Optical sensing in microfluidic lab-on-a-chip by femtosecond-laser-written waveguides

We use direct femtosecond laser writing to integrate optical waveguides into a commercial fused silica capillary electrophoresis chip. High-quality waveguides crossing the microfluidic channels are fabricated and used to optically address, with high spatial selectivity, their content. Fluorescence from the optically excited volume is efficiently collected at a 90° angle by a high numerical aperture fiber, resulting in a highly compact and portable device. To test the platform we performed electrophoresis and detection of a 23-mer oligonucleotide plug. Our approach is quite powerful because it allows the integration of photonic functionalities, by simple post-processing, into commercial LOCs fabricated with standard techniques. Figure Femtosecond laser written waveguides can selectively excite fluorescence in a microfluidic channel of a commercial lab-on-a-chip. A compact scheme for on-chip detection by laser induced fluorescence is applied to capillary electrophoresis of a 23-mer Cy3-labeled oligonucleotide     

Finite-temperature infinite matter with effective-field-theory-inspired energy-density functionals

The European Physical Journal A - We investigate $$J/\psi $$ decays into octet baryon–antibaryons pairs. The decay amplitudes are computed within the collinear QCD factorisation framework....     

Hybrid Polyoxotungstates as Functional Comonomers in New Cross‐Linked Catalytic Polymers for Sustainable Oxidation with Hydrogen Peroxide

Anchoring terminal octenyl tails on molecular polyoxotungstates yield polymerizable organic–inorganic monomers with formula [{CH₂?CH(CH₂)₆Si}_xO_ySiW_wO_z]^4? [x=2, w=11, y=1, z=39 ( 1 ); x=2, w=10, y=1, z=36 ( 2 ); and x=4, w=9, y=3, z=34 ( 3 )]. These molecular hybrids can use aqueous hydrogen peroxide to catalyze the selective oxidation of organic sulfides in CH₃CN. Copolymerization of 1 – 3 with methyl methacrylate and ethylene glycol dimethacrylate leads to porous materials with a homogeneous distribution of the functional monomers, as indicated by converging evidence from FTIR spectroscopy and electronic microscopy. The catalytic polymers activate hydrogen peroxide for oxygen transfer, as demonstrated by the quantitative and selective oxidation of methyl p‐tolyl sulfide, which was screened as model substrate. The hybrid material containing monomer 2 was also tested in n‐octane to evaluate its potential for the oxidation and removal of dibenzothiophene, a well‐known gasoline contaminant.     

Local Unit Roots and Global Stationarity of TARMA Models

In this paper the (strict and weak) stationarity of threshold autoregressive moving average models is discussed. After examining the strict stationarity, mainly based on the random coefficient autoregressive representation of the model, we provide sufficient conditions for its weak stationarity that allow to obtain a wider stationarity region with respect to some previous results given in the literature. These conditions are discussed to distinguish between global and local stationarity, whose relation has been considered in detail. The threshold process has been further evaluated to face the problem related to the so called existence of a threshold structure in the data generating process that is strictly related to the stationarity and has significant relevance when the parameters of the model have to be estimated.     

7‐Chloro‐3,6‐di­methyl‐1H‐indene‐2‐carb­aldehyde

In the crystal structure of C₁₂H₁₁ClO, the (planar) mol­ecules give rise to a parallel packing. A model crystal obtained by semi‐empirical and packing‐energy calculations is consistent with the observed structure.     

催化膜和催化膜反应器:整合的高效和环保催化过程

 The design of new heterogeneous photooxygenation systems able to employ visible light, oxygen, mild temperatures, and solvent with a low environmental impact has been investigated. In particular, the heterogenization of decatungstate (W10O4-32), a polyoxometalate with photocatalytic activity in oxidation reactions, has been carried out in polymeric membranes of polyvinylidenefluoride. The polymeric catalytic membranes prepared by phase inversion technique have been successfully applied in the aerobic mineralization of phenol in water, which was used as an example of organic pollutant. In order to evaluate the effect of the polymeric environment on the overall catalyst behavior, we have also heterogenized the decatungstate (opportunely functionalized) in perfluorinated membrane made of Hyflon. The photocatalytic composite membranes are characterized by different and tuneable properties depending on the nature of the polymeric micro-environment, in which the catalyst is confined. Moreover, the selective separation function of the membrane results in enhanced performance in comparison with homogeneous reactions.     

Investigating halo substructures with annual modulation signature

Galaxy hierarchical formation theories, numerical simulations, the discovery of the Sagittarius Dwarf Elliptical Galaxy (SagDEG) in 1994 and more recent investigations suggest that the dark halo of the Milky Way can have a rich phenomenology containing non-thermalized substructures. In the present preliminary study, we investigate the case of the SagDEG (the best known satellite galaxy in the Milky Way crossing the solar neighborhood) analyzing the consequences of its dark matter stream contribution to the galactic halo on the basis of the DAMA/NaI annual modulation data. The present analysis is restricted to some WIMP candidates and to some of the astrophysical, nuclear and particle physics scenarios. Other candidates such as e.g. the light bosonic ones we discussed elsewhere, and other non-thermalized substructures are not yet addressed here. PACS 95.35.+d