全文获取类型
收费全文 | 124篇 |
免费 | 2篇 |
专业分类
化学 | 47篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 9篇 |
物理学 | 64篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2018年 | 2篇 |
2017年 | 6篇 |
2016年 | 6篇 |
2015年 | 2篇 |
2014年 | 5篇 |
2013年 | 8篇 |
2012年 | 11篇 |
2011年 | 5篇 |
2010年 | 8篇 |
2009年 | 3篇 |
2008年 | 5篇 |
2007年 | 1篇 |
2006年 | 3篇 |
2004年 | 3篇 |
2003年 | 2篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 4篇 |
排序方式: 共有126条查询结果,搜索用时 15 毫秒
31.
Ganesh KS Baskaran L Rajasekaran S Sumathi K Chidambaram AL Sundaramoorthy P 《Colloids and surfaces. B, Biointerfaces》2008,63(2):159-163
Water is seriously polluted by the discharge of various industrial wastewater containing heavy metals. Among them, chromium is considered to be toxic to living organisms and it is released mostly from tanneries. The chromium-contaminated water is discharged into nearby water bodies and it affects both aquatic and terrestrial plants. So the present experiment was conducted with an aquatic plant, water lettuce (Pistia stratiotes L.) and a terrestrial plant soybean (Glycine max L. Merr.). They were treated with different concentrations (0, 5, 10, 25, 50, 100 and 200mg/L) of potassium dichromate solution. The biochemical parameters such as total chlorophyll, carotenoid, protein and amino acid content and the enzymatic activities like catalase and peroxidase were estimated. The accumulation of chromium was also analysed in both the plants. All the biochemical contents and enzyme activities of water lettuce and soybean seedlings showed a great variation with respect to the increase in chromium concentrations. The accumulation of chromium increased gradually with the increase of chromium concentrations. Total inhibition of all the parameters were observed at 300 mg/L chromium concentration. The terrestrial plant soybean was sensitive than the aquatic plant water lettuce towards chromium stress. 相似文献
32.
Murugesan Vairalakshmi Veerian Raj Ponnusamy Sami Kasi Rajasekaran 《Transition Metal Chemistry》2011,36(8):875-882
The kinetics of oxidation of phenol and a few ring-substituted phenols by heteropoly 11-tungstophosphovanadate(V), [PVVW11O40]4− (HPA) have been studied spectrophotometrically in aqueous acidic medium containing perchloric acid and also in acetate buffers
of several pH values at 25 °C. EPR and optical studies show that HPA is reduced to the one-electron reduced heteropoly blue
(HPB) [PVIVW11O40]5−. In acetate buffers, the build up and decay of the intermediate biphenoquinone show the generation of phenoxyl radical (ArO·) in the rate-determining step. At constant pH, the reaction shows simple second-order kinetics with first-order dependence
of rate on both [ArOH] and [HPA]. At constant [ArOH], the rate of the reaction increases with increase in pH. The plot of
apparent second-order rate constant, k
2, versus 1/[H+] is linear with finite intercept. This shows that both the undissociated phenol (ArOH) and the phenoxide ion (ArO−) are the reactive species. The ArO−–HPA reaction is the dominant pathway in acetate buffer and it proceeds through the OH− ion triggered sequential proton transfer followed by electron transfer (PT-ET) mechanism. The rate constant for ArO−–HPA reaction, calculated using Marcus theory, agrees fairly well with the experimental value. The reactivity of substituted
phenoxide ions correlates with the Hammett σ+ constants, and ρ value was found to be −4.8. In acidic medium, ArOH is the reactive species. Retardation of rate for the
oxidation of C6H5OD in D2O indicates breaking of the O–H bond in the rate-limiting step. The results of kinetic studies show that the HPA-ArOH reaction
proceeds through a concerted proton-coupled electron transfer mechanism in which water acts as proton acceptor (separated-CPET). 相似文献
33.
T. Balu T.R. Rajasekaran P. Murugakoothan 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(4):955-958
Single crystals of bis (glycine) lithium molybdate [BGLM] with dimensions 20 mm × 10 mm × 5 mm were grown by slow evaporation technique. The grown crystals were subjected to powder X-ray diffraction studies. Functional groups of the crystallized molecules were confirmed by FTIR analyses. Transmission range of the crystal was determined by UV–vis–NIR spectra. Vickers microhardness test was performed on the prominent plane (0 1 1) of the grown crystal. The NLO property of the crystal was confirmed by Kurtz SHG test and compared with NLO efficiency of KDP crystal. 相似文献
34.
We study a model of quark confinement defined by the vanishing of colour currents. The model is shown to be equivalent to
quantum chromodynamics and this equivalence is interpreted as due to the compositeness of the colour gluons. The Green’s functions
of the theory are found to contain nontrivial structure only for colour singlet composites which can be identified with hadrons. 相似文献
35.
By using Kikkawa’s method the equivalence of the nonrenormalizable pair interaction
to a renormalizable theory is proved. Equivalence relationships between a few other nonrenormalizable and renormalizable
interactions are also indicated. 相似文献
36.
37.
Colour SU(3) symmetry is broken spontaneously by the introduction of coloured Higgs scalars in the standard SU(3)×SU(2)×U(1)
model, so as to make the quarks integrally charged. The resulting couplings of the Higgs bosons with the gauge bosons are
worked out. 相似文献
38.
Thermal fluctuations in angular momentum due to excitation is investigated. Shape changes or structural rearrangement are
observed as a consequence of fluctuation in second moment of spin. The uncertainty in angular momentum is considerably enhanced
due to thermal fluctuation and is strongly dependent on spin and structural changes. 相似文献
39.
Ifμ-e universality is assumed, there are 17 neutral-current parameters of current experimental interest, including the parity-violating
nuclear force sector. We deduce the general relations among these parameters implied by gauge models. In single-Z boson models, there are 10 relations, while two-boson models lead to 4 relations. Ifμ-e universality is abandoned, the number of parameters increases to 31, while the number of relations becomes 21 in single-boson
models and 12 in two-boson models. We derive all these relations. 相似文献
40.
We formulate a theory of generalized Fock spaces which underlies the different forms of quantum statistics such as ‘infinite’,
Bose-Einstein and Fermi-Dirac statistics. Single-indexed systems as well as multi-indexed systems that cannot be mapped into
single-indexed systems are studied. Our theory is based on a three-tiered structure consisting of Fock space, statistics and
algebra. This general formalism not only unifies the various forms of statistics and algebras, but also allows us to construct
many new forms of quantum statistics as well as many algebras of creation and destruction operators. Some of these are: new
algebras for infinite statistics,q-statistics and its many avatars, a consistent algebra for fractional statistics, null statistics or statistics of frozen
order, ‘doubly-infinite’ statistics, many representations of orthostatistics, Hubbard statistics and its variations. 相似文献