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81.
Margarita Arias 《Journal of Mathematical Analysis and Applications》2010,367(2):499-507
We study the solvability of the quasilinear elliptic problem of parameter s
82.
Let Φ be a linear functional of the space ${\mathcal{C} =\mathcal{C}(\Delta)}$ of continuous functions on an interval Δ. The nonlocal boundary problem for an arbitrary linear differential equation $$ P\left(\frac{d}{d t}\right)y = F(t) $$ with constant coefficients and boundary value conditions of the form $$ \Phi\{\,y^{(k)}\} =\alpha_k,\,\,\,k = 0,\,1,\,2,\, \ldots,\,{\rm deg} P-1 $$ is said to be a nonlocal Cauchy boundary value problem. For solution of such problems an operational calculus of Mikusiński’s type, based on the convolution $$ (f*g)(t) = \Phi_\tau\, \left\{{\int\limits_\tau^t} f(t+\tau - \sigma)\,g(\sigma)\, d \sigma\, \right\}, $$ is developed. In the frames of this operational calculus the classical Heaviside algorithm is extended to nonlocal Cauchy problems. The obtaining of periodic, antiperiodic and mean-periodic solutions of linear ordinary differential equations with constant coefficients both in the non-resonance and in the resonance cases reduces to such problems. Here only the non-resonance case is considered. Extensions of the Duhamel principle are proposed. 相似文献
83.
To demonstrate the nature of the interaction of optical isomers of propranolol with the surface of the graphitic electrode modified with melamine, uracil, cyanuric, and isocyanuric acids, we have performed molecular dynamics simulations of the four‐component systems with variable modifier's molecules. We have considered the possible formation of complexes between the propranolol and modifier's molecules, covering the electrode approximated as the graphene surface. Our simulations demonstrate that the l ‐isomer in aqueous solutions is bonded to the electrode surface stronger than its d ‐counterpart; hence, the difference in analytical signals arises. Different strengths of bonding of the propranolol enantiomers to the surface modifiers are caused by the different intramolecular interactions taking place in the molecules of d ‐ and l ‐isomers. Thus, we have computationally shown that the modification of the graphite surface with melamine, uracil, cyanuric, and isocyanuric acids allows for increasing the sensitivity of the electrode toward the propranolol enantiomers and using the modified graphitic electrodes for the detection of its d ‐ and l ‐forms. 相似文献
84.
Jesús Alvarez Marien Lopez-Arias Rebeca de Nalda Margarita Martín 《Applied Physics A: Materials Science & Processing》2008,92(4):831-836
The neutral species present in CdS ablation plumes upon nanosecond 532 nm laser irradiation at a moderate fluence of 0.5–0.75 J cm−2 have been studied. Neutral Cd
n
S
m
clusters have been identified, some as large as (CdS)33−34 (1–2 nm in diameter). The analysis of the dynamics of neutral species shows an expansion with two components that differ
both in composition and dynamics. A fast, high kinetic energy component, dominated by S2 which acquires free-flow conditions at short distances from the target, is followed by a slower component characterized by
similar speeds for all species. This slower component shows dynamic features that are expected to favor aggregation processes
leading to effective cluster formation. 相似文献
85.
86.
A full-field generic photonic biosensor approach, which relies on a bio-doped polymeric strip waveguide configuration, is described. We show the potential of tailor-made hybrid polymeric materials prepared by sol-gel technology for the fabrication of ultra-compact biosensor devices, where both the transducer and the recognition elements are merged into one single microstructure. Such devices were fabricated by micromolding in capillaries (MIMIC) soft lithographic technique. In contrast to evanescent field sensors, the sensor response does not only rely on the interaction of the evanescent wave with the recognition element, but on the interaction of the whole field, thus enabling a reduction of the sensor dimensions and/or a decrease of its limit of detection (LOD). The potential of this generic approach was demonstrated by developing a biosensor for the detection of H(2)O(2) using horseradish peroxidase (HRP) as the doping agent. Solutions containing 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic) acid (ABTS) and different concentrations of H(2)O(2) were dispensed over the waveguide and the green-coloured cation radical ABTS*(+) product was mainly obtained inside the photonic structure, resulting in a maximum absorption increase of 2.5 a.u. at a set working wavelength of 670 nm over the H(2)O(2) concentration range studied. The sensor exhibited a sensitivity of (3.1+/-0.2) x 10(3) a.u./mol L(-1) and a limit of detection (LOD) of 4.4 x 10(-5) mol L(-1) H(2)O(2). These results anticipate that full-field waveguide microstructures based on bio-doped sol-gel polymers will enable the fabrication of cost-effective photonic biosensors. Moreover, the ease of fabrication by a soft lithography technique and the use of such polymeric materials are fully compatible with their integration in compact automatic analysis systems. 相似文献
87.
The 3-oxygenated-cis-dialkyl-2,5-substituted tetrahydrofuran system, present in several natural products, was prepared with good selectivity by acidic cyclization of 5-alkene-1,2,4-triol derivatives. The starting alkenol was obtained in few steps from a chiral cis-diol resulting from microbial oxidation of bromobenzene. The study of the cyclization allowed the rationalization of all experimental results by assuming a complete ionization at the allylic position and a model close to the one proposed by Labelle for homoallylic induction in five-membered ring closures. 相似文献
88.
Margarita Baeva 《Plasma Chemistry and Plasma Processing》2016,36(1):151-167
Effects caused by thermal and chemical nonequilibrium in free-burning arcs in argon are presented and discussed. The results cover a range of arc currents between 100 and 200 A, interelectrode distance of 5–10 mm, and a variation of the electrode material and the shape of the cathode tip. The results obtained show that nonequilibrium in the near-electrode regions has a strong impact on the distributions of temperatures, electric conductivity and current density, and the arc voltage. Departure from chemical nonequilibrium in the vicinity of the cathode as a result of transport processes is indicated. Moreover, overpopulation of the atomic ground state close to the arc axis, under population of the excited states in the arc periphery with respect to the equilibrium values, axial dependence of the off-axis maximum of the radial emission coefficient of Ar I at 696.5 nm, and enhanced population of the Ar (1s4) resonance level due to trapping of resonance radiation in the arc periphery are considered. 相似文献
89.
We investigate the conditions for the coefficients of probabilistic and multinomial values of cooperative games necessary and/or sufficient in order to satisfy some properties, including marginal contributions, balanced contributions, desirability relation and null player exclusion property. Moreover, a similar analysis is conducted for transfer property of probabilistic power indices on the domain of simple games. 相似文献
90.
de Oca Porto RM Pérez AR Correa Vidal MT 《Rapid communications in mass spectrometry : RCM》2007,21(12):1871-1876
Ephedrines have central nervous system stimulating properties and, for this reason, some of them are forbidden in sport by the World Antidoping Agency (WADA). They are screened and quantitated in urine by several published techniques and confirmed by gas chromatography/mass spectrometry (GC/MS). In this paper, a simple confirmation procedure for norpseudoephedrine, norephedrine, ephedrine and pseudoephedrine in human urine by GC/electron ionization (EI)-MS is described. After the addition of levallorphane as internal standard, a liquid-liquid extraction procedure under alkaline conditions with tert-butyl methyl ether was applied to the samples. The analytes were derivatized with acetic acid anhydride and N-methyl-N-trimethylsilyltrifluoroacetamide to form N-acetyl-O-trimethylsilyl derivatives. The EI mass spectra of all the studied substances have many diagnostic ions with relative abundance in accordance with WADA requirements and show great structural information content. A curious migration of the trimethylsilyl group is proposed. 相似文献