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Caio L. Firme Andrei V. Grafov Marcos L. Dias 《Journal of polymer science. Part A, Polymer chemistry》2005,43(18):4248-4259
Ethylene and propylene polymerization using Ind2ZrCl2 and Ind2Zr(CH3)2/MAO catalytic systems modified by the sterically demanding bridged alicyclic alcohols, adamantan‐1‐ol, adamantan‐2‐ol, 2‐methyladamantan‐2‐ol, and fenchyl alcohol, was investigated. Lower alcohols like isopropanol completely deactivate the system, whereas in the case of catalysts modified by these voluminous alcohols only a slight decrease in the catalytic activity proportional to alcohol/metallocene molar ratio was observed. The addition of the modifiers gives rise to polymers with higher molecular weights than the nonmodified systems, but no structural changes in the polyethylenes were observed. The addition of the sterically demanding alcohols to the reaction medium changes the regioregularity of polypropylenes, but does not significantly influence their stereoregularity, at 30 °C. Propylene–ethylene copolymers containing up to 8.6% of ethylene units derived from 1,3‐insertion and significant amount of rr‐centered pentads were obtained by single‐monomer polymerization of propylene with Ind2ZrCl2/MMAO/adamantan‐1‐ol, at 70 °C. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4248–4259, 2005 相似文献
154.
A reverse flow injection spectrophotometric enzymatic method is proposed to quantify total phenols in urine samples. The polyphenol oxidase (PPO; EC 1.14.18.1) obtained as a crude extract from sweet potato root (Ipomoea batatas) was used as enzymatic catalyze. The detection limit, the sample throughput and relative standard deviation were 7.7 mg l−1 of total phenols, 49 h−1 and 0.9%, respectively. The method was applied to real samples and a recovery study was carried out in order to its validation. 相似文献
155.
The Compartmentalised Knapsack Problem (CKP) is similar to the ordinary Knapsack Problem except that items to be packed belong to separate classes, and items can only be packed, in knapsack compartments, amongst items in their own class. This paper addresses a case study in the cutting of steel rolls in which the CKP arises. The rolls are cut in two-phases: the first phase produces sub-rolls (compartments) which are, after reducing the thickness, cut in a second phase to produce ribbons (a class consists of ordered items with the same thickness). Finally, two methods of solving CKP are presented, and these are used to generate columns in the classical linear optimisation model of Gilmore and Gomory. Results of computational experiments are presented. 相似文献
156.
A. Fernández‐Torres P. Posadas A. Marcos‐Fernández A. Rodríguez L. González 《Journal of Polymer Science.Polymer Physics》2007,45(5):544-556
An experimental approach based on the freezing‐point depression of a solvent in a swollen gel has been developed to characterize the structure of rubber networks. This property depends on the conditions required for the formation of crystalline nuclei, which are limited by the elastomer network restrictions. Information about the functionality, spatial distribution, and number of crosslinks can be obtained by the use of this easy and ready experimental method. Application of the tube model of rubber elasticity in the uniaxial stress–strain experiments of natural rubber samples vulcanized with dicumyl peroxide yields the characteristic parameters of the rubber networks, which are in concordance with the network structures predicted by the freezing point method. Finally influence of vulcanization conditions in network structure and its relationship with the mechanical properties was evaluated. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 544–556, 2007 相似文献
157.
Carolyn M. Sofka Richard C. Semelka Hani B. Marcos John T. Woosley 《Magnetic resonance imaging》1997,15(10):1205-1208
The MR findings in a 32-year-old man with pancreatic VIPoma and liver metastases are described. A 2-cm mass was present in the region of the tail of the pancreas that was best shown on T1-weighted fat-suppressed images as a low-signal intensity mass. Multiple liver metastases were present that showed intense peripheral ring enhancement on immediate post gadolinium spoiled gradient echo images. 相似文献
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159.
It has been shown by Trudinger and Moser that for normalized functions u of the Sobolev space ??1, N (Ω), where Ω is a bounded domain in ?N, one has ∫Ω exp(αN|u|N/(N ? 1))dx ≤ CN, where αN is an explicit constant depending only on N, and CN is a constant depending only on N and Ω. Carleson and Chang proved that there exists a corresponding extremal function in the case that Ω is the unit ball in ?N. In this paper we give a new proof, a generalization, and a new interpretation of this result. In particular, we give an explicit sequence that is maximizing for the above integral among all normalized “concentrating sequences.” As an application, the existence of a nontrivial solution for a related elliptic equation with “Trudinger‐Moser” growth is proved. © 2002 John Wiley & Sons, Inc. 相似文献
160.
Marcela Cecilia González-Araya Luís Alberto Duncan Rangel Marcos Pereira Estellita Lins Luiz Flávio Autran Monteiro Gomes 《Annals of Operations Research》2002,116(1-4):271-288
This paper presents an application of the UTA method for building utility functions for the evaluation criteria defined by the Staff Evaluation Commission (CAD) of the Rio de Janeiro Federal University (UFRJ). Every year, the CAD-UFRJ gives the staff evaluation results for each Postgraduate Engineering Programme. However, the method used to generate the staff evaluation is assumed unknown. Trying to find the CAD-UFRJ preference structure, the evaluation results supplied by CAD-UFRJ are used to apply the UTA method. Some additional information obtained from the CAD-UFRJ data is incorporated in the optimal solutions analysis. 相似文献