全文获取类型
收费全文 | 11265篇 |
免费 | 562篇 |
国内免费 | 3篇 |
专业分类
化学 | 8223篇 |
晶体学 | 86篇 |
力学 | 332篇 |
数学 | 1611篇 |
物理学 | 1578篇 |
出版年
2023年 | 99篇 |
2022年 | 90篇 |
2021年 | 147篇 |
2020年 | 213篇 |
2019年 | 206篇 |
2018年 | 267篇 |
2017年 | 227篇 |
2016年 | 456篇 |
2015年 | 392篇 |
2014年 | 391篇 |
2013年 | 778篇 |
2012年 | 818篇 |
2011年 | 908篇 |
2010年 | 488篇 |
2009年 | 407篇 |
2008年 | 806篇 |
2007年 | 811篇 |
2006年 | 726篇 |
2005年 | 649篇 |
2004年 | 471篇 |
2003年 | 464篇 |
2002年 | 364篇 |
2001年 | 138篇 |
2000年 | 114篇 |
1999年 | 97篇 |
1998年 | 66篇 |
1997年 | 69篇 |
1996年 | 116篇 |
1995年 | 68篇 |
1994年 | 60篇 |
1993年 | 64篇 |
1992年 | 57篇 |
1991年 | 41篇 |
1990年 | 29篇 |
1989年 | 32篇 |
1987年 | 31篇 |
1986年 | 23篇 |
1985年 | 64篇 |
1984年 | 51篇 |
1983年 | 24篇 |
1982年 | 52篇 |
1981年 | 40篇 |
1980年 | 56篇 |
1979年 | 40篇 |
1978年 | 33篇 |
1977年 | 33篇 |
1976年 | 46篇 |
1975年 | 40篇 |
1974年 | 31篇 |
1973年 | 31篇 |
排序方式: 共有10000条查询结果,搜索用时 687 毫秒
21.
In order to investigate the relative effects of the differences between the structures and lipophilicities of 1, 10-dioxa-4, 7, 13, 16-tetra-azacyclo-octadecane (TA-18-crown-6) and the tetrabenzyl derivative of 1,10-dioxa-4, 7, 13, 16-tetra-azacyclo-octadecane (TBTA-18-crown-6) on their extraction-abilities and -selectivities for transition metal cations, constants of the overall extraction (logK
ex) of 1:1 (M:L) complexes, the distribution (K
D) for two diluents (CH2Cl2 and CHCl3) with different dielectric constants have been determined at 25 ± 0.1 °C. The magnitude of logK
ex is largely determined by that of K
D. The equilibrium constants of TA-18-crown-6 have been compared with those of TBTA-18-crown-6. It is found that:(i) logK
ex sequences of TA-18-crown-6 and TBTA-18-crown-6 for transition metals in CH2Cl2 lie in order: Fe3+ > Cu2+ > Mn2+ > Co2+ > Cd2+ > Ni2+ > Zn2+ and Fe3+ > Cu2+ > Co2+ > Mn2+ > Ni2+ > Cd2+ > Zn2+ respectively; (ii) the stability sequences of two types of tetra-aza-crown ethers with the transition metal cations in CHCl3 are the same as follows: Fe3+ > Ni2+ > Cu2+ > Co2+ > Zn2+ > Cd2+ > Mn2+, and (iii) unusual selectivities are observed for transition metal-tetra-aza-crowns, e.g. the high Fe3+/M
n+ selectivity factors (Sf) of TA-18-crown-6, except for the competitive-extractions for the special case in CHCl3 of TBTA-18-crown-6, it was found that the Mn2+/M
n+ values were relatively higher according to the other transition metal cations. A systematic sequence in these two types of solvents is not found for a given transition metal cation in terms of the variation of selectivity with the tetra-aza-crown ethers. The results provide alternatives for the rational design of other specific ligands on the transition metal cations. 相似文献
22.
23.
This paper presents an approach based on topology for the determination of characteristics and properties of curves used in the trimming of NURBS surfaces. Through discrete subdivision and topological criteria, a method is presented to determine characteristics of the boundary; such as whether the set of trimming curves forms a set of closed loops, whether trimming curves contain singularities or self intersections, and whether the boundary is simply connected. A surface mesh partitionning the parameter space is used, formed of isoparametric lines in both parametric directions. Topological properties of the cells of this mesh and their intersections with the trimming curves allow to localize the boundary. Topological treatment of this localization allows to define the interior and exterior of the face, and to refine the boundary localization. Singularities and self intersections of the boundary as well as voids in the face are investigated through the study of topological properties of neighbors. As an application, an algorithm for point localization is presented that very rapidly allows to determine whether a given point in parameter space lies inside, on the boundary or outside of the trimmed surface. 相似文献
24.
Monika Goikoetxea María J. Barandiaran José M. Asua 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5838-5846
The mechanisms involved in the formation of n‐butanol during the synthesis of butyl acrylate containing latices were investigated. The experimental results showed that neither the hydrolysis of butyl acrylate nor of the ester bond in the butyl acrylate segments of the polymer played a major role in the formation of n‐butanol, which was mainly generated from the polymer backbone, by transfer reactions to polymer chain followed by cyclization. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5838–5846, 2007 相似文献
25.
We introduce here some Itô calculus for non-continuous Dirichlet processes. Such calculus extends what was known for continuous Dirichlet processes or for semimartingales. In particular we prove that non-continuous Dirichlet processes are stable under C
1 transformation. 相似文献
26.
François Ledrappier Mark Pollicott 《Bulletin of the Brazilian Mathematical Society》2005,36(2):143-176
In this paper we study the ergodic properties of the linear action of lattices Γ of SL(2,ℚp) on ℚp × ℚp and distribution results for orbits of Γ. Following Serre, one can define a “geodesic flow” for an associated tree (actually
associated to GL(2,ℚp)). The approach we use is based on an extension of this approach to “frame flows” which are a natural compact group extension
of the geodesic flow. 相似文献
27.
28.
Regina S. Burachik Rafail N. Gasimov Nergiz A. Ismayilova C. Yalçin. Kaya 《Journal of Global Optimization》2006,34(1):55-78
We study convergence properties of a modified subgradient algorithm, applied to the dual problem defined by the sharp augmented
Lagrangian. The primal problem we consider is nonconvex and nondifferentiable, with equality constraints. We obtain primal
and dual convergence results, as well as a condition for existence of a dual solution. Using a practical selection of the
step-size parameters, we demonstrate the algorithm and its advantages on test problems, including an integer programming and
an optimal control problem.
*Partially Supported by 2003 UniSA ITEE Small Research Grant Ero2.
Supported by CAPES, Brazil, Grant No. 0664-02/2, during her visit to the School of Mathematics and Statistics, UniSA. 相似文献
29.
Jean-François Burnol 《Annales Henri Poincare》2006,7(6):1013-1034
We study Hilbert space aspects of the Klein-Gordon equation in two-dimensional spacetime. We associate to its restriction
to a spacelike wedge a scattering from the past light cone to the future light cone, which is then shown to be (essentially)
the Hankel transform of order zero. We apply this to give a novel proof, solely based on the causality of this spatio-temporal
wave propagation, of the theorem of de Branges and V. Rovnyak concerning Hankel pairs with a support property. We recover
their isometric expansion as an application of Riemann’s general method for solving Cauchy-Goursat problems of hyperbolic
type.
Communicated by Vincent Rivasseau
Submitted: October 28, 2005; Accepted: February 17, 2006 相似文献
30.
Francois NICOLEAU 《数学学报(英文版)》2006,22(5):1485-1492
We consider a pair of Hamiltonians (H, H0) on L2(R^n), where H0=p^2 -x^2 is a SchrSdinger operator with a repulsive potential, and H = H0+V(x). We show that, under suitable assumptions on the decay of the electric potential, V is uniquely determined by the high energy limit of the scattering operator. 相似文献