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71.
Some algebraic structures determined by the class (þ) of all effects of a Hilbert space þ and by some subclasses of (þ) are investigated, in particular de Morgan-Brouwer-Zadeh posets [it is proved that (þ
n
)(n<) has such a structure], Brouwer-Zadeh
*
posets (a quite trivial example consisting of suitable effects is given), and Brouwer-Zadeh
3
posets which are both de Morgan and
*.It is shown that a nontrivial class of effects of a Hilbert space exists which is a BZ
3
poset. An -preclusivity relation on the set of all vectors of þ is introduced, and it is shown that it satisfies the regularity condition also for [1/2, 1]. 相似文献
72.
Roberto Conti 《Letters in Mathematical Physics》1995,35(3):237-250
In a theory of local field algebras satisfying the split property, we introduce an algebra generated by the local energy-momentum operators obtained from the canonical local implementation of translations, and possibly by the local charges operators. We discuss the relations of this algebra to the given algebra of local observables and take some steps toward the characterization of theories where they coincide. In the presence of spontaneously broken symmetries, we present a no-go theorem. 相似文献
73.
Mohammad R. Ahmady Roberto R. Mendel 《Zeitschrift fur Physik C Particles and Fields》1995,65(2):263-265
The decay rates for the exclusiveB decaysBK
c
andBK*
c
are calculated in the context of the heavy quark effective theory. We obtain(BK
c
)/ (BK)=1.6±0.2 and(BK*
c
)/ (K*)=0.39±0.04. These results lead to estimates BR(BK
c
)=(0.11±0.02)% and BR(BK*
c
)=(0.05±0.01)% if we use the central current experimental values forB(K, K
*) branching ratios. 相似文献
74.
Roberto Zucchini 《Communications in Mathematical Physics》1996,181(3):529-568
A lagrangian euclidean model of Drinfeld-Sokolov (DS) reduction leading to generalW-algebras on a Riemann surface of any genus is presented. The background geometry is given by the DS principal bundleK associated to a complex Lie groupG and anSL(2,) subgroupS. The basic fields are a hermitian fiber metricH ofK and a (0, 1) Koszul gauge fieldA
* ofK valued in a certain negative graded subalgebrar ofg related tos. The action governing theH andA
* dynamics is the effective action of a DS field theory in the geometric background specified byH andA
*. Quantization ofH andA
* implements on one hand the DS reduction and on the other defines a novel model of 2d gravity, DS gravity. The gauge fixing of the DS gauge symmetry yields an integration on a moduli space of DS gauge equivalence classes ofA
* configurations, the DS moduli space. The model has a residual gauge symmetry associated to the DS gauge transformations leaving a given fieldA
* invariant. This is the DS counterpart of conformal symmetry. Conformal invariance and certain non-perturbative features of the model are discussed in detail. 相似文献
75.
Roberto Pignoni 《Geometriae Dedicata》1993,45(3):263-287
We study some global projective properties of real plane curves with cusps, beaks and normal crossings. Starting from Fabricius-Bjerre's formula on the singularities of a curve in an affine plane, we describe its extension to a projective setting. Given a curve RP2, by fixing a base point we associate some indices to its singularities and double tangents. We prove two global relations linking these entities together. 相似文献
76.
Natalini B Marinozzi M Sardella R Macchiarulo A Pellicciari R 《Journal of chromatography. A》2004,1033(2):363-367
The chromatographic resolution of enantiomeric amino acids is accomplished on a reversed phase column using aqueous mobile phase containing the chiral reagent N,N-dimethyl-S-phenylalanine-Cu(II). The separation is a result of the whole interaction between the diastereomeric complex surface and the mixed stationary phase realized by the dynamic coating of the RP-18 carbon chains layer. The elution order seems to be related to the different water coordination capability on copper ion in the formation of the mixed ternary complexes. 相似文献
77.
José Roberto Caetano da RochaLúcio Angnes Mauro Bertotti Koiti ArakiHenrique Eisi Toma 《Analytica chimica acta》2002,452(1):23-28
The modification of a glassy carbon surface by coating with an electrostatically assembled film of tetraruthenated cobalt porphyrin/(meso-tetra(4-sulphonatephenyl)porphyrinate zinc(II) yields an indicator electrode that allows the determination of nitrite to be performed with a limit of detection of 0.1 μM in a flow injection configuration. The dynamic range extends up to 1000 μM and the repeatability of the measurements was evaluated to be 1.5% with a throughput of 50 samples per hour. The efficiency of the bilayered film to mediate the electron transfer allows the determinations to be performed at a less positive potential (+0.75 V) with enhanced sensitivity. The coating also prevents the surface poisoning and its stability is maintained over several weeks. The same detector was used for determination of nitrate after reduction to nitrite in a reductor column containing copperised cadmium. This method was used for the determination of nitrate and nitrite in mineral water, saliva and cured meats, the results being in agreement with certified values and those obtained by using recommended procedures. 相似文献
78.
Alonso AM Horcajada R Motevalli M Utley JH Wyatt PB 《Organic & biomolecular chemistry》2005,3(15):2842-2847
Radical-anions, electrochemically generated in aprotic solvent from C(2) symmetric homochiral phenazine derivatives, act as chiral electrogenerated bases (EGBs) in the desymmetrisation by selective deprotonation of a prochiral epoxide (3,4-epoxy-2,3,4,5-tetrahydrothiophene-1,1-dioxide); the anion produced is trapped by mesitoic anhydride. The phenazines may be recovered in high yield by air oxidation. Enantiomeric excesses are modest (8-34%) but this is to our knowledge the first demonstration of such stereoselective electrochemically-initiated deprotonation. The reactivity of phenazine radical-anions as EGBs has also been explored by measurements of the rates of proton transfer; the prochiral epoxide was found to have a kinetic acidity similar to that of the methyltriphenylphosphonium cation. 相似文献
79.
Tedesco E Della F Favaretto L Barbarella G Albesa-Jové D Pisignano D Gigli G Cingolani R Harris KD 《Journal of the American Chemical Society》2003,125(40):12277-12283
The "rigid-core" material 3,5-dimethyl-2,3'-bis(3-methylthiophene)-dithieno[3,2-b:',3'-d]thiophene-4,4-dioxide (DTTOMe4) has the highest photoluminescence ever reported for thiophene-based molecules in the solid state. We report the structure of this material, determined directly from powder X-ray diffraction data using the Genetic Algorithm method for structure solution, followed by Rietveld refinement, and the structural properties are discussed in relation to the structures of the corresponding subsystems DTTO and DTTOMe. While the crystal structures of the latter compounds contain cofacial dimers, the crystal structure of DTTOMe4 comprises layers of molecules aligned in an antiparallel fashion. Intermediate neglect of differential overlap with single configuration interaction (INDO/SCI) calculations on the intermolecular interactions in the three crystal structures show that the different solid-state photoluminescence efficiencies of DTTOMe4, DTTOMe, and DTTO cannot be correlated with the different types of dipole-dipole alignment in the solid state. Instead, photoluminescence efficiencies correlate well with the rate of formation of nonradiatively decaying charge-transfer pairs upon photoexcitation. Because of larger intermolecular distances in DTTOMe4, the photoluminescence is less effectively quenched by charge-transfer processes than in DTTOMe and DTTO. 相似文献
80.
A new method was developed for the determination of 2-furfural (2-F) and 5-methylfurfural (5-MF), two products of Maillard reaction in vinegar, with head-space solid-phase microextraction (HS-SPME) coupled to gas chromatography-mass spectrometry (GC-MS). A divinylbenzene (DVB)/carboxen (CAR)/polydimethylsiloxane (PDMS) fibre was used and SPME conditions were optimised, studying ionic strength effect, temperature effect and adsorption time. Both analytes were determined by calibration established on 2-furfural-d4 (2-F-d4). The method showed good linearity in the range studied (from 16 to 0.12 mg/l), with a regression coefficient r2 of 0.9999. Inter-batch precision and accuracy were found between 14.9 and 6.0% and between -11.7 and 0.2%, respectively. Detection limit was 15 microg/l. The method is simple and accurate and it has been applied to a series of balsamic and non-balsamic vinegars. 相似文献