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131.
132.
Maria G. Semenova Larisa E. Belyakova Anna S. Antipova Yu. N. Polikarpov Lida Klouda Anna Markovic Michael M. Il'in 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):47-54
We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na+), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed. 相似文献
133.
134.
Maria Manfredini Andrea Pascucci 《Proceedings of the American Mathematical Society》2003,131(4):1115-1120
We prove some maximum and gradient estimates for classical solutions to a wide class of quasilinear degenerate parabolic equations, including first order ones. The proof is elementary and exploits the smallness of the domain in the time direction.
135.
C. S. Munita L. P. Barroso P. M. S. Oliveira 《Journal of Radioanalytical and Nuclear Chemistry》2006,269(2):335-338
Summary In general, when characterizing samples, such as ceramic samples or other types of samples, for first time by means of chemical
elements, the analyst measures a large number of variables, many of which may not be very informative. In fact, some may even
be unrelated to the issue at hand and blur the picture instead of making it clearer. In subsequent studies the analyst may
wish to measure fewer variables for several reasons, such as being very time consuming; in cases where measurement time is
important, such as on-line monitoring; in order to reduce cost or effort; etc. Therefore, the hope is to determine those variables
that are most relevant without losing essential information and to remove the less productive information. The problem is
how to perform this in an objective way and to capture crucial information using a multivariate analysis. This paper aims
to describe and illustrate a stopping rule for the identification of redundant variables, and the selection of variable subsets,
preserving multivariate data structure using stepwise discriminant analysis, selecting those variables that are in some senses
adequate for discrimination purposes. One illustrative example using data sets obtained via INAA of ceramic samples from two
archaeological sites is provided. 相似文献
136.
The physico-chemical properties and reactivity tested by hydrogen reduction have been studied for two series of NiO-ZnO mixed oxides of various composition. The solid nickel oxide or zinc oxide in interaction with the solution of nitrate of the second component were used as the precursors in each series. The differences in some physico-chemical parameters of the samples in both series were correlated with their reduction behaviour, followed both in iso- and non-isothermal regime. Moreower, the influence of various factors modifying the reactivity of mixed oxides was also investigated and the results were compared with those obtained from earlier studied analogous systems of quite different origin.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
137.
Marcos Almeida Bezerra Sérgio Mitihiro do Nascimento Maêda Eliane Padua Oliveira Maria de Fátima Batista de Carvalho Ricardo Erthal Santelli 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰. 相似文献
138.
We investigate the connection between the dynamics of
synchronization and the modularity on complex networks. Simulating
the Kuramoto's model in complex networks we determine patterns of
meta-stability and calculate the modularity of the partition these
patterns provide. The results indicate that the more stable the
patterns are, the larger tends to be the modularity of the partition
defined by them. This correlation works pretty well in homogeneous
networks (all nodes have similar connectivity) but fails when
networks contain hubs, mainly because the modularity is never
improved where isolated nodes appear, whereas in the synchronization
process the characteristic of hubs is to have a large stability when
forming its own community. 相似文献
139.
M. C. Caracoche J. A. Martínez P. C. Rivas M. A. Taylor A. F. Pasquevich S. Barolin O. A. de Sanctis 《Hyperfine Interactions》2007,179(1-3):87-93
The hyperfine quadrupole interaction at Hf sites in films and powders of 14 mol% CaO–HfO2 and 20 mol% CaO–HfO2 has been determined as a function of temperature. Results indicate the formation of a cubic solid solution and other microstructures assigned to the ?1 (CaHf4O9) and ?2 (Ca6Hf19O44) phases. Dynamical effects on the electric field gradient reveal the existence of oxygen vacancies movements in the solid solution. The thermal behavior of the relaxation constant observed in films allowed the determination of activation energies of 0.54 eV and 0.70 eV for the 14 mol% and 20 mol% CaO doped hafnias, respectively. The influence of the microdomains and the stability of the cubic solid solution are discussed. 相似文献
140.
B. G. Konopelchenko L. Martínez Alonso E. Medina 《Theoretical and Mathematical Physics》2007,151(3):820-830
Based on the Lenard relations, we completely classify integrable deformations of general algebraic curves. We construct the
general solution of the Lenard relation from the invariance condition with respect to an element of the Galois group of the
curve. We give some examples and also some associated conservation laws.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 151, No. 3, pp. 458–469, June, 2007. 相似文献