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101.
Rimantė Zinkutė Ričardas Taraškevičius Tomas Želvys 《Central European Journal of Chemistry》2011,9(2):337-347
The relationship between real total contents of the major elements Na, Mg, Al, Si, P, S, K, Ca, Ti, Fe and the trace elements
Ag, As, B, Ba, Co, Cr, Cu, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, U, Zn in topsoil from the central part of Vilnius is analysed. The
amounts of most elements were determined by energy-dispersive X-ray fluorescence, while amounts of Ag, B, Co were measured
by optical atomic emission spectrophotometry. Two factors were distinguished according to major elements: anthropogenic (A)
including Ca, Mg, Fe, P, S and clayey (C) including K, Al, Ti. Boron, Mn, Cr and U are significantly correlated with members
of both factors, Sb with none of them and other trace elements either with all (Cu, Zn, Pb, Se, Ba, Ni, Co) or with separate
(V, Ag, Sn, Mo, As) members of the A-factor. Only B, Mn, Cr, U (partly their additive index Z1) are influenced by the C-factor,
while twelve other trace elements (also their additive index Z2) are influenced by the A-factor. The additive index Z of all
17 elements is also affected by the A-factor. Four groups of sites have been distinguished according to normal or higher contents
of both factors. The majority of trace element anomalies are related to the sites affected by the A-factor. 相似文献
102.
Central European Journal of Operations Research - Industry 4.0 (I4.0) implies a group of technologies, organisational concepts and management principles to improve the performance of manufacturing... 相似文献
103.
采用基于密度泛函理论的平面波超软赝势方法研究了 纯的和不同高氧空位浓度金红石型TiO2-x (x=0, 0.083, 0.125, 0.167, 0.25)超胞的能带结构分布、态密度分布.同时, 采用局域密度近似+U方法调准了带隙.结果表明, 高氧空位浓度越高, 金红石型TiO2的最小带隙越变窄、电子有效质量越减小, 自由电子浓度越高, 电子迁移率越低、电导率越低.计算结果与实验结果的变化趋势相符合.
关键词:
高氧空位
2')" href="#">金红石型TiO2
电导率
第一性原理 相似文献
104.
The total amplitude reflection coefficient of EM wave in a nonuniform plasma slab coated on perfect conductor plane is newly derived by using the scattering matrix method (SMM), and the attenuation is calculated. Three types of plasma electron density profile, that is the hyperbolic, sinusoidal, and linear profiles, are used. The external magnetic field and plasma parameters such as the maximum electron density and collision frequencies are discussed to calculate the attenuation of EM wave. The calculation results show that the plasma electron density profile and maximum electron density exert a large effect to the attenuation of EM wave and the attenuation under the uniform external magnetic field is taken place by the electron cyclotron resonance absorption, the up hybrid resonance absorption and geometric resonances absorption. 相似文献
105.
Slobodanka Stankovi Duan Lazar Ljubica Medi‐Mija
evi Katarina Penov‐Gai Marija Saka
Silvana Andri Bruvo Milenko 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):o172-o173
The title molecule, C26H30O3, shows a novel chemical rearrangement of the substituents at position 17, i.e. an α‐orientation of the hydroxy group and a β‐orientation of the bulky benzyl moiety. The packing arrangement consists of coils formed by O2?O3 hydrogen bonds along the c axis. The compound shows complete loss of oestrogenic activity, and neither does it exhibit an antagonistic effect. 相似文献
106.
A novel, convenient, efficient, three‐step, one‐pot synthesis of 2‐oxazolidinones from phenyl 2‐hydroxyalkyl selenides was developed. Using this methodology, 2‐oxazolidinones are obtained in good yields (76–85%) by reaction of phenyl 2‐hydroxyalkyl selenides with benzoyl isocyanate and subsequent oxidation/cyclization, followed by hydrolysis with hydrochloric acid solution. 相似文献
107.
DNA‐Hybrid‐Gated Multifunctional Mesoporous Silica Nanocarriers for Dual‐Targeted and MicroRNA‐Responsive Controlled Drug Delivery
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Penghui Zhang Fangfang Cheng Ri Zhou Dr. Juntao Cao Dr. Jingjing Li Prof. Dr. Clemens Burda Dr. Qianhao Min Prof. Dr. Jun‐Jie Zhu 《Angewandte Chemie (International ed. in English)》2014,53(9):2371-2375
The design of an ideal drug delivery system with targeted recognition and zero premature release, especially controlled and specific release that is triggered by an exclusive endogenous stimulus, is a great challenge. A traceable and aptamer‐targeted drug nanocarrier has now been developed; the nanocarrier was obtained by capping mesoporous silica‐coated quantum dots with a programmable DNA hybrid, and the drug release was controlled by microRNA. Once the nanocarriers had been delivered into HeLa cells by aptamer‐mediated recognition and endocytosis, the overexpressed endogenous miR‐21 served as an exclusive key to unlock the nanocarriers by competitive hybridization with the DNA hybrid, which led to a sustained lethality of the HeLa cells. If microRNA that is exclusively expressed in specific pathological cell was screened, a combination of chemotherapy and gene therapy should pave the way for a targeted and personalized treatment of human diseases. 相似文献
108.
An?elija Malenovi? Yannis Dotsikas Marija Maškovi? Biljana Jan?i?–Stojanovi? Darko Ivanovi? Mirjana Medenica 《Microchemical Journal》2011,99(2):454-460
In the current paper the application of multiobjective optimization (MOOP) technique, via Derringer's desirability function, to a microemulsion liquid chromatographic (MELC) method is described. Chromatographic separation of perindopril tert-butylamine and its four impurities was selected as the case study. Central composite design (CCD) with fractional factorial design, ± 0.5 α star design and four replications in central point was applied for a response surface study, in order to examine in depth the effects of the most important factors. As factors that influence the system mostly (i) content of ethyl acetate and (ii) butyl acetate in composite internal phase, (iii) content of sodium dodecyl sulfate (surfactant) and (iv) n-butanol (co-surfactant), as well as (v) pH of the mobile phase were selected. Retention factor of (a) perindoprilat and (b) impurity Y 31 and (c) resolution factor for impurities Y 32 and 33 were chosen for simultaneous optimization. By adjustment of the importance coefficients and weights, according to defined objectives, the optimal mobile phase composition was predicted to be: 0.24% w/v butyl acetate, 0.3% w/v ethyl acetate, 2% w/v SDS, 7.75% w/v n-butanol and pH of the mobile phase 3.7. The sensitivity analysis of desirability function for these optimal conditions was conducted for the first time in LC separations, by applying a sensitivity procedure. The performed sensitivity analysis confirmed that the higher overall desirability does not necessarily mean a better solution. The accuracy of prediction might be affected if the optimal levels of input variables, achieved from several design points, end up with equal settings and different corresponding overall desirability. In our study this was not the issue, which confirmed the adequacy of predicted optimum. 相似文献
109.
Marija Dimitrijević Larisa Jonke Lutz Möller Efrossini Tsouchnika Julius Wess Michael Wohlgenannt 《Czechoslovak Journal of Physics》2004,54(11):1243-1248
A general formalism is developed, that allows the construction of field theory on quantum spaces which are deformations of ordinary spacetime. The symmetry group of spacetime is replaced by a quantum group. This formalism is demonstrated for the -deformed Poincaré algebra and its quantum space. The algebraic setting is mapped to the algebra of functions of commuting variables with a suitable -product. Fields are elements of this function algebra. As an example, the Klein-Gordon equation is defined and derived from an action. 相似文献
110.
关于Hardy不等式的加强改进 总被引:6,自引:0,他引:6
对 Hardy不等式 ,建立如下结构的加强不等式 :∑∞n=11n∑nk=1akp 1 ,an≥ 0 (n∈ N) ,0 <∑∞n=1apn<∞ ,Cp=1 -(1 -p- 1) p- 1,p≥ 2 ;1 -p- 1,1
相似文献