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81.
V. A. Zayats A. N. Nikolaevskii T. A. Filippenko O. P. Kniga G. A. Tikhonova 《Russian Journal of Applied Chemistry》2006,79(10):1651-1654
Specific features of the initiated oxidation of polyethylene and its low-molecular-weight analogue tridecane, associated with the occurrence of the process in the short-chain mode, were studied. 相似文献
82.
V. P. Korolev 《Russian Journal of Applied Chemistry》2006,79(11):1779-1784
An equation for the standard enthalpy of solvation of a compound in a binary solvent is derived. The enthalpies of solvation in water-methanol mixtures are estimated for 1,3-propane-and 1,6-hexanediols, 1,2,4-butane-and 1,3,5-pentanetriols, 2-methoxy-and 2-propoxyethanols, and diethylene glycol. The enthalpy of solvation of 1,2-dimethoxyethane in the water-methanol mixed solvent is determined experimentally. 相似文献
83.
R. L. Moreira P. Saint-Grgoire M. Lopez M. Latour 《Journal of Polymer Science.Polymer Physics》1989,27(3):709-722
The thermal and dielectric behaviors of poly(vinylidene fluoride-trifluoroethylene) copolymers near the ferroelectric-to-paraelectric phase transition are investigated for samples with 20, 25, 30, and 40 mol% trifluoroethylene (TrFE). The data suggest that the transition becomes continuous for a particular composition near 50 mol% TrFE. Experimental data are sensitive to thermal history (kinetics of crystallization, and kinetics and cycling over the structural transition). It is found that several anomalies are present at the structural change, and in particular the 30 mol% TrFE sample shows the most marked anomalies. These phenomena can be attributed to defects, but another possibility would be the existence of an intemediate supplementary phase. Both hypotheses are discussed. 相似文献
84.
Summary High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for relatively homogeneous elements at ppm and sub-ppm level. About 40 elements could be determined with detection limits of 10 to 30 ppb. Two pattern recognition methods, principal component analysis and clustering analysis, were applied to obtain information on trace element distribution, which indicated that a number of elements were strongly spatially correlated in the analysed sample.
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
Chemische Analyse und Verteilungsbestimmung von Spurenelementen in Indium-Matrix durch Funkenquellen-Massenspektrometrie
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
85.
T. Yu. Gumerov A. F. Dobrynina R. A. Yusupov V. P. Barabanov 《Russian Journal of Applied Chemistry》2006,79(12):1935-1939
The behavior of real disperse systems with organic impurities was examined under conditions of destabilization by inorganic coagulants. A number of physicochemical methods of analysis and a simulation method were used to identify the character and type of the complexes formed and to calculate their stability constants. 相似文献
86.
Rare earths exhibit complex magnetic phase diagrams resulting from the competition between various contributions to the magnetic
energy: exchange, anisotropy and magnetostriction. The epitaxy of a rare-earth film on a substrate induces (i) a clamping
to the substrate and (ii) pseudomorphic strains. Both these effects are shown to lead to modifications of the magnetic properties
in (0 0 1)Dy, (0 0 1)Tb and (1 1 0)Eu films. In Dy and Tb films, spectacular variations of the Curie temperature have been
evidenced. Additionally, Tb films exhibit a new large wavelength magnetic modulation. In Eu films, one of the helical magnetic
domains disappears at low temperature whereas the propagation vectors of the other helices are tilted. The link between structural
and magnetic properties is underlined via magnetoelastic models. Moreover, molecular beam epitaxy permits the growth of Sm
in a metastable dhcp phase. The magnetic structure of dhcp Sm has been elucidated for the first time. In this review, neutron
scattering is shown to be a powerful technique to reveal the magnetic structures of rare-earth films. 相似文献
87.
P. V. Dvornikov 《Russian Physics Journal》2006,49(4):392-401
A standard model Lagrangian is constructed making the pseudo-Finsleroid generalization of the Yang-Mills field equation by
the conformal method. The Higgs field potential is suggested that ensures generation of particle masses caused by the spontaneous
symmetry breaking. After transition to the conformal coordinates, the expressions obtained assume the standard form that in
many cases allows the results of pseudo-Euclidean theory to be used in calculations of the Feynman diagrams.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 44–51, April, 2006. 相似文献
88.
A method for suppressing self-modulation in backward-wave tubes is proposed. Additional delay is introduced into the feedback
circuit, owing to which the output signal amplitude affects the electron beam current that enters into the interaction space.
Numerical simulations demonstrate that the operating current in the single-frequency oscillation mode may be increased roughly
twofold. 相似文献
89.
L. Villa P. D' Agati C. Mansueto C. Pellerito M. Scopelliti T. Fiore L. Nagy L. Pellerito 《应用有机金属化学》2003,17(2):106-112
Ascidia malaca gametes before fertilization incubated in 10?5 or 10?7 M solutions of tributyltin(IV) chloride, TBTCl, for 3 h appear highly damaged under transmission electron microscopy observation. Also, the fertilization process is affected by the compound: the damaged spermatozoa are present in the vitelline coat and the egg does not cleave. An increase of microbodies, structurally similar to peroxisomes, have been detected in the egg peripheral cytoplasm, probably in relation to their role in alleviating damage to some cellular components. The results have shown that the reproduction of ascidians under unfavourable environmental conditions is prevented. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
90.
María G. Armentano Ricardo G. Durn 《Numerical Methods for Partial Differential Equations》2003,19(5):653-664
In this article we analyze the effect of mass‐lumping in the linear triangular finite element approximation of second‐order elliptic eigenvalue problems. We prove that the eigenvalue obtained by using mass‐lumping is always below the one obtained with exact integration. For singular eigenfunctions, as those arising in non convex polygons, we prove that the eigenvalue obtained with mass‐lumping is above the exact eigenvalue when the mesh size is small enough. So, we conclude that the use of mass‐lumping is convenient in the singular case. When the eigenfunction is smooth several numerical experiments suggest that the eigenvalue computed with mass‐lumping is below the exact one if the mesh is not too coarse. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 653–664, 2003 相似文献