A memetic algorithm based on a NSGAII scheme for the flexible job-shop scheduling problem

The Flexible Job-Shop Scheduling Problem is concerned with the determination of a sequence of jobs, consisting of many operations, on different machines, satisfying several parallel goals. We introduce a Memetic Algorithm, based on the NSGAII (Non-Dominated Sorting Genetic Algorithm II) acting on two chromosomes, to solve this problem. The algorithm adds, to the genetic stage, a local search procedure (Simulated Annealing). We have assessed its efficiency by running the algorithm on multiple objective instances of the problem. We draw statistics from those runs, which indicate that this Memetic Algorithm yields good and low-cost solutions.     

Portfolio selection in the Spanish stock market by interactive multiobjective programming

This study examines new versions of two interactive methods to address multiobjective problems, the aim of which is to enable the decision maker to reach a solution within the range of those considered efficient in a portfolio selection model, in which several objectives are pursued concerning risk and return and given that these are clearly conflicting objectives, the profile of the model proposed is multicriteria. Normally the range of efficient portfolios is fairly extensive thus making the selection of a single one an onerous task. In order to facilitate this process, interactive methods are used aimed at guiding the decision maker towards the optimal solution based on his preferences. Several adaptations were carried out on the original methods in order to facilitate the interactive process, improving the quality of the obtained portfolios, and these were applied to data obtained from the Madrid Stock Market, interaction taking place with two decision makers, one of whom was more aggressive than the other in their selections made.     

A Masked Form of an O-Borylated Breslow Intermediate for the Diastereoselective FLP-Type Activation of Aldehydes

Breslow intermediates are very often elusive species whose application in frustrated Lewis pair (FLP) chemistry is unprecedented. Described herein is the use of a masked form of an O-borylated Breslow (OBB) intermediate that performs FLP-type activation of the carbonyl function of five different benzaldehyde derivatives with complete diastereoselectivity. The resulting compounds are characterised in solution by NMR spectroscopy (compounds 4 – 8 ) and in solid state by X-ray diffraction analysis (compounds 4 – 6 ). A combined kinetic and theoretical investigation reveals the associative nature of the rate determining step and suggests that the OBB intermediate part is never released during the whole process.     

Synthesis and reactivity of alkynyl niobocene complexes

The synthesis of alkynyl containing niobocene complexes with differing auxiliary ligands is described. The niobium(III) derivatives of the general formula [Nb(η⁵-C₅H₄SiMe₃)₂(CCR)(L)] where L is either carbonyl, phosphine, phosphite, or isocyanide, were prepared by the reaction of the bis(alkynyl)magnesium reagent with the corresponding cloro-niobocene precursor. In a similar manner the niobium(V) imido compounds, of the general formula, [Nb(=NR′)(η⁵-C₅H₄R″)₂(CCR)], were prepared. The characterization of these complexes is discussed. The reactivity of the alkynyl compounds towards oxidation and protonation has been studied.     

On the dirichlet problem for surfaces of prescribed mean curvature

A necessary and sufficient condition is given for the solvability of the Dirichlet problem for surfaces of prescribed mean curvature, and global regularity of the solution is studied.     

Antiunitary symmetry operators in quantum mechanics

A criterion to decide that some symmetries of a quantum system must be realized as antiunitary operators is given. It is based on some mathematical theorems about the second cohomology group of the symmetry group when expressed in terms of those of a normal subgroup and the corresponding factor group. It is also shown that this criterion implies that the only possibility for the unitary subgroup in the Galilean case is that generated by the space reflection and the connected component containing the identity; otherwise only massless systems would arise.     

Functionalized HMS mesoporous silica as solid phase extractant for Pb(II) prior to its determination by flame atomic absorption spectrometry

In this work, a mesoporous silica has been chemically modified with 5-mercapto-1-methyl-1-H-tetrazol using the homogeneous route (MTTZ-HMS). This synthetic route involved the reaction of 5-mercapto-1-methyl-1-H-tetrazol with 3-chloropropyltriethoxysilane, prior to immobilization on the support. The resulting material has been characterized and employed as solid phase extractant for Pb(II). The effect of several variables (stirring time, pH, temperature, metal concentration, presence of other metals) has been studied using batch and column techniques. In batch experiments, 15 min stirring time, 55 degrees C and pH 8 were the optimal conditions for Pb(II) adsorption. In column experiments, sorption was quantitative for 1000 mL of 2.41 x 10(-4 )mM of Pb(II) solution and adsorbed ions were eluted out by 5 mL of 1 M HCl (preconcentration factor of 200). Spiked tap water was used for the preconcentration and determination of Pb(II) by flame atomic absorption spectrometry, and a 100% recovery was obtained. The LOD and LOQ values of the proposed method were found to be 3.52 x 10(-3) and 4.20 x 10(-3 )mM, respectively. The RSD for three preconcentration experiments was found to be 相似文献