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951.
952.
Otti D’Huys Javier Rodríguez-Laguna Manuel Jiménez Elka Korutcheva Wolfgang Kinzel 《The European physical journal. Special topics》2018,227(10-11):1129-1150
We study the dynamics of networks with coupling delay, from which the connectivity changes over time. The synchronization properties are shown to depend on the interplay of three time scales: the internal time scale of the dynamics, the coupling delay along the network links and time scale at which the topology changes. Concentrating on a linearized model, we develop an analytical theory for the stability of a synchronized solution. In two limit cases, the system can be reduced to an “effective” topology: in the fast switching approximation, when the network fluctuations are much faster than the internal time scale and the coupling delay, the effective network topology is the arithmetic mean over the different topologies. In the slow network limit, when the network fluctuation time scale is equal to the coupling delay, the effective adjacency matrix is the geometric mean over the adjacency matrices of the different topologies. In the intermediate regime, the system shows a sensitive dependence on the ratio of time scales, and on the specific topologies, reproduced as well by numerical simulations. Our results are shown to describe the synchronization properties of fluctuating networks of delay-coupled chaotic maps. 相似文献
953.
954.
Victor García David Zorrilla Jesús Sánchez-Márquez Manuel Fernández 《Molecular physics》2018,116(18):2310-2320
Simplified Box Orbitals (SBOs) are a kind of spatially restricted basis functions with a similar use to Slater functions, but fulfilling an exact version of the zero-differential overlap approximation. These functions also allow for a drastic reduction in the number of bielectronic integrals when dealing with huge systems, and can be adapted to study confined systems such as molecules in solution. In previous studies, the necessary SBOs parameters to be used for different elements were defined. However, the accuracy of those basis functions decreases with the atomic number of the atoms under study, and therefore their use was discouraged beyond the Ar atom. In the present study, we verify that slightly increasing the terms of SBOs for a better definition, is enough to correctly handling atoms beyond Ar. This, together with other improvements exposed in this work, allowed obtaining accurate SBOs for K–Kr atoms. To make possible the use of SBOs in standard quantum chemistry calculation software, Gaussian expansions to the proposed basis functions–were achieved. Then, simple formulas for directly obtaining those expansions were deduced. Finally, the results of an SZ basis set of the proposed SBOs are analysed and compared with a similar STO basis set. 相似文献
955.
956.
M. Raja K. Bicy Shruti Suriyakumar N. Angulakshmi Sabu Thomas A. Manuel Stephan 《Ionics》2018,24(11):3451-3457
A high performing and thermally stable magnesium aluminate (MgAl2O4) coated on both sides of Celgard 2320 for applications in lithium batteries was prepared. The MgAl2O4-coated membrane was thermally stable up to 440 °C and capable of up-taking electrolytes up to 250%. The contact angle of MgAl2O4-coated membrane was lower (21°) than that of uncoated membrane. The MgAl2O4-coated ceramic separator exhibited appreciable ionic conductivity and better compatibility with lithium metal anode. Finally, a 2032-type coin cell comprising Li/MgAl2O4-coated separator/LiFePO4 was assembled and its charge-discharge behavior was analyzed at 0.1, 0.5, and 1 C-rates. A stable discharge capacity was achieved even at 1 C-rate which qualifies this MgAl2O4-coated membrane for lithium battery applications. 相似文献
957.
Manuel O. Cáceres 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(4):74
The concept of continuous-time random walk is generalized into the quantum approach using a completely positive map. This approach introduces in a phenomenological way the concept of disorder in the transport problem of a quantum open system. If the waiting-time of the continuous-time renewal approach is exponential we recover a semigroup for a dissipative quantum walk. Two models of non-Markovian evolution have been solved considering different types of waiting-time functions. 相似文献
958.
Julia Winroth Wolfgang Kropp Carsten Hoever Thomas Beckenbauer Manuel Männel 《Applied Acoustics》2017
The purpose of this study is to clarify the influence of air-pumping related noise sources on typical tyre/road noise. The aim is to increase the understanding of noise generation mechanisms and catalyse the development of existing tyre/road noise simulation tools. The speed dependency of measured and simulated tyre/road noise is analysed and the results show that a large part of the noise can be explained by a high speed exponent traditionally connected with air-pumping mechanisms. Surprisingly, this is also the case for rough road surfaces which are expected to mainly generate noise by tyre vibrations. It is also found that vehicle wind noise may have a strong influence on the pass-by noise and care must be taken when analysing measurement data of quiet tyre/road combinations. Even simulated tyre/road noise shows higher speed exponents than what is anticipated without the inclusion of any type of air-pumping mechanism in the model. It is concluded that it is unfeasible to separate noise created by tyre vibrations from noise created by air-pumping with a speed exponent analysis due to the overlap in the speed exponents connected with the different generation mechanisms. 相似文献
959.
960.
Nerea Picazas-Márquez María Sierra Clara Nova Juan Manuel Moreno Nuria Aboitiz Gema de Rivas Miguel A. Sierra Roberto Martínez-Álvarez Esther Gómez-Caballero 《Journal of the American Society for Mass Spectrometry》2016,27(9):1510-1519
A new class of compounds, mono- and bis-haloethylphosphonates (HAPs and bisHAPs, respectively), listed in Schedule 2.B.04 of the Chemical Weapons Convention (CWC), has been synthesized and studied by GC-MS with two aims. First, to improve the identification of this type of chemicals by the Organization for the Prohibition of Chemical Weapons, (OPCW). Second, to study the synergistic effect of halogen and silicon atoms in molecules undergoing mass spectrometry. Fragmentation patterns of trimethylsilyl derivatives of HAPs were found to depend on the nature of the halogen atom; this was in agreement with DFT-calculations. The data suggest that a novel intramolecular halogen transfer takes place during the fragmentation process. 相似文献