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21.
Agnieszka Grzelka Marek Cypryk Peter C. Hupfield 《Journal of organometallic chemistry》2004,689(4):705-713
Kinetics studies of the condensation of model hydroxyl-terminated oligosiloxanes, pentamethyldisiloxane-1-ol (MDH) and heptamethyltrisiloxane-1-ol (MD2H), catalysed by protic complex of tetrakis(pentafluorophenyl)borate in the toluene solution were performed. The dominating reaction was condensation, which was accompanied by disproportionation of oligosiloxanols. Water released in the condensation forms separate dispersed phase, but the phase separation and the presence of water does not affect the rate of the polycondensation. Both processes, condensation and disproportionation, show analogous kinetic laws being first order in silanol and half order in catalyst. They exhibit also similar values of activation parameters. The kinetics are explained by the formation of a reactive protic complex of silanol with borate being in fast preequilibrium with an unreactive complex including two borate molecules and the silanol molecules. The equilibrium lies to the side of the unreactive borate complex. 相似文献
22.
Examples of quasi-exactly solvable hamiltonians in the Bargmann—Fock representation are given. The existence of an invariant subspace is studied as a result of hidden symmetry of the spectral problem. 相似文献
23.
Marek Pękała Jan Mucha Benedicte Vertruyen Rudi Cloots Marcel Ausloos 《Journal of magnetism and magnetic materials》2006
Samples of La0.7Ca0.3Mn1−xGaxO3 with x=0, 0.025, 0.05 and 0.10 were prepared by standard solid-state reaction. They were first characterized chemically, including the microstructure. The magnetic properties and various transport properties, i.e. the electrical resistivity, magnetoresistivity (for a field below 8 T), thermoelectric power and thermal conductivity measured each time on the same sample, are reported. The markedly different behaviour of the x=0.1 sample from those with a smaller Ga content, is discussed. The dilution of the Mn3+/Mn4+ interactions with Ga doping considerably reduces the ferromagnetic double exchange interaction within the manganese lattice leading to a decrease of the Curie temperature. The polaron binding energy varies from 224 to 243 meV with increased Ga doping. 相似文献
24.
Summary This paper describes a simplified model which links the sedimentary concentration of selected biomarkers to their export primary production, their stability during transit to the anoxic sediment layer and the sediment bulk sedimentation rate. Manipulation of the biomarker data permits the individual effects of these processes to be separated. Examples demonstrate the use of this strategy in the evaluation of environmentally significant parameters. 相似文献
25.
We present a construction which shows that some special continua do not have the nonwandering-eventually-periodic property. The construction applies e.g. to the topologist's sin curve and to the harmonic fan. 相似文献
26.
Jon Samseth Richard J. Spontak Kell Mortensen 《Journal of Polymer Science.Polymer Physics》1993,31(4):467-474
Poly(siloxaneimide) (PSI) segmented copolymers exhibit organized microdomains if the blocks are sufficiently incompatible. As with neat diblock and triblock copolymers, the processing route employed to prepare films of PSI materials is expected to influence the dimensions and/or morphology of the resultant microstructure. In this work, small-angle neutron scattering (SANS) is utilized to characterize the disordered microstructure found in films of a series of PSI copolymers which are subjected to solvent casting and various thermal treatments. Microstructural dimensions such as the periodicity and correlation length are deduced from the Teubner-Strey (TS) model for disordered microemulsions. The scattering intensity of each copolymer up to q = 5.0 nm?1, where q is the scattering vector, is found to scale as q?2.8+?0.1. Results indicate that processing the materials as cast films or as melt-pressed films allowed to cool slowly has a small, but discernible, effect on microstructural characteristics. SANS profiles of films quenched from elevated temperatures reveal a clear transition in microdomain periodicity, which correlates well with the glass transition temperature of the imide microphase in these and other materials of similar chemical structure. © 1993 John Wiley & Sons, Inc. 相似文献
27.
The title compound (C14H8N2O7,M
r
=306.2) crystallizes in the orthorhombic space group Pbca witha=6.962(1).b=24.688(1), andc=15.890(1)Å,V=2731.0 Å3,D
x
=1.489 g·cm–3 forZ=8,=0.98 mm–1,F(000)=1296,T=293 K. FinalR=0.053 for 1873 observed reflections. The structure was solved by direct methods. Approximately planar molecules lie perpendicular to the [100] direction and show partial stacking. The structure is the first example of a symmetric anhydride which does not retain the symmetry in the crystal state. The two independent nitro groups twist out of the ring planes by 10.5 and 14.8°, respectively. 相似文献
28.
Summary Comparison theorems for weak splittings of bounded operators are presented. These theorems extend the classical comparison theorem for regular splittings of matrices by Varga, the less known result by Wonicki, and the recent results for regular and weak regular splittings of matrices by Neumann and Plemmons, Elsner, and Lanzkron, Rose and Szyld. The hypotheses of the theorems presented here are weaker and the theorems hold for general Banach spaces and rather general cones. Hypotheses are given which provide strict inequalities for the comparisons. It is also shown that the comparison theorem by Alefeld and Volkmann applies exclusively to monotone sequences of iterates and is not equivalent to the comparison of the spectral radius of the iteration operators.This work was supported by the National Science Foundation grants DMS-8807338 and INT-8918502 相似文献
29.
Summary Motivated by different mean value properties, the functional equationsf(x) – f(y)/x–y=[(x, y)], (i)xf(y) – yf(x)/x–y=[(x, y)] (ii) (x y) are completely solved when, are arithmetic, geometric or harmonic means andx, y elements of proper real intervals. In view of a duality between (i) and (ii), three of the results are consequences of other three.The equation (ii) is also solved when is a (strictly monotonic) quasiarithmetic mean while the real interval contains 0 and when is the arithmetic mean while the domain is a field of characteristic different from 2 and 3. (A result similar to the latter has been proved previously for (i).) 相似文献
30.
The dynamical system approach is applied to the study of dynamics of multidimensional cosmological models with topology FRW ×T
D (D-dimensional torus) in the presence of high-temperature quantum effects. The stability methods developed in the paper of Szydowski (Gen. Rel. Grav.,20, 221, 1988) are used in the analysis of typical states of the metric in the neighborhood of singularities and for large time values. The problems of dynamical dimensional reduction, structure of singularities, isotropization, etc., are discussed in this context. 相似文献