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41.
42.
Some nickel, copper, and silver salts or complexes are efficient catalysts for the oxidation of benzylic ethers with oxygen in 1,2-dimethoxyethane. Salts of the weakly coordinating anion trifluoroacetate are particularly efficient, approaching (and, in some cases, improving) the yields obtained with cobalt(II) chloride, the best catalyst so far reported. 相似文献
43.
P. González D. Fernández J. Pou E. García J. Serra B. León M. Pérez-Amor T. Szörényi 《Applied Physics A: Materials Science & Processing》1993,57(2):181-185
A study of the gas-phase parameters involved in ArF laser induced chemical vapour deposition of silicon-oxide thin films is presented. A complete set of experiments has been performed showing the influence of the concentration of the precursor gases, N2O and SiH4, and their influence on total and partial pressures on film growth and properties. In this paper we demonstrate the ability of this LCVD method to deposit silicon oxide films of different compositions and densities by appropriate control of gas composition and total pressure. Moreover, a material specific calibration plot comprising data obtained using different preparation techniques is presented, allowing determination of the stoichiometry of SiO
x
films by using FTIR spectroscopy independently of the deposition method. For the range of processing conditions examined, the experimental results suggest that chemical processes governing deposition take place mainly in the gas phase. 相似文献
44.
V.I. Fernández A. Iucci C.M. Naón 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(1):53-56
We present an extension of the Tomonaga-Luttinger model in which left and right-moving particles have different Fermi velocities.
We derive expressions for one-particle Green's functions, momentum-distributions, density of states, charge compressibility
and conductivity as functions of both the velocity difference ε and the strength of the interaction β. This allows us to identify
a novel restricted region in the parameter space in which the system keeps the main features of a Luttinger liquid but with
an unusual behavior of the density of states and the static charge compressibility κ. In particular κ diverges on the boundary
of the restricted region, indicating the occurrence of a phase transition.
Received 20 May 2002 / Received in final form 23 August 2002 Published online 19 November 2002 相似文献
45.
Maria Marques Zhengtian Yu Marvin D. Rausch James C. W. Chien 《Journal of polymer science. Part A, Polymer chemistry》1995,33(16):2787-2793
4-Vinylcyclohexene (VCH) and cyclooctadiene (COD) were investigated as termonomers in EPDM (ethylene/propylene/diene) synthesis by using rac-ethylenebis (1-η5-indenyl) zir-conium dichloride ( 1 ) as a catalyst precursor. Homopolymerizations of VCH, vinylcycloh-exane and cyclohexene were compared. The parameter Kπκp, which is the apparent rate constant for Ziegler-Natta polymerization, is about the same for VCH and vinylcyclohexanebut is 10 times smaller for cyclohexene. Therefore, the linear olefinic double bond is more active than the cyclic internal double bond. VCH reduces ethylene polymerization rate but not propylene polymerization rate in copolymerizations. In terpolymerizations, VCH tends to suppress ethylene incorporation especially at elevated polymerization temperature and Lowers the polymer MW by about two-fold. COD has very low activity as a termonomer. © 1995 John Wiley & Sons, Inc. 相似文献
46.
47.
48.
Lévy processes in matrix Lie groups are studied. Subordination (random time change) is used to show that quasi-invariance of the Brownian motion in a Lie group induces absolute continuity of the laws of the corresponding pure jump processes. These results are applied to several examples which are discussed in detail. 相似文献
49.
In this Note, we give a necessary and sufficient condition for Lagrangians in a symplectic vector bundle to be deformed stably into transversal Lagrangians. In the case of three Lagrangians, we show that the associated Grothendieck group can be identified with a Hermitian K-theory group. To cite this article: M. Karoubi, M.L. Lapa de Souza, C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
50.
Maria Chudnovsky Jim Geelen Bert Gerards Luis Goddyn Michael Lohman Paul Seymour 《Combinatorica》2006,26(5):521-532
Let G=(V,E) be an oriented graph whose edges are labelled by the elements of a group Γ and let A⊂V. An A-path is a path whose ends are both in A. The weight of a path P in G is the sum of the group values on forward oriented arcs minus the sum of the backward oriented arcs in P. (If Γ is not abelian, we sum the labels in their order along the path.) We are interested in the maximum number of vertex-disjoint
A-paths each of non-zero weight. When A = V this problem is equivalent to the maximum matching problem. The general case also includes Mader's S-paths problem. We prove that for any positive integer k, either there are k vertex-disjoint A-paths each of non-zero weight, or there is a set of at most 2k −2 vertices that meets each of the non-zero A-paths. This result is obtained as a consequence of an exact min-max theorem.
These results were obtained at a workshop on Structural Graph Theory at the PIMS Institute in Vancouver, Canada. This research
was partially conducted during the period the first author served as a Clay Mathematics Institute Long-Term Prize Fellow. 相似文献