Probing Ag nanoparticle surface oxidation in contact with (in)organics: an X‐ray scattering and fluorescence yield approach

Characterizing interfacial reactions is a crucial part of understanding the behavior of nanoparticles in nature and for unlocking their functional potential. Here, an advanced nanostructure characterization approach to study the corrosion processes of silver nanoparticles (Ag‐Nps), currently the most highly produced nanoparticle for nanotechnology, is presented. Corrosion of Ag‐Nps under aqueous conditions, in particular in the presence of organic matter and halide species common to many natural environments, is of particular importance because the release of toxic Ag⁺ from oxidation/dissolution of Ag‐Nps may strongly impact ecosystems. In this context, Ag‐Nps capped with polyvinolpyrrolidone (PVP) in contact with a simple proxy of organic matter in natural waters [polyacrylic acid (PAA) and Cl^? in solution] has been investigated. A combination of synchrotron‐based X‐ray standing‐wave fluorescence yield‐ and X‐ray diffraction‐based experiments on a sample consisting of an approximately single‐particle layer of Ag‐Nps deposited on a silicon substrate and coated by a thin film of PAA containing Cl revealed the formation of a stable AgCl corrosion product despite the presence of potential surface stabilizers (PVP and PAA). Diffusion and precipitation processes at the Ag‐Nps–PAA interface were characterized with a high spatial resolution using this new approach.     

Observation of phase defects in quasi-two-dimensional Bose-Einstein condensates

We have observed phase defects in quasi-2D Bose-Einstein condensates close to the condensation temperature. Either a single or several equally spaced condensates are produced by selectively evaporating the sites of a 1D optical lattice. When several clouds are released from the lattice and allowed to overlap, dislocation lines in the interference patterns reveal nontrivial phase defects.     

Replica Bounds by Combinatorial Interpolation for Diluted Spin Systems

In two papers Franz et al. proved bounds for the free energy of diluted random constraints satisfaction problems, for a Poisson degree distribution (Franz and Leone in J Stat Phys 111(3–4):535–564, 2003) and a general distribution (Franz et al. in J Phys A 36(43), 10967, 2003). Panchenko and Talagrand (Probab Theo Relat Fields 130(3):319–336, 2004) simplified the proof and generalized the result of Franz and Leone (J Stat Phys 111(3–4):535–564, 2003) for the Poisson case. We provide a new proof for the general degree distribution case and as a corollary, we obtain new bounds for the size of the largest independent set (also known as hard core model) in a large random regular graph. Our proof uses a combinatorial interpolation based on biased random walks (Salez in Combin Probab Comput 25(03):436–447, 2016) and allows to bypass the arguments in Franz et al. (J Phys A 36(43):10967, 2003) based on the study of the Sherrington–Kirkpatrick (SK) model.     

Structure of optimal transport networks subject to a global constraint

The structure of pipe networks minimizing the total energy dissipation rate is studied analytically. Among all the possible pipe networks that can be built with a given total pipe volume (or pipe lateral surface area), the network which minimizes the dissipation rate is shown to be loopless. Furthermore, such an optimal network is shown to contain at most N-2 nodes in addition to the N sources plus sinks that it connects. These results are valid whether the possible locations for the additional nodes are chosen freely or from a set of nodes (such as points of a grid). Applications of these results to various physical situations and to the efficient computation of optimal pipe networks are also discussed.     

Random walks generated by affine mappings

This article is concerned with Markov chains on ^m constructed by randomly choosing an affine map at each stage, and then making the transition from the current point to its image under this map. The distribution of the random affine map can depend on the current point (i.e., state of the chain). Sufficient conditions are given under which this chain is ergodic.     

Torsional-flexural waves in thin-walled open beams

A one-dimensional theory is developed for coupled torsional-flexural waves in thin-walled elastic beams of arbitrary open cross-section. Complex kinematical effects are fully taken into account with an emphasis on consistency. Exact equations of motion are obtained in terms of generalized stresses and generalized displacements defined by an averaging procedure. Constitutive relations accounting for flexural-torsional couplings are proposed. They include and generalize the static laws of strength of materials. General features of the dispersion are analyzed. This theory is applied to the case of a standard angle-section of which the dispersion curves are given.     

High-power laser with Nd:YAG single-crystal fiber grown by the micro-pulling-down technique

We present optical characterization and laser results achieved with single-crystal fibers directly grown by the micro-pulling-down technique. We investigate the spectroscopic and optical quality of the fiber, and we present the first laser results. We achieved a cw laser power of 10 W at 1064 nm for an incident pump power of 60 W at 808 nm and 360 kW peak power for 12 ns pulses at 1 kHz in the Q-switched regime. It is, to the best of our knowledge, the highest laser power ever achieved with directly grown single-crystal fibers.     

Nonlinear evolution of anisotropic cosmological power

There has been growing interest in the possibility of testing more precisely the assumption of statistical isotropy of primordial density perturbations. If it is to be tested with galaxy surveys at distance scales < or = 10 Mpc, then nonlinear evolution of anisotropic power must be understood. To this end, we calculate the angular dependence of the power spectrum to third order in perturbation theory for a primordial power spectrum with a quadrupole dependence on the wave vector direction. Our results suggest that primordial power anisotropies will be suppressed by < or = 7% in the quasilinear regime. We also show that the skewness in the statistically anisotropic theory differs by no more than 1% from that in the isotropic theory.     

Nanoscopic Porous Iridium/Iridium Dioxide Superstructures (15 nm): Synthesis and Thermal Conversion by In Situ Transmission Electron Microscopy

Porous particle superstructures of about 15 nm diameter, consisting of ultrasmall nanoparticles of iridium and iridium dioxide, are prepared through the reduction of sodium hexachloridoiridate(+IV) with sodium citrate/sodium borohydride in water. The water-dispersible porous particles contain about 20 wt % poly(N-vinylpyrrolidone) (PVP), which was added for colloidal stabilization. High-resolution transmission electron microscopy confirms the presence of both iridium and iridium dioxide primary particles (1–2 nm) in each porous superstructure. The internal porosity (≈58 vol%) is demonstrated by electron tomography. In situ transmission electron microscopy up to 1000 °C under oxygen, nitrogen, argon/hydrogen (all at 1 bar), and vacuum shows that the porous particles undergo sintering and subsequent compaction upon heating, a process that starts at around 250 °C and is completed at around 800 °C. Finally, well-crystalline iridium dioxide is obtained under all four environments. The catalytic activity of the as-prepared porous superstructures in electrochemical water splitting (oxygen evolution reaction; OER) is reduced considerably upon heating owing to sintering of the pores and loss of internal surface area.