A green and environment-friendly magnetically separable nanocomposite, glutathione@magnetite was fabricated sonochemically through the functionalization of Fe3O4 by glutathione which was well characterized using Fourier-transform infrared spectroscopy, ultravoilet-visible spectroscopy, scanning electron microscope, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, thermogravimetric analysis, vibrating sample magnetometer, Brunauer-Emmett-Teller, and high-resolution transmission electron microscope. The parameters affecting adsorption including pH, temperature, contact time, initial adsorbate concentration, and adsorbent amount were optimized by batch experiments. The magnetic glutathione@magnetite was applied for the removal of uranium(VI) in water with maximum adsorption capacity found to be 333.33 mg/g in 120 min at a neutral pH at 25 °C showing high efficiency for U(VI) ions. Furthermore, adsorption results obtained from UV-vis spectroscopy were validated by inductively coupled plasma optical emission spectroscopy. The thermodynamic parameters, viz Gibbs free energy (ΔGº), standard enthalpy change (ΔHº), and standard entropy change (ΔSº) of the process were calculated using the Langmuir constants. The pseudo-second-order kinetics model is seen to be applicable for describing the uptake process using a kinetics test. Moreover, desorption studies reveals that glutathione@magnetite can be used repeatedly, and removal efficiency shows only a small decrease after six cycles. Thus, glutathione@magnetite acts as a potential adsorbent for the removal of U(VI) from the water with great adsorption performance. 相似文献
Pongamia pinnata Linn. (Papilionaceae) seeds have gained great commercial and industrial importance owing to their high oil content. Presently, there is no appropriate TLC based method available for standardization of P. pinnata. A simple, robust and reproducible TLC method for the determination of Karanjin is reported in the seeds of P. pinnata. The method involves separation of components by TLC on pre-coated silica gel G 60 F254 plates developed on toluene: ethyl acetate (7:3 v/v) and detection at 260 nm in absorbance mode. The sensitivity of the method was found to be 100 ng. The linearity range was 50–300 ng. Four samples of P. pinnata from different geographical locations were tested for their karanjin content using the developed method. The proposed method was found to be robust, precise, and accurate, it therefore holds potential for detection, monitoring and quantification of karanjin in Pongamia pinnata.
PbSrWO4 and PbBaWO4 have been synthesised by the solid state reaction technique XRD patterns show them to be tetragonal. Dielectric constant
(K/) and Dielectric loss (K//) of PbSrWO4 and PbBaWO4 have been measured at 1 kHz in the temperature range of 300 to 1050 K. The log K/ vs T as well as log K//vs T plot of PbSrWO4 and PbBaWO4 shows rapid increase of dielectric constant above 590 K and 640 K, respectively. 相似文献
Thin films of BixCo2−xMnO4 (x=0, 0.1 and 0.3) were grown on quartz, LaAlO3 (LAO) and YBa2Cu3O7 (YBCO) buffer layer coated LAO substrates by pulsed laser deposition (PLD). X-ray diffraction (XRD) and Raman scattering measurements showed that the thin films exhibit single phase polycrystalline cubic spinel structure on all the substrates. Near edge X-ray absorption fine structure (NEXAFS) studies confirmed the octahedral occupancy of the substituted Bi3+ ions. Temperature dependent zero-field cooled (ZFC) magnetization measurements show the ferrimagnetic (FM) behavior (TC∼186 K) and magnetization undergoes a crossover from positive to negative, owing to the opposite contributions of magnetic moments from Co and Mn ions. A weak ferroelectric property exhibited by the films above room temperature was evidenced through the capacitance-voltage (C-V) and dielectric measurements. Magnetoelectric coupling was found to be maximum just below FM-TC. 相似文献
In this paper our interest is in investigating properties and numerical solutions of Proximal Split feasibility Problems. First, we consider the problem of finding a point which minimizes a convex function \(f\) such that its image under a bounded linear operator \(A\) minimizes another convex function \(g\). Based on an idea introduced in Lopez (Inverse Probl 28:085004, 2012), we propose a split proximal algorithm with a way of selecting the step-sizes such that its implementation does not need any prior information about the operator norm. Because the calculation or at least an estimate of the operator norm \(\Vert A\Vert \) is not an easy task. Secondly, we investigate the case where one of the two involved functions is prox-regular, the novelty of this approach is that the associated proximal mapping is not nonexpansive any longer. Such situation is encountered, for instance, in numerical solution to phase retrieval problem in crystallography, astronomy and inverse scattering Luke (SIAM Rev 44:169–224, 2002) and is therefore of great practical interest. 相似文献