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21.
M. Singh 《Journal of the Iranian Chemical Society》2006,3(4):334-339
Using upper consolute temperatures (UCT) and corresponding consolute compositions (CC) of water-phenol systems with each of 0.1 mol kg?1 salts and acids, 1.0% polyethylene glycol 200, 0.01 mol kg?1 surfactant and aromatic compounds, we obtained 0.01 mol kg?1 CaF2 and CrCl3 compositions. Focusing on UCT and CC, the role of valence electrons and shell number, basicity, hydrophilic, hydrophobic and π conjugated electrons of corresponding additives are reported. The surfactants and π conjugation electrons are noted to decrease the UCT in a constant ratio that depicts the state and inherent strength of ionic and molecular-water interactions. The data are useful in the investigation of cloud points of immiscible solutions based on the Hofmeister series. 相似文献
22.
23.
Raj Gandhi Kamales Kar S. Uma Sankar Abhijit Bandyopadhyay Rahul Basu Pijushpani Bhattacharjee Biswajoy Brahmachari Debrupa Chakraborti M. Chaudhury J. Chaudhury Sandhya Choubey E. J. Chun Atri Desmukhya Anindya Datta Gautam Dutta Sukanta Dutta Anjan Giri Sourendu Gupta Srubabati Goswami Namit Mahajan H. S. Mani A. Mukherjee Biswarup Mukhopadhyaya S. N. Nayak M. Randhawa Subhendu Rakshit Asim K. Ray Amitava Raychaudhuri D. P. Roy Probir Roy Suryadeep Roy Shiv Sethi G. Sigl Arunansu Sil N. Nimai Singh Mark Vagins Urjit Yagnik 《Pramana》2003,60(2):405-409
This is the report of neutrino and astroparticle physics working group at WHEPP-7. Discussions and work on CP violation in
long baseline neutrino experiments, ultra high energy neutrinos, supernova neutrinos and water Cerenkov detectors are discussed. 相似文献
24.
Vern I. Paulsen Dinesh Singh 《Proceedings of the American Mathematical Society》2004,132(12):3577-3579
We prove a uniform algebra analogue of a classical inequality of Bohr's concerning Fourier coefficients of bounded holomorphic functions. The classical inequality follows trivially.
25.
Molar extinction coefficients of aqueous solutions of some organic compounds, viz. formamide (CH3NO),N-methylformamide (C2H5NO),NN-dimethylformamide (C3H7NO),NN-dimethylacetamide (C4H9NO), 1,4-dioxane (C4H8O24), succinimide (C4H5NO2) and solutions of acetamide (C2H5NO) and benzoic acid (C7H6O2) in 1,4-dioxane (C4H8O2) have been determined by narrow beam γ-ray transmission method at 81, 356, 511, 662, 1173 and 1332 keV. The experimental
values of mass attenuation coefficients of these compounds have been used to calculate effective atomic numbers and electron
densities. The additivity rule earlier used for aqueous solution has been extended to non-aqueous (1,4-dioxane) solutions. 相似文献
26.
Excess enthalpies of mixing H
m
E
of tetrahydrofuran and tetrahydropyran with trichloromethane, tetrachloromethane, 1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane have been determined at 26.9°C and are found to be negative over the entire composition range for both sets of the ether mixtures. H
m
E
decreases in the sequence; dichloroethane > tetrachloromethane > trichloroethane > trichloromethane > tetrachloroethane. The results are explained on the basis of strong O...H-C and weak Cl...O specific interactions. Flory's theory has been used to correlate the experimental data with good agreement found between the theoretical and experimental values of H
m
E
. 相似文献
27.
28.
A self-consistent system of gravitational field with a binary mixture of perfect fluid and dark energy given by a cosmological
constant has been considered in Bianchi Type-V universe. The perfect fluid is chosen to be obeying either the equation of
state p=γρ with γ ε |0,1| or a van der Waals equation of state. The role of A-term in the evolution of the Bianchi Type-V universe has been
studied. 相似文献
29.
A poly(vinyl chloride)-based membrane composed of dithio-tetraaza macrocyclic compound as a neutral carrier with sodium tetraphenylborate (NaTPB) as an anion excluder and nitrobenzene (NB) as plasticizer was prepared and investigated as a Th(IV)-selective electrode. The electrode exhibits a Nernstian slope of 14.2 +/- 0.3 mV per decade over a wide concentration range (1.0 x 10(-6) to 1.0 x 10(-1) M) with a detection limit of 8.0 x 10(-7) M between pH 3.5 and 9.5. The response time of the sensor is about 10 s and it can be used over a period of 5 months without any divergence in potential. The proposed membrane sensor revealed a good selectivity for Th(IV) over a wide variety of other metal ions and proved to be a better electrode in many respects than those reported in the literature. It was successfully applied as an electrode indicator as well as in the direct determination of thorium ions in standard and real samples. 相似文献
30.
J.M. Chatterjee S. Basu-Roy S.S. Ghugre S. Chattopadhyay R.P. Singh G.O. Rodrigues R.K. Chattopadhyay R.K. Bhowmik 《The European Physical Journal A - Hadrons and Nuclei》1998,1(1):55-59
A search for new isomers of nanosecond lifetimes were carried out in 153Eu via the 150Nd(7Li,xnγ) reaction. The single particle angular momentum alignment and dynamical moment of inertia estimated from the experimental
data indicate a configuration change at rotational energy ħω∼ 0.30 MeV. A decrease of B(E2) values is also observed at the
same frequency. An isomeric level is identified at an excitation energy of 3100 keV (Jπ=35/2−) which corresponds to this frequency. The lifetime of the level is found to be 8.6 ± 1.3 nanosecond.
Received: 22 April 1997 / Revised version: 26 September 1997 相似文献