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971.
4-Amino-3-arylisothiazole-5-carboxylate esters are converted to the corresponding desamino, chloro, bromo, and iodo esters by processes involving nonaqueous diazotization. These related procedures open up the possibility for the conversion of readily available heterocyclic ortho-amino esters and nitriles to related heterocyclic derivatives, which are not easily obtained by alternate routes. 相似文献
972.
Summary High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for relatively homogeneous elements at ppm and sub-ppm level. About 40 elements could be determined with detection limits of 10 to 30 ppb. Two pattern recognition methods, principal component analysis and clustering analysis, were applied to obtain information on trace element distribution, which indicated that a number of elements were strongly spatially correlated in the analysed sample.
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
Chemische Analyse und Verteilungsbestimmung von Spurenelementen in Indium-Matrix durch Funkenquellen-Massenspektrometrie
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
973.
In the framework of three-dimensional stability equations, we study the local instability of a horizontal excavation with elliptic cross-section under the assumption that the rock mass behaves like an elastoviscoplastic media. An estimate of the influence of the rock mass parameters on the value of the critical pressure is given. 相似文献
974.
Consider the problem of three point vortices (also called Helmholtz’ vortices) on a plane, with arbitrarily given vorticities.
The interaction between vortices is proportional to 1/r, where r is the distance between two vortices. The problem has 2 equilateral and at most 3 collinear normalized relative equilibria.
This 3 is the optimal upper bound. Our main result is that the above standard statements remain unchanged if we consider an
interaction proportional to r
b, for any b < 0. For 0 < b < 1, the optimal upper bound becomes 5. For positive vorticities and any b < 1, there are exactly 3 collinear normalized relative equilibria. The case b = −2 of this last statement is the well-known theorem due to Euler: in the Newtonian 3-body problem, for any choice of the
3 masses, there are 3 Euler configurations (also known as the 3 Euler points). These small upper bounds strengthen the belief
of Kushnirenko and Khovanskii [18]: real varieties defined by simple systems should have a simple topology. We indicate some
hard conjectures about the configurations of relative equilibrium and suggest they could be attacked within the quasi-polynomial
framework. 相似文献
975.
976.
High even order generalizations of the traditional upwind method are introduced to solve second order ODE-BVPs without recasting
the problem as a first order system. Both theoretical analysis and numerical comparison with central difference schemes of
the same order show that these new methods may avoid typical oscillations and achieve high accuracy. Singular perturbation
problems are taken into account to emphasize the main features of the proposed methods.
AMS subject classification (2000) 65L10, 65L12, 65L50 相似文献
977.
Polyvinyl alcohol (PVA)-based proton conducting polymer electrolytes have been prepared by the solution cast technique. The
conductivity is observed to increase from 10−9 to 10−4 S cm−1 as a result of orthophosphoric acid (H3PO4) addition. The plot of conductivity vs temperature shows that a phase transition occurred at 343 K in the sample PVA-33 wt%
H3PO4. The β-relaxation peak is observed at 313 K. The glass transition temperature of PVA-33 wt% H3PO4 is 343 K. Orthophosphoric acid seems to play a dual role, i.e., as a proton source and as a plasticizer. The ac conductivity
σ
ac = Aω
s was also calculated in the temperature range from 303 to 353 K. The conduction mechanism was inferred by plotting the graph
of s vs T from which the conduction mechanism for sample PVA-17 wt% H3PO4 was inferred to occur by way of the overlapping large polaron tunneling (OLPT) model and the conduction mechanism for the
sample PVA-33 wt% H3PO4 by way of the correlated barrier height (CBH) model. 相似文献
978.
J.T. Elizalde Galindo A.H. Adair C.E. Botez V. Corral Flores D. Bueno Baques L. Fuentes Cobas J.A. Matutes-Aquino 《Applied Physics A: Materials Science & Processing》2007,87(4):743-747
Measurements of ac-susceptibility and dc-magnetization were carried out on samples of Ni1-xZnxFe2O4 nanoparticles (x=0, 0.25, 0.5, 0.75) with average diameters 〈D〉≈7 nm. Values of the superparamagnetic blocking temperature
T̄B were obtained from the characteristic temperature behavior of the imaginary susceptibility χimag. An Arrhenius-type law, which accurately describes the relationship between the observation time τobs and the blocking temperature, was used to determine the effective energy barrier to magnetization reversal Ueff. A Zn-content dependence of the energy barrier is observed, where Ueff changes little for 0≤x≤0.25, it peaks at x=0.5, and decreases back upon further Zn-doping. The large increase of Ueff at x=0.5 is attributed to an enhanced magnetic anisotropy induced by the crossover between two spatial arrangements of spins
in the A and B sub-lattices of the ferrimagnetic inverse spinel.
PACS 75.50.Bb; 75.50.Gg; 75.30.Et 相似文献
979.
D.L. Mills 《Applied Physics A: Materials Science & Processing》2007,87(3):427-431
This paper begins with some historical remarks regarding the author’s early interest in the use of electron energy loss spectroscopy
to probe dynamical phenomena on crystal surfaces. We then discuss the physical nature of the interactions responsible for
vibrational and spin waves losses, with attention to their role in related phenomena.
PACS 61.14.-x; 68.35.Ja; 68.49.Jk; 68.49.Uv 相似文献
980.
Y.-Q. Peng J.-H. Yang F.-P. Lu Q.-S. Yang H.-W. Xing X.-S. Li C.-A. Song 《Applied Physics A: Materials Science & Processing》2007,86(2):225-229
Based on the assumption of Gaussian energy distributions of the lowest unoccupied molecular orbital (LUMO) and the highest occupied molecular orbital (HOMO), analytical expressions of generalized Einstein relation in chemically doped organic semiconductor are developed, by approximation of Coulomb traps with a rectangle potential well. Numerical calculations show that traditional Einstein relations do not hold for chemically doped organic semiconductors. Similar to physical doping, the dependence of diffusion coefficient to mobility D/μ ratio on the carrier concentration has a maximum. An essential difference between chemical doping and physical doping is that, the D/μ ratio in chemically doped organic semiconductors depends not only on carrier concentration and doping concentration, but also on the applied electric field. PACS 71.20.Rv; 72.90.+y; 73.50.-h 相似文献