全文获取类型
收费全文 | 58595篇 |
免费 | 1917篇 |
国内免费 | 58篇 |
专业分类
化学 | 38027篇 |
晶体学 | 308篇 |
力学 | 960篇 |
综合类 | 1篇 |
数学 | 10348篇 |
物理学 | 10926篇 |
出版年
2023年 | 430篇 |
2022年 | 718篇 |
2021年 | 952篇 |
2020年 | 936篇 |
2019年 | 909篇 |
2018年 | 1185篇 |
2017年 | 1058篇 |
2016年 | 2067篇 |
2015年 | 1790篇 |
2014年 | 1717篇 |
2013年 | 3799篇 |
2012年 | 3638篇 |
2011年 | 3570篇 |
2010年 | 2336篇 |
2009年 | 2031篇 |
2008年 | 3110篇 |
2007年 | 2890篇 |
2006年 | 2540篇 |
2005年 | 2543篇 |
2004年 | 2197篇 |
2003年 | 1829篇 |
2002年 | 1642篇 |
2001年 | 1108篇 |
2000年 | 1078篇 |
1999年 | 768篇 |
1998年 | 620篇 |
1997年 | 524篇 |
1996年 | 696篇 |
1995年 | 494篇 |
1994年 | 566篇 |
1993年 | 515篇 |
1992年 | 527篇 |
1991年 | 463篇 |
1990年 | 495篇 |
1989年 | 432篇 |
1988年 | 429篇 |
1987年 | 375篇 |
1986年 | 370篇 |
1985年 | 508篇 |
1984年 | 491篇 |
1983年 | 367篇 |
1982年 | 390篇 |
1981年 | 399篇 |
1980年 | 333篇 |
1979年 | 317篇 |
1978年 | 322篇 |
1977年 | 298篇 |
1976年 | 309篇 |
1974年 | 263篇 |
1973年 | 278篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
191.
192.
D. I. T. Fávaro D. Mafra V. A. Maihara L. Cuppari M. B. A. Vasconcellos S. M. F. Cozzolino 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(3):533-536
Having in mind the importance of Fe and Zn content in the diets of nondialyzed patients with chronic renal failure, diets
of 39 patients with ages varying from 18 to 79 years under a conservative treatment were analyzed by INAA. The 24-hour recall
method was used for sample collection. The content of proximate composition was also determined. The average daily dietary
intake was compared to the new recommended values by the Food and Nutrition Board. It was observed that the diets were deficient
for these elements and, therefore, there should be a nutritional follow-up to avoid possible negative effects.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
193.
In this paper, we use an algebraic type of closure, which is called vector closure, and through it we introduce some adaptations to the proper efficiency in the sense of Hurwicz, Benson, and Borwein in real linear spaces without any particular topology. Scalarization, multiplier rules, and saddle-point theorems are obtained in order to characterize the proper efficiency in vector optimization with and without constraints. The usual convexlikeness concepts used in such theorems are weakened through the vector closure. 相似文献
194.
I. Zvára 《Physics of Atomic Nuclei》2003,66(6):1125-1130
Studies of chemistry of the transactinoid elements, which are available only as single atoms, by gas (thermo)chromatographic techniques can provide the adsorption enthalpies of the atoms or molecules. These values serve the ultimate goal—to characterize bulk volatility of the species in terms like sublimation enthalpies. The paper attempts an in-depth discussion of the statistical significance of the adsorption enthalpies derived in such experiments. Usually, the counting statistics are very poor and one faces nonstandard problems in evaluating the confidence intervals for the values of parameters. Here, a most efficient way seems to be the Bayesian approach, realized, when necessary, by Monte Carlo simulations of the counting results. Necessarily, the adsorption enthalpy is not evaluated based on the second law of thermodynamics but through accepting an a priori value of the adsorption entropy. More additional assumptions about the mechanisms and parameters involved are needed. This may produce systematic errors in the quantitative conclusions; the analysis of some recent works with elements 106 and 108 corroborates this concern. Despite such problems, it is possible to reveal qualitative differences in the adsorption behavior of a transactinoid and its expected known congeners as well as to use chemistry for an independent assignment of the atomic numbers of transactinoid nuclides. 相似文献
195.
K. Migléczi Gy. Somorjai M. Pátfalusi G. Tóth Gy. Horváth I. Hazai 《Chromatographia》2004,60(1):S67-S74
GYKI-16084 – (+)-(R)-2-{3-(benzo[1,4]dioxan-2-yl-methylamino)-1-propyl}-3(2H)-pyridazinone hydrochloride – is a new drug candidate for the treatment of benign prostatic hyperplasia. In our study the major metabolites formed in the rat and dog were isolated from dog and rat urine, then their structures were elucidated by means of MS and NMR. A two stage solid phase extraction (SPE) procedure and a semi-preparative HPLC method were developed utilizing various mechanisms of separation. The major metabolites proved to be isomeric glucuronides of the benzodioxane moiety hydroxylated at positions 6 or 7 and {2-(2-carboxyethyl)-3(2H)-pyridazinone}. 相似文献
196.
Essam Totry Carlos González Javier LLorca 《International Journal of Solids and Structures》2008,45(6):1663-1675
The influence of the loading path on the failure locus of a composite lamina subjected to transverse compression and out-of-plane shear is analyzed through computational micromechanics. This is carried out using the finite element simulation of a representative volume element of the microstructure, which takes into account explicitly fiber and matrix spatial distribution within the lamina. In addition, the actual failure mechanisms (plastic deformation of the matrix and interface decohesion) are included in the simulations through the corresponding constitutive models. Two different interface strength values were chosen to explore the limiting cases of composites with strong or weak interfaces. It was found that failure locus was independent of the loading path for the three cases analyzed (pseudo-radial, compression followed by shear and shear followed by compression) in the composites with strong and weak interfaces. This result was attributed to the fact that the dominant failure mechanism in each material was the same in transverse compression and in shear. Failure is also controlled by the same mechanisms under a combination of both stresses and the failure locus depended mainly on the magnitude of the stresses that trigger fracture rather than in the loading path to reach the critical condition. 相似文献
197.
The vertical migration of 85Sr, 137Cs and 131I in some arable and undisturbed single-contaminated soils was studied by gamma-spectrometry measurements under lysimetric laboratory conditions during irrigation of the soil profiles with wet atmospheric precipitation for about one year, except 131I. A new simple exponential compartment (box) model was derived, which makes it possible to calculate the migration rate constants and migration rates in the individual soil layers (vertical sections) as well as the total vertical migration rate constants and total vertical migration rates of radionuclides in the bulk soil horizon. The relaxation times of radionuclides in respective soil horizons can also be evaluated. 相似文献
198.
Stanis aw Urban Maria Massalska-Arod
Albert Wü rflinger Roman D browski 《Liquid crystals》2003,30(3):313-318
The pressure-temperature ( p - T ) phase diagrams for four smectogenic members of the 4'-alkyl-4-cyanobiphenyl homologous series ( n CB, n =9, 10, 11 and 12) over the temperature range 320-410 K and pressure range 0.1-300 MPa (3 kbar) were constructed using DTA. At 1 atm 9CB exhibits nematic and smectic A d phases, while the other members show only the smectic A d phase. However, at elevated pressures the clearing line splits in the case of 10CB and 11CB which indicates the induction of a nematic phase. It was found that the triple point, where the isotropic, nematic and smectic phases coexist, is strongly shifted to higher pressures with increasing chain length. This was interpreted as being caused by a loss of the rod-like shape of the molecules containing longer alkyl tails which explore a range of conformations. The slope of the clearing line, d T /d p , depends strongly on the length of the alkyl chain for the n CB series, but does not show a step-wise change between the nematogenic and smectogenic members. 相似文献
199.
In this paper an automatic technique for handling discontinuous IVPs when they are solved by means of adaptive Runge–Kutta codes is proposed. This technique detects, accurately locates and passes the discontinuities in the solution of IVPs by using the information generated by the code along the numerical integration together with a continuous interpolant of the discrete solution. A remarkable feature is that it does not require additional information on the location of the discontinuities. Some numerical experiments are presented to illustrate the reliability and efficiency of the proposed algorithms. 相似文献
200.