A cyclic hexacopper(II) fluoro complex that encapsulates two fluoride anions

The complex [[Cu3(HpztBu)4(mu-pztBu)2(mu-F)2(mu 3-F)]2]F2 (HpztBu = 3[5]-tert-butylpyrazole) has a cyclic, C2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three HpztBu ligands.     

Phase-object analysis with a speckle interferometer

We describe the characteristics of a double-exposure specklegram obtained through a double-aperture system, by introduction of a wedge in front of one aperture in one exposure. It is assumed that a uniform displacement of the diffuser is produced between exposures. The average intensity distribution and visibility of the interferometric fringes in the Fourier plane are analyzed. An alternative interferometric technique for phase-object detection is proposed.     

A correction algorithm for undersampled images using dynamic segmentation and entropy based focus criterion

A post-processing technique is presented for correcting images undersampled in k-space. The method works by taking advantage of the image's background zeros (dynamically segmented through the application of a threshold) to extrapolate the missing k-space samples. The algorithm can produce good quality images from a small set of k-space frequencies with only a few iterations of simple matrix operations, using the image entropy as the focus criterion. It does not require any special patient preparation, extra pulse sequences, complex gradient programming or specialized hardware. This makes it a good candidate for any application that requires short scan times or where only few frequencies can be sampled.     

Noise- and inertia-induced inhomogeneity in the distribution of small particles in fluid flows

The dynamics of small spherical neutrally buoyant particulate impurities immersed in a two-dimensional fluid flow are known to lead to particle accumulation in the regions of the flow in which vorticity dominates over strain, provided that the Stokes number of the particles is sufficiently small. If the flow is viewed as a Hamiltonian dynamical system, it can be seen that the accumulations occur in the nonchaotic parts of the phase space: the Kolmogorov-Arnold-Moser tori. This has suggested a generalization of these dynamics to Hamiltonian maps, dubbed a bailout embedding. In this paper we use a bailout embedding of the standard map to mimic the dynamics of neutrally buoyant impurities subject not only to drag but also to fluctuating forces modeled as white noise. We find that the generation of inhomogeneities associated with the separation of particle from fluid trajectories is enhanced by the presence of noise, so that they appear in much broader ranges of the Stokes number than those allowing spontaneous separation. (c) 2002 American Institute of Physics.     

Imaging the neural circuitry and chemical control of aggressive motivation

Background  

With the advent of functional magnetic resonance imaging (fMRI) in awake animals it is possible to resolve patterns of neuronal activity across the entire brain with high spatial and temporal resolution. Synchronized changes in neuronal activity across multiple brain areas can be viewed as functional neuroanatomical circuits coordinating the thoughts, memories and emotions for particular behaviors. To this end, fMRI in conscious rats combined with 3D computational analysis was used to identifying the putative distributed neural circuit involved in aggressive motivation and how this circuit is affected by drugs that block aggressive behavior.     

A Semigroup Crossed Product Arising in Number Theory

Recently Bost and Connes have studied an interesting C*-algebraicHecke algebra arising in number theory. Here it is shown thatthis algebra can be realised as a semigroup crossed product,and be profitably studied using methods developed by the authorsfor analysing Toeplitz algebras. One main result is a characterisationof faithful representations of the Hecke algebra.     

Soil delta15N patterns in old-growth forests of southern Chile as integrator for N-cycling

Old-growth forests of southern Chile represent an important reserve of temperate (rain) forests in the world. Wetter and colder forest ecosystems appear to be more efficient in conserving and recycling N such that mostly non-plant available N species are lost, which could be indicated by more depleted delta15N values of the soil and plants. Hydrological N loss from the old-growth forests in southern Chile occurs mainly via dissolved organic nitrogen and not via dissolved inorganic N. Forest disturbances (e.g. fire, clear-cutting or enhanced N deposition) cause (abrupt) changes in ecosystem N-cycling processes. In this study, we hypothesized that delta15N signatures of soil profiles under old-growth forests could be used as an integrator for ecosystem N-cycling, and changes of these delta15N profiles could be valuable to assess ecosystem resilience towards disturbances. Six old-growth forests were selected in the phytogeographical region of the Valdivian rain forest in southern Chile. One of the sites has been partly burned in February 2002. First, we observed that ecosystems with higher mean annual precipitation and lower mean annual temperature were relatively more depleted in 15N. Secondly, we found that a forest fire caused a 100-fold increase of the nitrate export and induced an enrichment of the soil delta15N signal in the upper 20 cm.     

A Bernstein type theorem on a Randers space

We consider Finsler spaces with a Randers metric F=+, on the three-dimensional real vector space, where is the Euclidean metric and is a 1-form with norm b,0 b1. By using the notion of mean curvature for immersions in Finsler spaces, introduced by Z. Shen, we obtain the partial differential equation that characterizes the minimal surfaces which are graphs of functions. For each b, 0 b1/, we prove that it is an elliptic equation of mean curvature type. Then the Bernstein type theorem and other properties, such as the nonexistence of isolated singularities, of the solutions of this equation follow from the theory developped by L. Simon. For b 1/, the differential equation is not elliptic. Moreover, for every b, 1/b1 we provide solutions, which describe minimal cones, with an isolated singularity at the origin.Partially supported by CAPES/PROCAD.Partially supported by NSF grant DMS-0072242.Partially supported by CNPq and CAPES/PROCAD.     

Existence and asymptotic stability for evolution problems on manifolds with damping and source terms

One considers the nonlinear evolution equation with source and damping terms

     

Application of vernier thinning techniques to segmented annular arrays

Due to the aperture periodicity, the inter-element spacing of two-dimensional squared arrays is maintained near lambda/2 in order to avoid grating lobes. This condition gives rise to severe problems derived from the huge number of array elements and from their little size that causes the signal to noise ratio to bring down. Vernier techniques have been proposed to lower the number of active elements, but the drastic reduction of the ultrasonic energy is still a great problem for the image contrast. In this work, vernier techniques for segmented annular (SA) arrays are theoretically studied. SA arrays produce lower grating lobes than squared arrays and, therefore, allow the element size to be increased beyond the lambda/2 constraint. Using larger elements, SA arrays have advantage to squared arrays because they have larger active area and smaller thinning order for the same complexity (number of channels) of the image system. Theoretical results of the vernier techniques applied to SA arrays in both radial and tangential directions are presented and compared with the equivalent squared array.