Polarographisches Verhalten von 1,2,3-Cyclohexantrion-trioxim in sauren Lösungen

The deoximation kinetics of 1,2,3-cyclohexanetrione trioxime was studied polarographically in 0.5 and 1.0M-HClO₄ solutions. From the three vicinal oxime groups, that in position 2 is hydrolysed by protonisation, followed by water uptake and hydroxylamine loss. The probable mechanism of the deoximation was proved by the study of the polarographic behaviour of 1,2,3-cyclohexanetrione-1,3-dioxime and by means of amperometric determination of the unchanged trioxime with Ni(II)-salt.     

Aktivierungsenergie des H2O2-Zerfalls im mikroheterogenen System in Gegenwart von Hydrosolen röntgenamorpher Eisen (III)-hydroxide

Zusammenfassung Die Hydrosole des röntgenamorphen Eisen (III)-hydroxids und seines Polymerysationsprodukts katalysieren in einer Reaktion I. Ordnung mit verschiedener Geschwindigkeit den H₂O₂-Zerfall, der bei 27° und 37° untersucht wurde. Auch die daraus berechneten Aktivierungsenergien ergaben differente Werte.     

Alcune classi di epimorfismi d’anelli

Riassunto Si indicano una costruzione e alcune proprietà del morfismo terminale nella categoria degli epimorfismi iniettivi di dato dominioA, conA anello commutativo unitario ridotto. Si considerano poi certi epimorfismi di dominioA, detti ?S-spezzamenti irriducibili? (S⊂A). GliS-spezzamenti irriducibili a codominio ridotto risultano parametrizzati (a meno di isomorfismi) dai chiusi di una opportuna topologia su SpecA.

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Summary LetA be any reduced commutative ring with 1. Consider the category of injective ring-epimorphisms with domainA. In the first part of this paper, a construction and some properties of a final morphism in the above category are shown. In the second part, some special epimorphisms with domainA are considered, which are called irreducible ?S-spezzamenti?. A parametrization of the collection of irreducible ?S-spezzamenti? (up to isomorphisms) is given, by the collection of closed sets of a suitable topology on SpecA.

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Lavoro eseguito nell’ambito del Gruppo Nazionale Strutture Algebriche e Geometriche e Applicazioni del C.N.R.