全文获取类型
收费全文 | 1583篇 |
免费 | 98篇 |
国内免费 | 7篇 |
专业分类
化学 | 1206篇 |
晶体学 | 13篇 |
力学 | 44篇 |
数学 | 112篇 |
物理学 | 313篇 |
出版年
2024年 | 4篇 |
2023年 | 37篇 |
2022年 | 36篇 |
2021年 | 53篇 |
2020年 | 65篇 |
2019年 | 58篇 |
2018年 | 57篇 |
2017年 | 47篇 |
2016年 | 91篇 |
2015年 | 63篇 |
2014年 | 84篇 |
2013年 | 128篇 |
2012年 | 159篇 |
2011年 | 119篇 |
2010年 | 91篇 |
2009年 | 68篇 |
2008年 | 90篇 |
2007年 | 84篇 |
2006年 | 63篇 |
2005年 | 55篇 |
2004年 | 41篇 |
2003年 | 37篇 |
2002年 | 27篇 |
2001年 | 19篇 |
2000年 | 16篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 9篇 |
1991年 | 3篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 1篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有1688条查询结果,搜索用时 78 毫秒
31.
Indoles undergo smooth coupling with phenylacetylene in the presence of 10 mol % of gallium(III) chloride or gallium(III) bromide under mild conditions to afford the corresponding 1,1-bis(1H-3-indolyl)-1-phenylethanes in high yields and with high selectivity. 相似文献
32.
C.V. Ramana Mohabul A. Mondal Vedavati G. Puranik Mukund K. Gurjar 《Tetrahedron letters》2006,47(24):4061-4064
The central macrocyclic core of the macrocidins was constructed using RCM as the key reaction. A preliminary investigation dealing with the key reactions, that is, the Dieckmann cyclization and the RCM, revealed that RCM of the β-ketoamide is better than RCM of the corresponding acyltetramic acid. 相似文献
33.
Mondal A Sarkar S Chopra D Row TN Rajak KK 《Dalton transactions (Cambridge, England : 2003)》2004,(20):3244-3250
The green colored complexes of the type Re(V)O(L(SB))Cl(2), 1, have been synthesised by reacting NBu(4)[ReOCl(4)] with HL(SB) in dry ethanol. Here, L(SB)(-) are the deprotonated forms of N-(2-hydroxybenzyl)-2-picolylamine (HL(SB)(1)); N-(2-hydroxybenzyl)-N',N'-dimethylethylenediamine (HL(SB)(2)) and N-(2-hydroxybenzyl)-N',N'-diethylethylenediamine (HL(SB)(3)). Similarly, NBu(4)[ReOCl(4)] reacted with N,N-bis(2-hydroxybenzyl)-2-picolylamine (H(2)L(1)); N,N-bis(2-hydroxybenzyl)-N',N'-dimethylethylenediamine (H(2)L(2)); N,N-bis(2-hydroxybenzyl)-N',N'-diethylethylenediamine (H(2)L(3)); [N-(2-hydroxybenzyl)-N-(2-pyridylmethyl)]-2-aminoethanol (H(2)L(4)); [N-(2-hydroxybenzyl)-N-(2-pyridylmethyl)]-2-methyl-2-amino-1-propanol (H(2)L(5)); N,N-bis(1-hydroxyethyl)-2-picolylamine (H(2)L(6)), to give the monochloro complexes Re(V)O(L)Cl, 2. The X-ray structures of the complexes are reported. The molecular structures observed in the solid state are preserved in solution ((1)H NMR). In acetonitrile solution the Re(V)O(L)Cl, 2, display a one-electron couple, Re(VI)O(L)Cl(+)-Re(V)O(L)Cl, near 1.0 V vs SCE. The electrogenerated hexavalent complexes [Re(VI)O(L)Cl]ClO(4), 3, are paramagnetic and display sextet EPR spectra in solution at room temperature (A(av) approximately 417 (G), g approximately 1.914). 相似文献
34.
Manoj KumarS.S Sekhon 《European Polymer Journal》2002,38(7):1297-1304
The addition of plasticizer to the polyethylene oxide (PEO)-ammonium fluoride (NH4F) polymer electrolytes has been found to result in an increase in conductivity value and the magnitude of increase has been found to depend upon the dielectric constant of the plasticizer used. The addition of dimethylacetamide as a plasticizer with dielectric constant (?=37.8) higher than that of PEO (?∼5) results in an increase of conductivity by more than three orders of magnitude whereas the addition of diethylcarbonate as a plasticizer with dielectric constant (?=2.82) lower than that of PEO does not enhance the conductivity of PEO-NH4F polymer electrolytes. The increase in conductivity has further been found to depend upon the concentration of plasticizer, the concentration of salt in the polymer electrolyte as well as on the dielectric constant value of the plasticizer used. The conductivity modification with the addition of plasticizer has been explained on the basis of dissociation of ion aggregates formed in PEO-NH4F polymer electrolytes at higher salt concentrations. 相似文献
35.
36.
37.
38.
39.
40.