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81.
In this paper the electrophoretic mobility and the electrical conductivity of concentrated suspensions of spherical colloidal particles have been numerically studied under arbitrary conditions including zeta potential, particle volume fraction, double-layer thickness (overlapping of double layers is allowed), surface conductance by a dynamic Stern layer model (DSL), and ionic properties of the solution. We present an extensive set of numerical data of both the electrophoretic mobility and the electrical conductivity versus zeta potential and particle volume fraction, for different electrolyte concentrations. The treatment is based on the use of a cell model to account for hydrodynamic and electrical interactions between particles. Other theoretical approaches have also been considered for comparison. Furthermore, the study includes the possibility of adsorption and lateral motion of ions in the inner region of the double layers (DSL model), according to the theory developed by C. S. Mangelsdorf and L. R. White (J. Chem. Soc. Faraday Trans.86, 2859 (1990)). The results show that the correct limiting cases of low zeta potentials and thin double layers for dilute suspensions are fulfilled by our conductivity formula. Moreover, the presence of a DSL causes very important changes, even dramatic, on the values of both the electrophoretic mobility and the electrical conductivity for a great range of volume fractions and zeta potentials, specially when double layers of adjacent cells overlap, in comparison with the standard case (no Stern layer present). It can be concluded that in general the presence of a dynamic Stern layer causes the electrophoretic mobility to decrease and the electrical conductivity to increase in comparison with the standard case for every volume fraction, zeta potential, and double-layer thickness. 相似文献
82.
Octavio A. C. Antunes Jairo Bordinhão Nakédia M. F. Carvalho James L. Wardell Pedro A. Arroyo Márcio E. Berezuk Lucio Cardozo-Filho Edward R. T. Tiekink 《Journal of chemical crystallography》2007,37(4):291-298
Two structures of the closely related piperazinium salts, [1,4-bis-(2-methoxy-2-carbonylethyl)piperazinium (2+)] chloride
(1) and [1,4-bis-(2-amidoethyl)piperazinium (2+)] perchlorate (2) reveal the persistence of a layer structure, interspersed with anions, held in place by N–H···Cl, C–H···O and C–H···Cl interactions
in the case of 1, and N–H···O and C–H···O interactions in the case of 2. Compound 1 crystallizes in the triclinic space group P-1 with a=6.7667(6) ?, b = 6.9467(6) ?, c=9.3880(18) ?, α=105.845(9)°, β=99.896(16)°, γ=103.600(9)°, and Z=1. Compound 2 crystallizes in the monoclinic space group P21/c with a = 9.0930(8) ?, b=10.0525(11) ? c=10.2104(13) ?, β=114.279(9)°, and Z=2. 相似文献
83.
J. M. Aceves G. A. Arroyo Y. M. Vargas R. Miranda A. Cabrera F. Delgado 《Heteroatom Chemistry》2004,15(1):71-76
The reactions between 1,2-ethandithiol with several carbonylic compounds to form the corresponding 1,3-dithiolanes were performed using a natural clay as promotor. The target molecules are used as reagents to obtain fine chemicals, herbicides, fungicides, and pharmaceutical compounds among others applications. A kinetic study of camphorquinone and 1,2-ethandithiol showed a first-order dependence with 1,2-ethandithiol as well as with camphorquinone. The substrate transformation in percent was found to be dependent with the reaction time, the amount of catalyst, and the reagents concentration. © 2003 Wiley Periodicals, Inc. 15:71–76, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/.10215 相似文献
84.
D. Arroyo P. Chamorro J.M. Amigó F.B. Rodríguez P. Varona 《The European physical journal. Special topics》2013,222(2):457-472
In this work, we apply ordinal analysis of time series to the characterisation of neuronal activity. Automatic event detection is performed by means of the so-called permutation entropy, along with the quantification of the relative cardinality of forbidden patterns. In addition, multivariate time series are characterised using the joint permutation entropy. In order to illustrate the suitability of the ordinal analysis for characterising neurophysiological data, we have compared the measures based on ordinal patterns of time series to the tools typically used in the context of neurophysiology. 相似文献
85.
86.
Guadalupe Alcerreca Rubén Sanabria René Miranda Gabriel Arroyo Joaquín Tamariz Francisco Delgado 《合成通讯》2013,43(7):1295-1301
Several benzaldehydes were condensed with barbituric acid under infrared irradiation, in absence of solvent, affording the corresponding 5-benzylidene barbituric acids. 相似文献
87.
We consider Dirichlet boundary value problems for second order elliptic equations over polygonal domains. The coefficients of the equations under consideration degenerate at an inner point of the domain, or behave singularly in the neighborhood of that point. This behavior may cause singularities in the solution. The solvability of the problems is proved in weighted Sobolev spaces, and their approximation by finite elements is studied. This study includes regularity results, graded meshes, and inverse estimates. Applications of the theory to some problems appearing in quantum mechanics are given. Numerical results are provided which illustrate the theory and confirm the predicted rates of convergence of the finite element approximations for quasi-uniform meshes.
88.
A. O. Bazarko C. G. Arroyo K. T. Bachmann T. Bolton C. Foudas B. J. King W. C. Lefmann W. C. Leung S. R. Mishra E. Oltman P. Z. Quintas S. A. Rabinowitz F. J. Sciulli W. G. Seligman M. H. Shaevitz F. S. Merritt M. J. Oreglia B. A. Schumm R. H. Bernstein F. Borcherding H. E. Fisk M. J. Lamm W. Marsh K. W. B. Merritt H. M. Schellman D. D. Yovanovitch A. Bodek H. S. Budd P. de Barbaro W. K. Sakumoto T. Kinnel P. H. Sandler W. H. Smith 《Zeitschrift fur Physik C Particles and Fields》1995,65(2):189-198
We present the first next-to-leading-order QCD analysis of neutrino charm production, using a sample of 6090
– and
-induced opposite-sign dimuon events observed in the CCFR detector at the Fermilab Tevatron. We find that the nucleon strange quark content is suppressed with respect to the non-strange sea quarks by a factor =0.477
–0.053
+0.063
, where the error includes statistical, systematic and QCD scale uncertainties. In contrast to previous leading order analyses, we find that the strange seax-dependence is similar to that of the non-strange sea, and that the measured charm quark mass,m
c
=1.70±0.19 GeV/c2, is larger and consistent with that determined in other processes. Further analysis finds that the difference inx-distributions betweenxs(x) and
is small. A measurement of the Cabibbo-Kobayashi-Maskawa matrix element |V
cd
|=0.232
–0.020
+0.018
is also presented. 相似文献
89.
90.
André C. Silva Alan Arroyo R. Bruce Richter Orlando Lee 《Discrete Mathematics》2019,342(11):3201-3207
The crossing number of a graph is the least number of crossings over all possible drawings of . We present a structural characterization of graphs with crossing number one. 相似文献