全文获取类型
收费全文 | 91篇 |
免费 | 3篇 |
专业分类
化学 | 93篇 |
物理学 | 1篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 5篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 4篇 |
2010年 | 1篇 |
2009年 | 1篇 |
2008年 | 9篇 |
2007年 | 2篇 |
2006年 | 6篇 |
2005年 | 7篇 |
2004年 | 4篇 |
2003年 | 4篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1968年 | 4篇 |
1966年 | 2篇 |
排序方式: 共有94条查询结果,搜索用时 31 毫秒
61.
A series of substituted vinylgermanes and divinylgermanes have been synthesized in moderate or high yield via two reactions of olefins and dienes catalyzed by [RuHCl(CO) (PCy3)2], i.e. germylative coupling with vinylgermanes and dehydrogenative germylation with hydrogermanes. While the former reaction can be a versatile way of regioselective synthesis of products (particularly useful for the stereoselective synthesis of germylsilylethenes), the latter could be used as a complement, especially in synthesis of germylate dioxol ethene and vinyl ethers. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
62.
Ewa Ma
ecka Bogdan Marciniec Cezary Pietraszuk A. Cameron Church Kenneth B. Wagener 《Journal of molecular catalysis. A, Chemical》2002,190(1-2):27-31
The acyclic diene metathesis (ADMET) copolymerization of divinyltetraethoxydisiloxane with 1,9-decadiene, catalyzed by RuCl2(=CHPh)(PCy3)2, is the first example of a siloxylene–vinylene–alkenylene copolymer reported in the literature. This copolymer was isolated and characterized by 1H, and 13C NMR spectroscopy and GPC analysis (Mn=18 000, PDI=2.9). 相似文献
63.
Ohne Zusammenfassung 相似文献
64.
Catalytic, synthetic, and analytical investigations of the hydrosilylation of vinyltri(chloro, methyl)silanes by tri(chloro, methyl)silanes in the presence of palladium phosphine complexes show the process to occur giving mostly 1,2-bis(silyl)ethanes (β-adducts) except in the case of all chloro substituents at both silicons of the substrates. The latter reaction was reported earlier [3] to give selectively 1,1-bis(trichlorosilyl)ethane (α-adduct). All results allow to propose a general scheme of the mechanism of catalysis of vinylsilane hydrosilylation by palladium phosphine complexes. 相似文献
65.
66.
Barbara Marciniec M. Kozak Katarzyna Dettlaff 《Journal of Thermal Analysis and Calorimetry》2004,77(1):305-317
Four azole derivatives showing antimycotic activity (Miconazole, Ketoconazole, Clotrimazole, Fluconazole) in solid phase were
exposed to beta irradiation at the dose of 20-200 kGy and then alterations in the physicochemical properties of the above
derivatives were studied using the methods: scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and
X-ray diffraction (XRD) analysis. It was found that the compounds irradiated with sterilising doses (20-50 kGy) showed no
significant alterations in their physicochemical properties, while application of doses >50 kGy resulted in small changes
in the X-ray diffraction patterns and in the course of DSC curves, including a decrease in the melting points and enthalpy
of the process. For Miconazole and Fluconazole, a linear and relatively strong correlation was found (from r =0.9782 to r =0.9003) between the size of the dose of irradiation and the decrease in the melting point and enthalpy value.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
67.
Bogdan Marciniec Hieronim Maciejewski Karol Szubert Magdalena Kurdykowska 《Monatshefte für Chemie / Chemical Monthly》2006,137(5):605-611
Summary. The hydrosilylation of 1-heptene, allyl glycidyl ether and, allyl polyether by heptamethylhydrotrisiloxane and poly(hydro,
methyl)(dimethyl)siloxane catalyzed by rhodium(I) complexes (particularly [{Rh(μ–OSiMe3)(cod)}2]) in imidazolium ionic liquids (especially [TriMIM]MeSO4) gives heptyl and glycidyloxy functional (poly)siloxanes and silicone polyethers with high yield and selectivity. The catalytic
system based on rhodium siloxide can be easily separated from the product and successfully reused up to five times. 相似文献
68.
Itami Y Marciniec B Kubicki M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(5):1239-1248
Functionalization of octavinylsilsesquioxane (Vi(8)T(8), 1) by two reactions catalyzed by ruthenium complexes is reported: a silylative coupling reaction catalyzed by [RuHCl(CO)(PCy(3))(2)] (I) and cross-metathesis catalyzed by first- (II) and second-generation (III) Grubbs' catalysts. The two reactions of 1 with styrene take place highly regio- and stereoselectively (the X-ray structure of the product 2 has also been obtained); the cross-metathesis of 1-hexene and allyltrimethylsilane occurs quite effectively, whereas the silylative coupling with these compounds gives a mixture of isomers. Functionalization of 1 with heteroatom-substituted vinyl derivatives (Si, O, N) by silylative coupling reaction has been found to be highly efficient, but cross-metathesis appears to be the more effective method for the synthesis of S-substituted vinyl-silsesquioxane. 相似文献
69.
Wojciech Duczmal Bogdan Marciniec Elżbieta Śliwińska Wlodzimierz Urbaniak 《Transition Metal Chemistry》1989,14(6):407-410
Summary A promoting role of an oxidant, present in commercial 1-hexene, in the substitution of phosphine in the complex [RhCl(COD)(phosphine)] (1) where the phosphine is PPh3 or 1/2 BPS-2 [bis(diphenylphosphinoethyl)tetra-methyldisiloxane] and COD=cycloocta-1,5-diene, has been detected and explained. When [oxidant]>[(1)] two reaction steps are distinguished: an oxidation of phosphine to phosphine oxide with generation of [RhCl(COD)], followed by its fast dimerization, and an oxidation of the dimer to RhIII species. When [oxidant]<[(1)] the latter step is not observed and the reaction of [RhCl(COD)] with 1-hexene is favoured, particularly when an excess of phosphine (even at high oxidant concentration) is present. Most rate constants of the individual steps were evaluated. 相似文献
70.
Marciniec B. Kozak M. Ogrodowczyk M. 《Journal of Thermal Analysis and Calorimetry》2004,77(2):581-596
The effect of sterilisation by irradiation has been studied for the seven most often used in medicine derivatives of 1,4-dihydropyridine
(nifedipine, nisoldipine, nicardipine, nitrendipine, nimodipine, felodipine and amlodipine). The sterilisation was performed
for the compounds in the solid phase with an electron beam of the energy 10 MeV, at room temperature, using the irradiation
doses from 20 to 400 kGy. The effects of the irradiation were studied by the methods SEM, DSC, XRD and TLC. The sterilisation
with doses 20-100 kGy was found to cause no changes in the physico-chemical properties of the compounds, while the irradiation
with higher doses (200-400 kGy) was found to induce changes in the colour, DSC spectrum and TLC picture. As follows from the
TLC results, the main product of radiolysis of the compounds studied was a pyridine nitrozoderivative, which indicates the
same mechanism of decomposition as in the process of photodegradation. The results prove that the 1,4-dihydropyridine derivatives
being highly sensitive to visible and UV radiation are generally resistant to ionising radiation and thus can be subjected
to sterilisation by irradiation.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献