Synthesen von α,β-ungesättigten 2-(2-Oxo-benzazolin-3-yl)-3-hydroxy-dithio-carbonsäure-alkylestern und entsprechend substituierten Keten-S,S-acetalen sowie deren Kristall- und Molekülstruktur

Summary The new alkyl 2-(2-oxo-benzazoline-3-yl)-3-hydroxy dithiocrotonates and dithiocinnamates4 and the corresponding ketene dithioacetals2 and5 are obtained by dithiocarboxylation of the 3-acceptormethyl substituted benzazoline-2-ones1 or3. Alkylation at room temperature gives compounds4 whereas at higher alkylation temperature2 or5 are formed. The results of X-ray analyses performed for methyl 3-hydroxy-p-chloro-dithiocinnamate4d and of N-[1-(4-chloro-benzoyl)-2,2-bis(methylthio)-vinyl]-benzothiazoline-2-one5e are discussed.

     

Quantum chemical calculations of the molecular structure of diphenylguanidine and experimental studies of its tautomerism in solution

MNDO-PM3 and AM1 quantum chemical calculations of the molecular structure of N,N′-diphenyl-guanidine (DPG) prove that the molecule preferably exists as an asymmetric tautomer with a basic center C = N−. IR and UV spectral data, dipole moments, and average molecular weights of DPG solutions in nonpolar and low-polar solvents confirm the results of calculations, indicating formation of hydrogen-bonded cyclic self-associates of DPG in solution. Translated fromZhumal Strukturnoi Khimii, Vol. 39, No. 4, pp. 618–625, July–August, 1998.     

Substitutive sulfotrioxidation of unsaturated and araliphatic organofluorine compounds

Conclusions Reaction of SO₂ or SO₃/[B₂O₃] with terminal fluoroolefins or fluoroalkylbenzenes gives the corresponding fluoroalken-2-yl fluorosulfates and fluorobenzyl fluorosulfates.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2791–2795, December, 1982.     

Functional derivatives of thiophene. I. Synthesis and 1H-NMR spectra in the 2-aminothiophene series

The preparation of 2-amino-5-nitrothiophene, 2-formamido-5-nitrothiophene, 2-acetamido-5-nitrothiophene and 2-t-butyloxycarbonylamino-5-nitrothiophene are described. Abnormal values of the coupling constants J_3.4 had been observed in the ¹H-nmr spectra of compounds obtained.     

Microanalysis of Si,S and Zn in GaSb by use of direct observation of (p,p′γ) reactions

The use of direct observation of nuclear reactions (p,p′γ) is discussed. The main characteristics of this method are presented and applied to the case of the miroanalysis of Si, S and Zn in GaSb.