Crossing of shears bands in 196Pb

High-spin states in 196Pb have been populated using the reaction ¹⁷⁰Er(³⁰Si,4n). The previously observed shears bands in this nucleus have been extended and some of their transitions have been reordered. They now form regular bands with band crossings. One of the bands splits into two pathways at high spin.     

Bidding strategy with forecast technology based on support vector machine in the electricity market

The participants in the electricity market are concerned very much with the market price evolution. Various technologies have been developed for price forecasting. The SVM (Support Vector Machine) has shown its good performance in market price forecasting. Two approaches for forming the market bidding strategies based on SVM are proposed. One is based on the price forecasting accuracy, with which the rejection risk is defined. The other takes into account the impact of the producer’s own bid. The risks associated with the bidding are controlled by the parameter settings. The proposed approaches have been tested on a numerical example.     

Physico-chemical properties of aqueous extremely diluted solutions in relation to ageing

An extensive study has been carried out on aqueous ‘extremely diluted solutions’ (EDS). The employed experimental methodologies were well established physico-chemical techniques: flux calorimetry, conductometry, pH-metry, e.m.f. of suitable galvanic cell. The obtained results show that the preparation procedure significantly alters the physico-chemical behaviour of such solutions. Moreover, the analysis of the experimental data vs. the ‘arrow of time’ turned out to be astonishingly important. In fact some measured physico-chemical parameters evolve with time. Some experimentally measurable physico-chemical properties of the solvent water were largely affected by both time and the ‘life path’ of the samples. In particular, we evidenced two new experimental phenomena characterizing the EDS: the presence of a series of maximums in the measured electrical conductivity vs. the sample age; the dependence of said maximums on the volume of the EDS during its ageing. All of these new experimental results clearly suggest the presence of an extended and ‘ordered’ dynamics involving the whole of the water molecules in the liquid. A temporal evolution, featuring three maximums in the course of four years of ageing and the dependence on the ageing volumes do not fit the framework of classical thermodynamics. It therefore seems appropriate to interpret these phenomena on the basis of the thermodynamics of dissipative structures, which are far from equilibrium systems.     

Catalytic Alkyne Semihydrogenation with Polyhydride Ni/Ga Clusters

The bimetallic, decanuclear Ni₃Ga₇-cluster of the formula [Ni₃(GaTMP)₃(μ²-GaTMP)₃(μ³-GaTMP)] ( 1 , TMP=2,2,6,6-tetramethylpiperidinyl) reacts reversibly with dihydrogen under the formation of a series of (poly-)hydride clusters 2 . Low-temperature 2D NMR experiments at −80 °C show that 2 consist of a mixture of a di- ( 2_Di ), tetra- ( 2_Tetra ) and hexahydride species ( 2_Hexa ). The structures of 2_Di and 2_Tetra are assessed by a combination of 2D NMR spectroscopy and DFT calculations. The cooperation of both metals is essential for the high hydrogen uptake of the cluster. Polyhydrides 2 are catalytically active in the semihydrogenation of 4-octyne to 4-octene with good selectivity. The example is the first of its kind and conceptually relates properties of molecular, atom-precise transition metal/main group metal clusters to the respective solid-state phase in catalysis.     

Amplified Chirality Transfer to Aromatic Molecules through Non-specific Inclusion by Amorphous,Hyperbranched Poly(fluorenevinylene) Derivatives

Optically active, hyperbranched, poly(fluorene-2,4,7-triylethene-1,2-diyl) [poly(fluorenevinylene)] derivatives bearing a neomenthyl group and a pentyl group at the 9-position of the fluorene backbone at various ratios acted as a chirality donor (host polymers) efficiently included naphthalene, anthracene, pyrene, 9-phenylanthracene, and 9,10-diphenyanthracene as a chirality acceptor (guest molecules) in their interior space in film as well as in solution, with the guest molecules exhibiting intense circular dichroism through chirality transfer with chirality amplification. The efficiency of the chirality transfer was much higher with higher-molar-mass polymers than lower-molar-mass ones as well as with hyperbranched polymers compared to the analogous linear ones. The hyperbranched polymers include the small molecules in their complex structure without any specific interactions at various stoichiometries. The included molecules may have ordered intermolecular arrangement that may be somewhat similar to those of liquid crystals. Naphthalene, anthracene, and pyrene included in the polymer exhibited efficient circularly polarized luminescence, where the chirality was remarkably amplified in excited states, and anthracene exhibited especially high anisotropies in the emission on the order of 10⁻².     

79Kr高自旋超形变的观测

通过５５Ｍｎ（３０Ｓｉ,αｐｎ）反应布居了７９Ｋｒ的高自旋态．用ＧＡＳＰ阵列配以由４０个ΔＥ×ＥＳｉ（Ａｕ）望远镜所组成的带电粒子球实现γγγ－带电粒子符合测量．观测到由相对强度为（２．７±０．３）％的８条级联γ跃迁所组成的７９Ｋｒ高自旋超形变转动带．除了在转动频率ω＞０．９５ＭｅＶ处急剧下降外,该带的动力学转动惯量近乎常数（22ñ2／ＭｅＶ）并被解释为具有四极形变参数β２＝０．５１以及本征侵入组态为π５０ν５１． High-spinstates in 79Kr were populated via the fusion evaporation reaction 55Mn (30Si,αpn)at 130 MeV.Promptγ γγ charged particle coincidences were measured by using the GASP array in conjunction with the ΔE×E Si(Au) charged particle ball.Asu perdeformed band consisting of 8 γ ray transitions with an intensity of (2.7±0.3)% has been indentified in 79Kr.The dynamic moment of inertia for the band is nearly constant at approxately 22ñ2/MeV below arotational frequency of 0.95 MeV...     

Proteomics of bovine myelin sheath: Characterization of a truncated form of P0 by MALDI-TOF/TOF mass spectrometry

The glycoprotein P0, the major structural protein of the peripheral nerve myelin, plays a critical role in holding myelin lamellae together via interaction of both extracellular and cytoplasmic domains. Mutations in the human P0 gene give rise to severe and progressive forms of dominantly inherited peripheral neuropathies like CMT1B. Here we report on the characterization of a bovine P0-derived protein of nearly 26 kD that corresponds to the P0 protein truncated in its cytoplasmic domain. Matrix assisted laser desorption ionization (MALDI)-time-of-flight/time-of-flight (TOF/TOF) mass spectrometry (MS) analysis on its tryptic digest has provided a peptide mapping, the main difference of which from the normal P0 analog was represented by the absence of the cluster of peaks at m/z 1513.7501, 1530.7701, and 1546.7651. The latter corresponds to the P0 fragment QTPVLYAMLDHSR and to its pyroglutamic and methionine-oxidized derivatives. The species at 1530.7701 covering the sequence 186-198 of P0 is not an artifact and might have a functional role in the myelin architecture.     

Modeling impurity-assisted chain creation in noble-metal break junctions

In this work we present the generalization of the model for chain formation in break junctions, introduced by Thiess et al (2008 Nano Lett. 8 2144), to zigzag transition-metal chains with s and p impurities. We apply this extended model to study the producibility trends for noble-metal chains with impurities, often present in break junction experiments, namely, Cu, Ag and Au chains with H, C, O and N adatoms. Providing the material-specific parameters for our model from systematic full-potential linearized augmented plane-wave first-principles calculations, we find that the presence of such impurities crucially affects the binding properties of the noble-metal chains. We reveal that both the impurity-induced bond strengthening and the formation of zigzag bonds can lead to a significantly enhanced probability for chain formation in break junctions.     

Light and heavy dansyl reporter groups in food chemistry: amino acid assay in beverages

5-Dimethylamino-1-sulfonyl naphthalene (DNS, commonly referred as dansyl) is a functionality, bearing well-established properties in directing the fragmentation, by mass spectrometry (MS), of the corresponding ionized sulfonylated derivatives. This property is shared also by its labeled analogs. The use of d(0)/d(6) DNS derivatives is now exploited in the application of the well-established isotope dilution mass spectrometric approach in the assay of complex mixtures. A new method for the quantitation of amino acids (AAs) in beverages is therefore presented, which relies on liquid chromatographic separation of their N-dansylated derivatives followed by comparative electrospray tandem MS/MS of the d(0)/d(6) isobaric mixtures. Labeled and unlabeled DNS derivatives of the selected AAs are readily available by microwave-assisted synthetic protocols. The novelty of the method is represented by the use of heavy and light DNS-isotopologue providing suitable reporter groups. Multiple-reaction monitoring has been applied in the assay of AAs in wine, pineapple juice and bergamot juice with good-to-excellent results as proved by both relative standard deviation, lower than 15%, and by the accuracy values in the range 90-110%.     

Correlation between yield and operating conditions in the electrochemical fluorination of tripropylamine

Electrochemical fluorination of tripropylamine in anhydrous hydrogen fluoride was studied in order to verify the correlation between the operating conditions and the yield of the corresponding perfluoroamine. The parameters tested were: temperature, voltage, initial concentration of amine in the bath, constant concentration of amine in the bath and stirring effect. Experimental data show that temperature is the parameter exerting the most remarkable influence over perfluoroamine yield and by-products formation.