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11.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
12.
Ricaurte Rodríguez Manuel Nogueras Justo Cobo John N. Low Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(7):o376-o378
Molecules of the title compound, C12H13ClN4, are linked by two independent N—H...N hydrogen bonds into a chain of edge‐fused R22(8) rings. The significance of this study lies in its attempt to rationalize the patterns of supramolecular aggregation in the title compound and in a range of analogous 4,6‐disubstituted 2‐aminopyrimidines. 相似文献
13.
Anatoliy Samoilenko Manuel Pinto Sergei Trofimchuk 《Proceedings of the American Mathematical Society》2005,133(1):145-154
We apply the Krylov and Bogolyubov asymptotic integration procedure to asymptotically autonomous systems. First, we consider linear systems with quasi-periodic coefficient matrix multiplied by a scalar factor vanishing at infinity. Next, we study the asymptotically autonomous Van-der-Pol oscillator.
14.
A method employing a wide pore polymeric reversed phase column has been developed for the separation of most of the chlorophylls and related compounds previously described as occurring in marine microalgae. The high selectivity toward molecular shape of this kind of stationary phase has enabled compounds of very similar structure, such as chlorophylls c1, c2 and Mg-divinylpheoporphyrin a5 monomethyl ester, and chlorophyll a and the phytol-substituted chlorophyll c-like pigments, which commonly coelute on monomeric bonded phases, to be resolved in a single run. Some of these pigments, formerly thought to be a single compound, have, in fact, been demonstrated to be groups of two or more. The method has been successfully applied to both algal cultures and natural sea water samples. When visible light absorbance detection was used, the method proved suitable for separation of various carotenoids. 相似文献
15.
V. V. Lozhkarev S. G. Garanin R. R. Gerke V. N. Ginzburg E. V. Katin A. V. Kirsanov G. A. Luchinin A. N. Mal’shakov M. A. Mart’yanov O. V. Palashov A. K. Poteomkin N. N. Rukavishnikov A. M. Sergeev S. A. Sukharev G. I. Freidman E. A. Khazanov A. V. Charukhchev A. A. Shaikin I. V. Yakovlev 《JETP Letters》2005,82(4):178-180
In experiments on the parametrical amplification of femtosecond pulses in wide-aperture DKDP crystals, a power of more than 100 TW has been reached, which is much higher than the record level achieved in such lasers. The energy efficiency obtained for the parametric amplifier is equal to 27%. The energy of a 72-fs pulse is equal to 10 J. 相似文献
16.
Humberto Bustos Rodriguez Dagoberto Oyola Lozano Yebrayl A. Rojas Martínez Germán A. Pérez Alcázar Stefan Flege Adam G. Balogh Louis J. Cabri Michael Tubrett 《Hyperfine Interactions》2007,175(1-3):195-206
X-ray diffraction (XRD), Mössbauer spectrometry (MS), secondary ions mass spectroscopy (SIMS) and laser-ablation microprobe–inductively coupled plasma–mass spectrometry (LAM–ICP–MS) were used to study mineral samples of Colombian auriferous ores collected from the “El Diamante” mine, located in the municipality of Guachavez-Nariño, in Colombia. The samples were prepared as polished thin sections and polished sections. From XRD data, quartz, sphalerite and pyrite were detected and their respective cell parameters were estimated. From MS analyses, pyrite, arsenopyrite and chalcopyrite were identified; their respective hyperfine parameters and respective texture were deduced. Multiple regions of approximately 200 × 200 μm in each sample were analyzed with SIMS; the occurrence of “invisible gold” associated mainly with pyrite and secondarily with arsenopyrite could thus be assigned. It was also found that pyrite is of the arsenious type. Spots from 30 to 40 μm in diameter were analyzed with LAM–ICP–MS for pyrite, arsenopyrite and sphalerite; Au is “homogeneously” distributed inside the structure of the arsenious pyrite and the arsenopyrite (not as inclusions); the chemical composition indicates similarities of this “invisible gold”, forming a solid solution with arsenious pyrite and arsenopyrite. One hundred nineteen and 62 ppm of ‘invisible gold’ was quantified in 21 spots analyzed on pyrite and in 14 spots on arsenopyrite, respectively. 相似文献
17.
Jose Manuel Corcuera Joao Guerra David Nualart Wim Schoutens 《Applied Mathematics and Optimization》2006,53(3):279-309
In this paper we consider the optimal investment problem in a market where the stock price process is modeled by a geometric
Levy process (taking into account jumps).
Except for the geometric Brownian model and the geometric Poissonian model, the
resulting models are incomplete and there are many equivalent martingale measures.
However, the model can be completed by the so-called power-jump assets. By doing this we allow investment in these new assets
and we can try to maximize the expected utility of these portfolios. As particular cases we obtain the optimal portfolios
based in stocks
and bonds, showing that the new assets are superfluous for certain martingale measures
that depend on the utility function we use. 相似文献
18.
The atomic structure and magnetic and electric properties of the Cr0.5TiSe2-Cr0.5TiTe2 system of intercalated phases were studied in detail by gradually replacing selenium by tellurium. It was revealed that this replacement changes the crystalline structure from monoclinic in the initial compounds to hexagonal in the compounds containing various types of chalcogen atoms; this is accompanied by disordering of chromium atoms in the van der Waals gaps. The electrical resistance and magnetic characteristics vary nonmonotonically on replacement of selenium by tellurium, which is associated with a change in the degree of atomic disordering during the transition from Cr0.5TiSe2 to Cr0.5TiTe2. 相似文献
19.
We consider the generalization of the classical P||Cmax problem (assign n jobs to m identical parallel processors by minimizing the makespan) arising when the number of jobs that can be assigned to each processor cannot exceed a given integer k. The problem is strongly NP-hard for any fixed k > 2. We briefly survey lower and upper bounds from the literature. We introduce greedy heuristics, local search and a scatter search approach. The effectiveness of these approaches is evaluated through extensive computational comparison with a depth-first branch-and-bound algorithm that includes new lower bounds and dominance criteria. 相似文献
20.
Models, describing relativistic particles, where Lagrangian densities depend linearly on both the curvature and the torsion of the trajectories, are revisited in D=3 space forms. The moduli spaces of trajectories are completely and explicitly determined using the Lancret program. The moduli subspaces of closed solitons in the three sphere are also determined. 相似文献