Design of neutral, mono- or di-cationic water-soluble trihydrazidophosphoradamantanes

The versatile behavior of a trihydrazidophosphoradamantane allowing the synthesis of a variety of neutral, mono- or di-cationic water-soluble molecules of potential interest for biphasic catalysis is reported.     

Sufficiency in Quantum Statistical Inference

This paper attempts to develop a theory of sufficiency in the setting of non-commutative algebras parallel to the ideas in classical mathematical statistics. Sufficiency of a coarse-graining means that all information is extracted about the mutual relation of a given family of states. In the paper sufficient coarse-grainings are characterized in several equivalent ways and the non-commutative analogue of the factorization theorem is obtained. As an application we discuss exponential families. Our factorization theorem also implies two further important results, previously known only in finite Hilbert space dimension, but proved here in generality: the Koashi-Imoto theorem on maps leaving a family of states invariant, and the characterization of the general form of states in the equality case of strong subadditivity. Supported by the EU Research Training Network Quantum Probability with Applications to Physics, Information Theory and Biology and Center of Excellence SAS Physics of Information I/2/2005. Supported by the Hungarian grant OTKA T032662     

Challenging Students to View the Concept of Area in Triangles in a Broad Context: Exploiting the Features of Cabri-II

This study focuses on the constructions in terms of area and perimeter in equivalent triangles developed by students aged 12–15 years-old, using the tools provided by Cabri-Geometry II [Labore (1990). Cabri-Geometry (software), Université de Grenoble]. Twenty-five students participated in a learning experiment where they were asked to construct: (a) pairs of equivalent triangles “in as many ways as possible” and to study their area and their perimeter using any of the tools provided and (b) “any possible sequence of modifications of an original triangle into other equivalent ones”. As regards the concept of area and in contrast to a paper and pencil environment, Cabri provided students with different and potential opportunities in terms of: (a) means of construction, (b) control, (c) variety of representations and (d) linking representations, by exploiting its capability for continuous modifications. By exploiting these opportunities in the context of the given open tasks, students were helped by the tools provided to develop a broader view of the concept of area than the typical view they would construct in a typical paper and pencil environment.     

Growth rate of the Schrödinger group on Zhidkov spaces

We give an upper bound on the growth rate of the Schrödinger group on Zhidkov spaces. In dimension 1, we prove that this bound is sharp. To cite this article: C. Gallo, C. R. Acad. Sci. Paris, Ser. I 342 (2006).     

Asymptotic optimality of the bayes estimator in models differentiable in quadratic mean

We study the asymptotic properties of the Bayes estimator in models differentiable in quadratic mean (DQM) in the case of independent and identically distributed observations. The goal is to define weak assumptions on the model under which this estimator is asymptotically efficient, regular, and asymptotically of minimal risk. The results of the paper are applied to models based on a mixture distribution, the Cauchy distribution with location and scale parameter, and the Weibull distribution. Bibliography: 10 titles. Published in Zapiski Nauchnykh Seminarov POMI, Vol. 328, 2005, pp. 114–146.     

Observation of dielectronic satellites in the K-spectrum of argon ions in plasma produced by femtosecond laser pulses

The satellite structure of 1s2p ^1,3 P ₁-1s ²¹ S ₀ lines of the He-like argon ion in plasma produced by a 45-fs laser pulse in a gas-jet cluster target is measured with a high spectral resolution. Radiation transitions 2p → 1s from autoionizing states (AISs) are detected for ions ranging from Li-like to F-like. The spectrum observed is theoretically simulated with the use of the spectroscopic data for the AISs of multicharged ions obtained within the multiconfiguration relativistic Hartree-Fock method. Good agreement with experimental data is obtained when the main population channels of these states are taken into account for typical values of cluster-target plasma parameters.     

Syntactic characterization of closure under connected limits

Summary We give a syntactic characterization of (finitary) theories whose categories of models are closed under the formation of connected limits (respectively the formation of pullbacks and substructures) in the category of all structures. They are also those theories whose consistent extensions by new atomic facts admit in each component an initial structure (respectively an initial term structure), and also thoseT for whichM(T) is locally finitely multi-presentable in a canonical way. We also show that these two properties of theories are nonuniform.     

Une formule de Landau–Zener pour un croisement non dégénéré et involutif de codimension 3Landau–Zener formula for non-degenerate involutive codimension 3 crossings

In this Note, we study a 2×2 system of evolution equations with some codimension 3 crossing. We derive two conditions of non-degeneracy. We focus on one of them and reduce our system to some Landau–Zener's type system. Using this reduction, we describe the energy transfer at the crossing by Landau–Zener formula for 2-scales semi-classical measures. To cite this article: C. Fermanian Kammerer, P. Gérard, C. R. Acad. Sci. Paris, Ser. I 335 (2002) 915–920.