全文获取类型
收费全文 | 8183篇 |
免费 | 465篇 |
国内免费 | 34篇 |
专业分类
化学 | 5847篇 |
晶体学 | 35篇 |
力学 | 257篇 |
数学 | 1408篇 |
物理学 | 1135篇 |
出版年
2023年 | 48篇 |
2022年 | 55篇 |
2021年 | 114篇 |
2020年 | 151篇 |
2019年 | 153篇 |
2018年 | 129篇 |
2017年 | 93篇 |
2016年 | 283篇 |
2015年 | 231篇 |
2014年 | 280篇 |
2013年 | 500篇 |
2012年 | 546篇 |
2011年 | 621篇 |
2010年 | 388篇 |
2009年 | 353篇 |
2008年 | 522篇 |
2007年 | 528篇 |
2006年 | 505篇 |
2005年 | 515篇 |
2004年 | 413篇 |
2003年 | 366篇 |
2002年 | 324篇 |
2001年 | 112篇 |
2000年 | 92篇 |
1999年 | 105篇 |
1998年 | 71篇 |
1997年 | 78篇 |
1996年 | 90篇 |
1995年 | 64篇 |
1994年 | 47篇 |
1993年 | 43篇 |
1992年 | 34篇 |
1991年 | 46篇 |
1990年 | 32篇 |
1989年 | 44篇 |
1988年 | 24篇 |
1986年 | 23篇 |
1985年 | 52篇 |
1984年 | 57篇 |
1983年 | 35篇 |
1982年 | 59篇 |
1981年 | 36篇 |
1980年 | 51篇 |
1979年 | 46篇 |
1978年 | 51篇 |
1977年 | 40篇 |
1976年 | 41篇 |
1975年 | 31篇 |
1974年 | 36篇 |
1973年 | 26篇 |
排序方式: 共有8682条查询结果,搜索用时 15 毫秒
51.
Nicole Fietkau Fran?ois G Chevallier Li Jiang Timothy G J Jones Richard G Compton 《Chemphyschem》2006,7(10):2162-2167
The size of a glass sphere positioned in the center of a microdisk electrode is determined by using a simple electrochemical procedure and is confirmed, additionally, by a microscopical measurement of the sphere at the time of the electrochemical measurement. The cyclic voltammetric response of the naked electrode and of the electrode with the sphere positioned in its center is recorded over a wide range of scan rates (0.002-1.5 V s(-1)). The size of the sphere is then determined by comparison of the experimental voltammogram with simulations for each individual scan rate. 相似文献
52.
53.
Thierry Boulanger Daniel P. Vercauteren Guy Evrard François Durant 《Journal of chemical crystallography》1987,17(5):561-573
The crystal structure of 2-(carboxy-3-propyl)-3-amino-6-cyclohexylpyridazinium bromide has been determined by single-crystal X-ray diffraction techniques and refined by full-matrix least squares. The compound crystallized in the tri-clinic space groupP ¯1 witha=10.275(1),b=11.215(1),c=7.082(1) Å,=91.84(1),=102.21(1), =106.77(1)°, andZ=2. FinalR-factor is 0.045. The main structural results are very similar to the ones observed for the 6-phenyl analog. These two compounds are GABA-A antagonists.Ab initio molecular orbital calculations, with STO-3G and 4-31G basis sets, suggest that the exocyclic nitrogen accurately mimics the nitrogen atom of GABA. 相似文献
54.
A density functional theory of diffusion is developed for lattice fluids with molecular flux as a functional of the density distribution. The formalism coincides exactly with the generalized Ono-Kondo density functional theory when there is no gradient of chemical potential, i.e., at equilibrium. Away from equilibrium, it gives Fick's first law in the absence of a potential energy gradient, and it departs from Fickian behavior consistently with the Maxwell-Stefan formulation. The theory is applied to model a nanopore, predicting nonequilibrium phase transitions and the role of surface diffusion in the transport of capillary condensate. 相似文献
55.
The role of search theory in the exploitation of natural resources is discussed in this paper. After a brief history and taxonomy of search problems, the mathematics of search is discussed. This includes underlying probability distributions, the differential equations of search, Bayesian use of search information and optimization problems in search theory. The theory is illustrated by applications in fisheries, pest control, animal foraging, and oil and mineral exploration. 相似文献
56.
Joyeux M 《The Journal of chemical physics》2005,122(7):074303
Vibrational energy localization and/or redistribution in hydrogen peroxide H2O2 is studied at about 4000 cm(-1) above the quantum mechanical ground state using the ab initio potential energy surface of Koput, Carter, and Handy [J. Phys. Chem. A 102, 6325 (1998)]. In this work, the recently derived canonical perturbation procedure for floppy molecules serves two purposes. First, from the quantum mechanical point of view, it is shown that the energies of the lowest 130 states are reproduced with an average error smaller than 1.5 cm(-1) by a two-dimensional Hamiltonian, which is a function of the torsion and OO-stretch coordinates and momenta, while the other four degrees of freedom contribute only through powers of good quantum numbers. Moreover, the canonical perturbation procedure is also used in classical mechanics calculations, in order to define meaningful local modes, for which the ingoing and outgoing energy flows are monitored. Almost all the individual trajectories launched on the ab initio surface display the same behavior, that is, the superposition of (a) rapid (few hundreds of femtoseconds) and quasiperiodic energy exchanges between the two OH stretches and between the torsion and OO-stretch, and (b) slower (few to several picoseconds) but erratic-looking energy flows between all degrees of freedom. When averaging over large numbers of trajectories with the same local mode energies at time t=0, one observes instead a smooth and irreversible energy flow between all degrees of freedom, which usually thermalize in the range of several tens of picoseconds, that is, on time scales larger than the 5 ps period associated with the quantum density of states. 相似文献
57.
Leonard S Van Schepdael A Iványi T Lázár I Rosier J Vanstockem M Vermeersch H Hoogmartens J 《Electrophoresis》2005,26(3):627-632
A capillary electrophoretic (CE) method was developed for the separation of diastereoisomers of a new human immunodeficiency virus (HIV) protease inhibitor TMC114. In total 16 isomers of this drug have been synthesized (eight pairs of enantiomers). We succeeded in the separation of the eight diastereoisomers, but no enantiomers could be separated. Because of the high similarity and water-insolubility of these isomers, the separation is a real challenge. Different CE modes were tried out: capillary zone electrophoresis (CZE), nonaqueous capillary electrophoresis (NACE), micellar electrokinetic capillary chromatography (MEKC), and microemulsion electrokinetic capillary chromatography (MEEKC). Only MEEKC offered resolution of these compounds. 相似文献
58.
[reaction: see text] The macrocyclic 18-diazo-1,4,7,10,13,16-hexaoxacyclononadeca-17,19-dione (3-diazo-2,4-dioxo-19-crown-6, 1) readily forms complexes with potassium (2, stability constant in methanol is K(K+) = 229 +/- 25 M(-1)) and sodium ions (3, K(Na+) = 84.2 +/- 7.9 M(-1) in methanol). According to B3LYP/6-31G+(d,p) calculations and temperature-dependent 1H NMR spectroscopy, the predominant conformation of 1 has a Z,Z arrangement of the diazo and carbonyl groups. The X-ray crystal structure analysis showed that the potassium complex (2) has the same Z,Z arrangement, while the sodium analogue (2) exists in conformation with Z,E geometry of the diazodicarbonyl moiety. Direct 254 nm photolysis of diazo compounds 1-3 in methanol results in the formation of 3-methoxy-2,4-dioxo-19-crown-6 (5), the product of the insertion of corresponding alpha,alpha'-dicarbonylcarbene into the O-H bond of the solvent. The triplet-sensitized photolysis of diazomalonates 1-3 produces 2,4-dioxo-19-crown-6 (6), which is apparently formed via the triplet state of the intervening carbene. 相似文献
59.
By means of potentiometric pH and pAg measurements, the stability constants and the stoichiometric composition of the silver(I) complexes of some N-methyl-substituted 4-H-diethylenetriamines, in aqueous medium of ionic strength 1.3 and at a temperature of 25.00 degrees , have been determined. In addition to mononuclear and polynuclear complexes, together with their protonated forms, some hydroxo complexes are formed. The values of the stability constants are discussed in terms of possible structures. 相似文献
60.
Katleen Boussu Jérémie De Baerdemaeker Charles Dauwe Marc Weber Kelvin G Lynn Diederik Depla Steliana Aldea Ivo F J Vankelecom Carlo Vandecasteele Bart Van der Bruggen 《Chemphyschem》2007,8(3):370-379
This study presents a methodology for an in-depth characterization of six representative commercial nanofiltration membranes. Laboratory-made polyethersulfone membranes are included for reference. Besides the physical characterization [molecular weight cut-off (MWCO), surface charge, roughness and hydrophobicity], the membranes are also studied for their chemical composition [attenuated total reflectance Fourier spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS)] and porosity [positron annihilation spectroscopy (PAS)]. The chemical characterization indicates that all membranes are composed of at least two different layers. The presence of an additional third layer is proved and studied for membranes with a polyamide top layer. PAS experiments, in combination with FIB (focused ion beam) images, show that these membranes also have a thinner and a less porous skin layer (upper part of the top layer). In the skin layer, two different pore sizes are observed for all commercial membranes: a pore size of 1.25-1.55 angstroms as well as a pore size of 3.20-3.95 angstroms (both depending on the membrane type). Thus, the pore size distribution in nanofiltration membranes is bimodal, in contrast to the generally accepted log-normal distribution. Although the pore sizes are rather similar for all commercial membranes, their pore volume fraction and hence their porosity differ significantly. 相似文献