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151.
Marcela Dvorakova Marie Pribylova Radek Pohl Marie E. Migaud Tomas Vanek 《Tetrahedron》2012,68(33):6701-6711
A migration of methyloxycarbonyl group from secondary to primary hydroxyl was observed in furanosides (ribosides and xylosides) under usual desilylation conditions using tetrabutylammonium fluoride. The migration was studied further on several alkyloxycarbonyl furanosides under either basic or acidic conditions. As follows from 13C labelling experiments and product distribution, the migration in xylosides, proceeds intramolecularly via six-membered cyclic carbonate, whereas in ribosides, the migration is intermolecular. Acidic conditions prevented the migration in ribosides whereas the migration in xylosides was circumvented under neutral conditions. 相似文献
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156.
Lidia Matesic Julie M. Locke Kara L. Vine Marie Ranson John B. Bremner Danielle Skropeta 《Tetrahedron》2012,68(34):6810-6819
To further expand the structure–cytotoxic activity relationships of isatin derivatives and to reduce flexibility in substituent groups at nitrogen, 20 analogues incorporating a ring system between the N1 and C7 atoms of isatin were prepared using a variety of synthetic strategies. This yielded pyrroloindole-, pyrroloquinoline-, pyrroloacridine-, pyrrolophenanthridine- and benzopyrrolophenanthridine-based systems with embedded isatin moieties, the latter possessing a novel carbon skeleton. These compounds were subsequently assessed for their in vitro cytotoxicity against human U937 lymphoma cells, with the brominated pyrroloacridine dione 27 showing the most promising activity (IC50 3.01 μM) after 24 h. 相似文献
157.
Soon-Lim ChongKhalijah Awang Marie Therese MartinMat Ropi Mokhtar Gomathi ChanMarc Litaudon Francoise GueritteKhalit Mohamad 《Tetrahedron letters》2012,53(40):5355-5359
Two structurally interesting novel limonoids, malayanine A and malayanine B, were isolated from the bark of Chisocheton erythrocarpus Hiern. The structures were fully characterized through spectroscopic methods. 相似文献
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159.
Gas-phase behaviour of negative ions produced from thiazidic diuretics under electrospray conditions
Garcia P Popot MA Fournier F Bonnaire Y Tabet JC 《Journal of mass spectrometry : JMS》2002,37(9):940-953
A systematic mass spectrometric study of 10 thiazidic diuretics and related compounds was undertaken by mass spectrometry (MS) with electrospray ionization in the negative ion mode. Collisional dissociation 'in-source' (CID-MS) and in a low-pressure collision cell (CID-MS/MS) were compared in both excitation regions. Spectra obtained by CID-MS and by CID-MS/MS were matched. Using the two methods, loss of HCl and consecutive dissociations from 2HCl losses were exhibited from compounds such as methyclothiazide and trichlormethiazide but not from other thiazidic diuretics that contain chlorine substituents in the aromatic moiety. However, deprotonated dichlorphenamide gave rise to loss of HCl by CID-MS and CID-MS/MS. For other diuretics such as hydroflumethiazide and hydrochlorothiazide, the loss of HCN and [HCN + SO(2)] was relevant. Reaction mechanisms were checked by means of deuterium-hydrogen exchange, which showed that deprotonation took place regioselectively on the heterocyclic moiety. The cleavage pathways require molecular isomerization forming ion-dipole complexes prior to decompositions, allowing long-distance proton transfer for neutral elimination. Identifications of the most specific fragmentations presented in this paper were applied to the screening and unambiguous identification of diuretics for horse doping control. 相似文献
160.
The particle size distribution of component materials can be important parameter governing the proper function of many industrial products. At present, accurate determination of particle size by currently available methods is difficult for both theoretical and practical reasons. In this paper, some elementary notions regarding particle sizing are reviewed as is the relative performance of commercially available particle sizing instrumentation which could be used for particle size analysis of dry powders. Our results indicate that various particle size instruments yield significantly (even vastly) different particle size distributions for the same material. Without great care on the part of the investigator, the results obtained from any given instrument may not accurately describe the powder in question and thus may cause incorrect technical recommendations. The use of Fraunhofer diffraction instruments on samples containing irregularly shaped small ( < 10 μm) particles of low refractive index requires considerable caution. 相似文献