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101.
The essential oil of Eucalyptus cinerea is reported to possess a higher 1,8-cineole content than other Eucalyptus species. Variations in the quantitative and qualitative characteristics of E. cinerea oil produced by hydrodistillation (HD) and supercritical carbon dioxide extraction (SCE) techniques and a comparison between glycoside-bound and free volatile constituents produced by HD have been studied. It was found that HD produced higher oil (free volatiles) content (3.1%) as compared with SCE (1.1%), whereas bound volatiles constituted only about 0.4%. Gas chromatographic (GC) analysis of the oil samples revealed significant difference in their chemical composition. The essential oil (free volatiles) produced by HD contained 1,8-cineole (85.1%) as the major constituent, followed by a-terpineol (7.2%) and limonene (4.4%). In the bound volatile fraction produced by HD, 1,8 cineole (20.6%), alpha-terpineol (7.6%), p-cymene (6.3%), and limonene (4.5%) were found as major constituents. The extract produced by SCE was dominated by 1,8-cineole (70.4%), a-terpineol (8.6%), globulol (3.1%), aromadendrene (2%), citronellal (1.7%), viridiflorol (1.3%), phytol (1.1%) and terpinen-4-ol (1%). Although HD produced higher oil yields, SCE produced better extract in terms of the number of components detected. 相似文献
102.
Frederick J. Davis Andrew Gilbert John Mann Geoffrey R. Mitchell 《Journal of polymer science. Part A, Polymer chemistry》1990,28(6):1455-1472
The synthesis is described of some acrylate based polymers containing both a mesogenic group (4-cyanophenyl benzoate) connected to the polymer backbone by a flexible spacer, and varying degrees of crosslinking, introduced by copolymerization. Optical and calorimetric techniques are used to determine the phase behavior, which is found to depend strongly on the crosslink density (and the flexible spacer length); though (nominally) a relatively high degree of crosslinking is possible without completely destroying the liquid crystal phase. Mechanical measurements in conjunction with supplementary analytical data, where available, are used to determine the efficiency of copolymerization at introducing intermolecular crosslinking. Some possible explanations for the unexpectedly low efficiency of this process are discussed. The properties of materials prepared in this fashion are compared briefly with some examples where crosslinking is introduced after polymerization; this latter process is seen to be rather more efficient. 相似文献
103.
We consider subgroups of powerfulp-groups. In particular, we give a new proof that allp-groups are sections of powerfulp-groups, give necessary and sufficient conditions for a 2-generator group to be a normal subgroup of a powerfulp-groups, and show thatp-groups of class 2, orp-groups with a cyclic commutator subgroup, are such normal subgroups. 相似文献
104.
Stphane Mann Dominique Florentin Denis Lesage Thierry Drujon Olivier Ploux Andre Marquet 《Helvetica chimica acta》2003,86(11):3836-3850
The mechanism of action of amiclenomycin ( 1a ), a naturally occuring inhibitor of diaminopelargonic acid aminotransferase, has been established. The enzyme catalyzes the formation of an aromatic adduct between the inhibitor and pyridoxal‐5′‐phosphate. The structure of the adduct, determined by mass spectrometry, is in agreement with the reported X‐ray crystal structure. Kinetic parameters, characteristic of kcat inhibitors, have been observed, with a KI value of 2 μM and a kinact value of 0.4 min?1. The irreversibility of the inactivation observed, in spite of the absence of covalent bond between the inhibitor and the protein, reveals the high affinity of the adduct for the active site. Two other cis‐1‐amino‐4‐substituted‐cyclohexa‐2,5‐dienes, 3a and 4a , were also found to efficiently inhibit the enzyme. The trans‐isomers were either much less potent ( 1b ) or inactive ( 3b and 4b ). The aminocyclohexadiene moiety, which is, apparently, responsible for the inhibition, could constitute an original pharmacophore for the design of new herbicides. 相似文献
105.
We consider possible tests of the Einstein Equivalence Principle for physical systems in which quantum-mechanical vacuum energies cannot be neglected. Specific tests include a search for the manifestation of non-metric effects in Lamb-shift transitions of hydrogenic atoms and in anomalous magnetic moments of massive leptons. We discuss how current experiments already set bounds on the violation of the equivalence principle in this sector and how new (high-precision) measurements of these quantities could provide further information to this end. 相似文献
106.
Ohne Zusammenfassung 相似文献
107.
R. B. Mann 《Foundations of Physics Letters》1991,4(5):425-449
A relativistic gravitational theory in (1 + 1) dimensions is presented which exhibits many of the qualitative features of (3 + 1)-dimensional general relativity. The field equations are simple enough for undergraduates to solve yet rich enough in structure to form a useful pedagogical example for exploring the qualitative features of relativistic gravitation. Black hole solutions to the field equations of the theory are derived and its relationship to Newtonian gravity is discussed in detail. 相似文献
108.
We obtain the general form and exhibit simple expressions for the transformation operator in the Jansen—Byers Brown exchange perturbation theory, without the use of an orthonormalization process. 相似文献
109.
The Mo(p, n)Tc reaction cross section and its use as a normalization for shuttle-system measurements
The 100Mo(p, n)100Tc reaction cross section was determined from 2 to 11 MeV (c.m.), by counting the delayed γ-rays from the 100Tc decays (half-life = 15.8 s). These yields were measured with Ge(Li) and NaI(Tl) detectors and thick natural Mo targets. The use of this reaction as a normalizing reaction for cross-section measurements with a rapid target-transfer system is discussed. This technique was applied to the measurement of the astrophysically interesting 23Na(p, n)23Mg cross section (23Mg HALF-LIFE = 11.57s). The results agree well with an independent 23Na(p, n)23Mg cross-section measurement. 相似文献
110.
(2S)-Tyrosine (5) is incorporated stereospecifically into tuberin (1) with retention of the 3--S proton and incomplete retention of the 2-S proton; a parallel pathway to the xanthocillin (4) is apparent with stereospecific retention of the 3--R proton of tyrosine; results of experiments with - and -3-hydroxytyrosine in relation to tuberin biosynthesis are reported. 相似文献