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141.
Substituted polythiophene and triethylenglycolpyrrolidino-C(60) blends are examined by time-resolved electron paramagnetic resonance (TR-EPR) at different temperatures. TR-EPR spectra recorded on the microsecond time scale after a short laser pulse are assigned to polythiophene and fullerene radical ion pairs, generated by electron transfer from the excited state of polythiophene to fullerene. At low temperatures, TR-EPR spectra show polarized lines with an antiphase emission/absorption pattern. The origin of the polarization pattern is described in the frame of spin correlated radical pair theory, in which two unpaired electron spins (on radical cation and anion, respectively) interact through isotropic spin exchange and anisotropic dipolar interactions. The polarization pattern is accounted for assuming a singlet excited state as the precursor of the charge-separated state. Spectral simulations yield dipolar and spin exchange coupling constants between unpaired electrons of the radical ion pair. Their values correspond to a mean distance between opposite charges of 22 A. When the temperature is increased, the spectra gradually loose their antiphase character and eventually consist of a signal totally in emission. This behavior is explained by a polarization mechanism involving a spin-selective charge recombination (ST(-1) mixing). The polarization pattern at different temperatures is examined in detail, and its generating mechanism is discussed. 相似文献
142.
Agnusdei M Bandini M Melloni A Umani-Ronchi A 《The Journal of organic chemistry》2003,68(18):7126-7129
A simple multistep synthetic strategy to 4-substituted 1,2,3,4-tetrahydro-beta-carboline and 1,3,4,9-tetrahydro-pyrano[3,4-b]indole derivatives starting from commercially available indole 2-carboxylic acid (5) is described. The final intramolecular Michael addition promoted by catalytic amount of InBr(3) (5-10 mol %) provided the expected polycyclic compounds in excellent yields (up to 97%) both in anhydrous organic and aqueous media. 相似文献
143.
André Begouen-Demeaux Gérard Villers Pierre Gibart 《Journal of solid state chemistry》1975,15(2):178-180
The system FeCrTe was investigated around the composition FeCr2Te4. FeCr2Te4 is a metastable compound. Single crystals with Fe0·93Cr1·76Te4 composition were grown by vapor transport or the Bridgman method. These crystals are metallic and anisotropic ferromagnets. 相似文献
144.
Journal of Algebraic Combinatorics - We define a new type of Golomb ruler, which we term a resolvable Golomb ruler. These are Golomb rulers that satisfy an additional “resolvability”... 相似文献
145.
Seymour (1981) proved that the cut criterion is necessary and sufficient for the solvability of the edge-disjoint paths problem when the union of the supply graph and the demand graph is planar and Eulerian. When only planarity is required, Middendorf and Pfeiffer (1993) proved the problem to be NP-complete. For this case, Korach and Penn (1992) proved that the cut criterion is sufficient for the existence of a near-complete packing of paths. Here we generalize this result by showing how a natural strengthening of the cut criterion yields better packings of paths.Analogously to Seymour's approach, we actually prove a theorem on packing cuts in an arbitrary graph and then the planar edge-disjoint paths case is obtained by planar dualization. The main result is derived from a theorem of Seb (1990) on the structure of ±1 weightings of a bipartite graph with no negative circuits.Research partially supported by the Hungarian National Foundation for Scientific Research Grants OTKA 2118 and 4271. 相似文献
146.
András Telcs 《Journal of Theoretical Probability》1995,8(1):77-96
This paper continues the study of exponentsd(x), d
(x), d
R
(x) andd
(x) for graphG; and the nearest neighbor random walk {X
n
}
nN
onG, if the starting pointX
0=x is fixed. These exponents are responsible for the geometric, resistance, diffusion and spectral properties of the graph. The main concern of this paper is the relation of these exponents to the spectral density of the transition matrix. A series of new exponentse, e
,e
R
,e
are introduced by allowingx to vary along the vertices. The results suggest that the geometric and resistance properties of the graph are responsible for the diffusion speed on the graph. 相似文献
147.
We consider the statistical properties of solutions of Burgers' equation in the limit of vanishing viscosity,
, with Gaussian whitenoise initial data. This system was originally proposed by Burgers[1] as a crude model of hydrodynamic turbulence, and more recently by Zel'dovichet al..[12] to describe the evolution of gravitational matter at large spatio-temporal scales, with shocks playing the role of mass clusters. We present here a rigorous proof of the scaling relationP(s)s
1/2,s1 whereP(s) is the cumulative probability distribution of shock strengths. We also show that the set of spatial locations of shocks is discrete, i.e. has no accumulation points; and establish an upper bound on the tails of the shock-strength distribution, namely 1–P(s)exp{–Cs
3} fors1. Our method draws on a remarkable connection existing between the structure of Burgers turbulence and classical probabilistic work on the convex envelope of Brownian motion and related diffusion processes.Inadvertently the sequel to this article, Statistical Properties of Shocks in Burgers Turbulence, II. Tail Probabilities for Velocities, Shock-Strengths and Rarefaction Intervals has already appeared in an earlier issue of Commun. Math. Phys. (Commun. Math. Phys.169, 45–59 (1995). 相似文献
148.
André LeClair 《Theoretical and Mathematical Physics》1994,98(3):297-305
We present a new application of affine Lie algebras to massive quantum field theory in 2 dimensions by investigating theq1 limit of theq-deformed affine
symmetry of the sine-Gordon theory, this limit occurring at the free fermion point. Working in radial quantization leads to a quasi-chiral factorization of the space of fields. The conserved charges which generate the affine Lie algebrasplit into two independent affine algebras on this factorized space, each with level 1 in the anti-periodic sector, and level 0 in the periodic sector. The space of fields in the anti-periodic sector can be organized using level-1 highest weight representations if one supplements the
algebra with the usual local integrals of motion. Introducing a particle-field duality leads to a new way of computing form-factors in radial quantization. Using the integrals of motion, a momentum space bosonization involving vertex operators is formulated. Form-factors are computed as vacuum expectation values of vertex operators in momentum space.Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 98. No. 3, pp. 430–441, March, 1994. 相似文献
149.
András Kroó 《Constructive Approximation》1994,10(2):197-206
In this paper we prove that given certain convex domains Δ on the plane, ε>0, andf∈C(Δ) such thatf=0 on θ2Δ={(θ2 x,θ2 y):(x,y)?Δ} (0<θ<1), a polynomialp(x, y) of the form $$p(x,y) = \sum\limits_{\theta n \leqslant k + l \leqslant n} {a_{kl} x^k y^l }$$ exists such that ∥f?p∥ C(Δ) ≤ε. The admissible convex domains include triangles and parallelograms with a vertex at the origin and sections of unit disk. 相似文献
150.