大型望远镜设计与研究

介绍一种４．３ｍ红外望远镜。它与２．１６ｍ望远镜用真空管道联机用于ＣＣＤ照相和光干涉测量，可使集光能力达４．８ｍ口径，分辨率达１０１ｍ口径。     

NMR在主族元素溶液无机化学中的若干应用

引用实例综述了NMR在主族元素溶液无机化学研究中的应用,内容包括碱金属负离子的确认,非水溶液中离子对和聚集体的确认以及无机盐溶剂化和水解产物的确认等。     

An empirical criterion for estimatingT 1 error

More than 200 inversion-recovery experiments on¹⁷O in D₂O have been performed in order to make a correlation between the error inT ₁ and the standard deviation in data fitting. The statistical results ofT ₁ show that the error limit is about 6 times as big as the standard deviation. This can be proposed as an empirical rule for estimating the precision inT ₁ measurements.     

相对论重离子反应的热化过程

本文从相对论BUU理论出发研究了1GeV/n能区重离子反应全局(global)和局域(local)平衡性质,计算表明在该能区平均场对反应动力学过程仍有相当的作用;对有限核系统的反应动力学过程的时间演化的研究表明,有限核系统无论全局的还是局域的平衡均未能达到完全平衡,因而对有限核系统重离子反应基于完全热平衡概念的适用性值得怀疑.     

超导体Bi1.8Pb0.2Sr2-xLaxCuOy的电阻率和热电势研究

本文对名义组份为Bi1.8Pb0.2Sr2-xLaxCuOy系列样品的电阻率和热电势特性进行了实验研究.测量表明,Pb掺杂可以进一步提高超导转变温度Tc ;随着La含量的增加,Tc 按照典型的抛物线型规律变化;La掺杂极大地影响超导体正常态的输运特性.我们的分析指出,热电势在正常态所表现出的规律与高温超导机制密切相关,而且电阻率正常态输运特性的变化可用La掺杂造成CuO6八面体顶点氧发生位移来解释.     

槲皮素-3-鼠李糖-(6-对羟基反式桂皮酰)葡萄糖甙1-2连接的NMR谱证据

用2D NMR技术研究了从银杏叶提取物中分离的一个黄酮双糖甙[槲皮素-3-鼠李糖-(6-对羟基反式桂皮酰)葡萄糖甙]的结构,对鼠李糖部分的¹H NMR,¹³C NMR化学位移进行了归属.¹³C化学位移和¹H NOE相关性都证明鼠李糖为1″-2″连接.     

Development and Validation of a Computer‐Administered Number Sense Scale for Fifth‐Grade Children in Taiwan

To investigate the structure of number sense and then to assess its uses in fifth‐grade children's number sense development, a computerized number sense scale was developed and evaluated. The findings of the study indicate that the newly developed scale, with four dominant factors identified and reconfirmed, is internally consistent and substantially valid. It can be reliably used as a screening measure for a quick check of students' number sense development via online self‐assessment. Compared with our previous study, both qualitative and quantitative changes were detected in students' number sense development at different grades. The qualitative change in number sense development is manifested in different numbers of factor components produced at different grades. The quantitative change is manifested in different amounts of factor variance explained at different grades. Furthermore, among the four aspects of number sense, Taiwanese students perform best on recognizing the relative number size yet relatively worse on judging the reasonableness of computational results.     

A Mössbauer spectroscopic study of an industrial catalyst for dehydrogenation of etylbenzene to styrene

Iron oxide catalyst with spinel structure used for dehydrogenation of ethylbenzene is one kind of important catalyst in petrochemical industry. In this work several series of industrial catalyst were prepared with different components and different manufacturing processes. Mössbauer Spectroscopy has been used to determine the optimal components and the better manufacturing process for spinel structure formation. The results may prove useful for producing the industrial dehydrogenation catalyst with better catalytic property.     

小试金富集ICP-AES法同时测定试样中的铂、钯、金

文章报道了用小试金富集ICP AES法同时测定试样中的铂、钯和金 ,将 1 0～ 2 0g试样中的铂、钯、金富集在毫克量的银合粒中 ,制成溶液后用ICP AES法同时测定铂、钯和金。该方法的检出限 (μg·mL-1 )Pt,Pd ,Au分别为 0 0 1 ,0 0 0 5 ,0 0 1 ,相对标准偏差 (RSD ,n =1 0 )分别为 0 1 % ,0 1 2 % ,0 0 9% ,标准回收率均在 97%以上。生产实践表明 ,本方法是一种快速、简便、准确的分析方法 ,已被我们应用于测定样品中的铂 ,钯和金     

催化动力学荧光法测定中草药对羟基自由基的清除率

苯甲酸具有很弱的荧光,在Co2+的催化下,过氧化氢能氧化苯甲酸发出强的荧光。中草药提取物可以清除溶液中的·OH, 使产物的生成量减少, 从而使溶液的荧光增加程度降低。据此原理建立了一种测定中草药对羟基自由基清除率的催化动力学荧光新体系。当中草药的浓度为4.0 mg(干重)·mL-1时,测得紫花地丁、苍术和赤芍对羟基自由基的清除率分别为60.8%,40.1%和94.3%。该方法与分光光度法测定结果相比无显著性差异。