds anticanonically embedded in codimension 4 that start from so-called Type I Tom centres. We apply this to compute the Picard rank of many such Fano 3-folds. 相似文献
990.