全文获取类型
收费全文 | 766篇 |
免费 | 25篇 |
国内免费 | 2篇 |
专业分类
化学 | 552篇 |
晶体学 | 4篇 |
力学 | 13篇 |
数学 | 96篇 |
物理学 | 128篇 |
出版年
2023年 | 8篇 |
2022年 | 9篇 |
2021年 | 13篇 |
2020年 | 19篇 |
2019年 | 13篇 |
2018年 | 14篇 |
2017年 | 16篇 |
2016年 | 27篇 |
2015年 | 25篇 |
2014年 | 23篇 |
2013年 | 47篇 |
2012年 | 48篇 |
2011年 | 62篇 |
2010年 | 29篇 |
2009年 | 31篇 |
2008年 | 36篇 |
2007年 | 37篇 |
2006年 | 39篇 |
2005年 | 51篇 |
2004年 | 33篇 |
2003年 | 25篇 |
2002年 | 27篇 |
2001年 | 17篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 11篇 |
1987年 | 5篇 |
1984年 | 5篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 5篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1966年 | 2篇 |
1963年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有793条查询结果,搜索用时 31 毫秒
41.
This paper describes a novel, sensitive detection system for biomolecules (DNA and proteins etc.) that is integrated in a lab-on-a-chip utilizing optical compact discs (CDs) and bio-nanofibers. The new method comprises a microchannel containing CD grating that confines fragments of unique bacterial cellulose fibrils (BC), which have nanometre scale fibers and holes. A maximum of six times higher sensitivity to detect DNA was obtained with this CD and BC system compared to a conventional method. We also demonstrate an effective light-confining effect for biological application with the new method. 相似文献
42.
Canevali C Mari CM Mattoni M Morazzoni F Nodari L Ruffo R Russo U Scotti R 《The journal of physical chemistry. B》2005,109(15):7195-7202
The mechanism of NO interaction with nanosized Ru(Pd,Pt)-doped SnO(2) was studied by electron paramagnetic resonance, M?ssbauer, and electric resistance measurements. Three steps were proposed for the reaction between the semiconductor oxide and the gaseous component: (i) the formation of bielectronic oxygen vacancies (V(o)) in SnO(2); (ii) their single-ionization (V(o)(*)) with injection of electrons into the SnO(2) conduction band; (iii) the subsequent transfer of electrons from V(o)(*) to [Ru(Pd,Pt)](4+). The last process induces the formation of further oxygen vacancies which reduce the transition metal centers to lower oxidation states; the redox processes is enhanced and the electrical resistance in transition metal-doped SnO(2) is stronger modified with respect to the undoped material. 相似文献
43.
Sugita M Yamaguchi A Yamagiwa N Handa S Matsunaga S Shibasaki M 《Organic letters》2005,7(23):5339-5342
[reaction, structure: see text] Chiral Y{N(SiMe3)2}3/linked-BINOL catalyst generated Y-enolate in situ from various hydroxyketones (R2 = aryl, heteroaryl). Beta-amino-alpha-hydroxy ketones (R1 = aryl, heteroaryl, alkenyl) were obtained syn-selectively (up to 96/4) in high ee (up to 98%) and good yield (up to 98% yield). 相似文献
44.
Using tools of quantum information theory we show that the ground state of the Dicke model exhibits an infinite sequence of instabilities (quantum-phase-like transitions). These transitions are characterized by abrupt changes of the bi-partite entanglement between atoms at critical values kappa(j) of the atom-field coupling parameter kappa and are accompanied by discontinuities of the first derivative of the energy of the ground state. We show that in a weak-coupling limit (kappa1 < or = kappa < or = kappa2) the Coffman-Kundu-Wootters inequalities are saturated, which proves that for these values of the coupling no intrinsic multipartite entanglement (neither among the atoms nor between the atoms and the field) is generated by the atom-field interaction. We show that in the strong-coupling limit the entangling interaction with atoms leads to a highly sub-Poissonian photon statistics of the field mode. 相似文献
45.
N.?LeprovostEmail author L.?Marié B.?Dubrulle 《The European Physical Journal B - Condensed Matter and Complex Systems》2004,39(1):121-129
A stochastic model is derived to predict the turbulent torque produced by a swirling flow. It is a simple Langevin process, with a colored noise. Using the unified colored noise approximation, we derive analytically the PDF of the fluctuations of injected power in two forcing regimes: constant angular velocity or constant applied torque. In the limit of small velocity fluctuations and vanishing inertia, we predict that the injected power fluctuates twice less in the case of constant torque than in the case of constant angular velocity forcing. The model is further tested against experimental data in a von Karman device filled with water. It is shown to allow for a parameter-free prediction of the PDF of power fluctuations in the case where the forcing is made at constant torque. A physical interpretation of our model is finally given, using a quasi-linear model of turbulence.Received: 29 January 2004, Published online: 18 June 2004PACS:
47.27.-i Turbulent flows, convection, and heat transfer - 47.27.Eq Turbulence simulation and modeling 相似文献
46.
Tellez MR Khan IA Schaneberg BT Crockett SL Rimando AM Kobaisy M 《Journal of chromatography. A》2004,1025(1):51-56
A new method involving concurrent solid-phase microextraction combined with continuous hydrodistillation of essential oil was developed. This new methodology allowed for the detection by GC-MS of very small amounts of a diagnostic peak for the authentication of Ephedra sinica, in a short period of time and using only small sample sizes. This diagnostic peak was identified as 4-vinylanisole, and elucidated from the chromatographic profile allowed for the identification of a sample as E. sinica among other species investigated in this study. To the best of our knowledge this is the first report on using continuous solid-phase microextraction coupled to hydrodistillation for the investigation of essential oil components, and the first report of 4-vinylanisole as a marker compound for E. sinica. A total of 46 collections representing 21 species of Ephedra were studied. 相似文献
47.
L.?Marié J.?Burguete F.?DaviaudEmail author J.?Léorat 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,33(4):469-485
A numerical study of the magnetic induction equation has
been performed on von Kármán type flows. These flows are
generated by two co-axial counter-rotating propellers in
cylindrical containers. Such devices are currently used in the
von Kármán sodium (VKS) experiment designed to study dynamo
action in an unconstrained flow. The mean velocity fields have
been measured for different configurations and are introduced in
a periodic cylindrical kinematic dynamo code. Depending on the
driving configuration, on the poloidal to toroidal flow ratio
and on the conductivity of boundaries, some flows are observed
to sustain growing magnetic fields for magnetic Reynolds numbers
accessible to a sodium experiment. The response of the flow to
an external magnetic field has also been studied: The results
are in excellent agreement with experimental results in the
single propeller case but can differ in the two propellers case. 相似文献
48.
Marián Slodička 《Applications of Mathematics》2003,48(1):49-66
In this paper, we consider a 2nd order semilinear parabolic initial boundary value problem (IBVP) on a bounded domain N, with nonstandard boundary conditions (BCs). More precisely, at some part of the boundary we impose a Neumann BC containing an unknown additive space-constant (t), accompanied with a nonlocal (integral) Dirichlet side condition.We design a numerical scheme for the approximation of a weak solution to the IBVP and derive error estimates for the approximation of the solution u and also of the unknown function . 相似文献
49.
Mariël G. Pikkemaat 《Analytical and bioanalytical chemistry》2009,395(4):893-905
Monitoring of food products from animal origin for the presence of antimicrobial residues is preferably done using microbial
screening methods because of their high cost-effectiveness. Traditionally applied methods fail to detect the maximum residue
limits which were established when EU Council Regulation 2377/90 came into effect. Consequently, during the last decade this
has led to the development of improved microbial screening methods. This review provides an overview of the efforts expended
to bring antibiotic screening methods into compliance with EU legislation. It can be concluded that the current situation
is still far from satisfactory. 相似文献
50.
Mariá Ernestina Chávez Rodríguez Angel López Gómez 《International Journal of Theoretical Physics》2001,40(1):95-104
The only pair of binary classical essential connectives for which the Artin braid relation holds is a distributive lattice, i.e. the Boolean disjunction and conjunction of 相似文献