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71.
We illustrate the efficacy of a discrete wavelet based approach to characterize fluctuations in non-stationary time series. The present approach complements the multifractal detrended fluctuation analysis (MF-DFA) method and is quite accurate for small size data sets. As compared to polynomial fits in the MF-DFA, a single Daubechies wavelet is used here for detrending purposes. The natural, built-in variable window size in wavelet transforms makes this procedure well suited for non-stationary data. We illustrate the working of this method through the analysis of binomial multifractal model. For this model, our results compare well with those calculated analytically and obtained numerically through MF-DFA. To show the efficacy of this approach for finite data sets, we also do the above comparison for Gaussian white noise time series of different sizes. In addition, we analyze time series of three experimental data sets of tokamak plasma and also spin density fluctuations in 2D Ising model. 相似文献
72.
We report theoretical results on the magnetic behavior of free standing nanowires of Ti. Four different structures of Ti nanowires-linear, ladder, dimerized, and zigzag-with nonmagnetic, ferromagnetic, and anti-ferromagnetic configurations were considered. Exploration of magnetism in these atomic chains leads to ferromagnetic behavior for all the structures: zigzag structure shows almost degenerate ferromagnetic and anti-ferromagnetic states though. The zigzag structure of Ti nanowires is favored of all for low values of nearest neighbor distances, whereas the dimerized structure is favored at larger atomic separations. Our work helps to resolve the controversy in the predicted ground state magnetic nature of zigzag chains of Ti as reported in recent previous works. The maximum value of magnetic moment (0.93 μB/atom) occurs in the ladder chains while the zigzag chains show the minimum value (0.17 μB/atom). Interestingly, all the structures in the magnetic configuration show metastable state except the dimerized structure. Ferromagnetic dimerized nanowires seem to be a potential candidate for use in spintronics. The projected density of states shows that dx2−y2 and dxy bands play a leading role in magnetism of linear and ladder structures, whereas there is no outstanding contribution from a particular d-orbital for zigzag and dimerized nanowires. The charge density plots suggest that linear and zigzag structures have metallic bonding whereas covalent bonding is predominant in the dimerized and ladder structures. The estimated diameters for the favored ferromagnetic configuration of these ultrathin nanowires lie in the range 1.9-3.4 Å and indicate the instability of the ladder structure, as also projected by the relative cohesive energy and relative break force values. 相似文献
73.
Optical time division multiplexing (OTDM) is emerging and promising alternative for future high-speed photonic networks because of its ability to accommodate higher bit rate and flexible bandwidth. Among other factors the performance of an OTDM system largely depends upon the switching characteristics of a de-multiplexer (DEMUX). Symmetric Mach-Zehnder (SMZ) have been found to be most suitable than all the available de-multiplexing switches because of compact size, thermal stability, and low power operation. In this paper, we simulate four-channel OTDM systems (all channel multiplexer (MUX) and DEMUX) with a Mach-Zehnder modulator and SMZ DEMUX to investigate the impact of signal power, pulse width and control signal power on BER. 相似文献
74.
Natarajan Thilagavathi Arumugam Manimaran Navendran Padma Priya Nagarajan Sathya Chinnasamy Jayabalakrishnan 《Transition Metal Chemistry》2009,34(7):725-732
A new series of mixed ligand semicarbazone or thiosemicarbazone complexes of Ru(II) having the general formula [RuCO(EPh3)(B)L] (where E = P or As; B = PPh3, AsPh3 or Pyridine; L = dibasic tridentate ligand derived by the condensation of ethylacetoacetate/methylacetoacetate and thiosemicarbazide/semicarbazide) have been synthesized and characterized by physico-chemical, spectroscopic and electrochemical studies. A comparative study on the catalysis of oxidation of benzyl alcohol, cyclohexanol, cinnamyl alcohol, n-butanol, n-propanol and iso-butyl alcohol has been done with N-methylmorpholine-N-oxide and molecular oxygen as co-oxidants. Catalytic activity studies of the complexes in coupling reactions have been carried out. The antibacterial properties of the complexes have also been examined. 相似文献
75.
Manimaran B Lai LJ Thanasekaran P Wu JY Liao RT Tseng TW Liu YH Lee GH Peng SM Lu KL 《Inorganic chemistry》2006,45(20):8070-8077
Alkoxy- and thiolato-bridged Re(I) molecular rectangles [{(CO)3Re(mu-ER)2Re(CO)3}2(mu-bpy)2] (ER = SC4H9, 1a; SC8H17, 1b; OC4H9, 2a; OC12H25, 2b; bpy = 4,4'-bipyridine) exhibit strong interactions with several planar aromatic molecules. The nature of their binding was studied by spectral techniques and verified by X-ray diffraction analysis. Standard absorption and fluorescence titrations showed that a relatively strong 1:1 interaction occurs between aromatic guests such as pyrene and these rectangles. The results of a single-crystal X-ray diffraction analysis show that the recognition of 1 with a pyrene molecule is mainly due to CH...pi interactions and the face of the guest pyrene is located over the edges of the bpy linkers of 1. This is a fairly novel example of an interaction that is rarely designed into a host-guest pair. Furthermore, the interaction of 1 with Ag+ results in the self-organization of supramolecular arrays, as revealed by solid-state data. 相似文献
76.
Yun J. Lee Jason R. King Bala Chandra Chenna Samuel B. OwensJr. Jason L. Freeman Gary M. Gray Sadanandan E. Velu 《Journal of chemical crystallography》2009,39(12):902-907
Abstract
Details of the synthesis and crystal structure determination of (E)-2-(7-(3-(thiophen-2-yl)acrylamido)-2,3-dihydro-5-oxobenzo[e][1,4]oxazepin-1(5H)-yl)ethyl acetate are presented. The compound crystallizes in the triclinic P−1 space group (a = 8.3377(17), b = 9.792(2), c = 12.469(3) ?, α = 96.39(3)°, β = 108.50(3)°, γ = 97.68(3)°, V = 943.9(3) ?3, Z = 2). Interesting features of the structure include intermolecular hydrogen bonding between the amide proton on one molecule and the carbonyl oxygen of the dihydrooxazepinone ring on an adjacent molecule, the boat conformation of the dihydrooxazepinone ring, and π-π stacking between thiophene and phenyl rings on adjacent molecules with a distance between centroids of 3.79(2) ?. 相似文献77.
Hashmi S. A. Bhat Md Yasir Singh Manoj K. Sundaram N. T. Kalyana Raghupathy Bala P. C. Tanaka Hideaki 《Journal of Solid State Electrochemistry》2016,20(10):2817-2826
Journal of Solid State Electrochemistry - We report the studies on composite gel polymer electrolytes (GPEs) comprising 0.5 M solution of sodium trifluoromethane sulfonate (Na-triflate or... 相似文献
78.
Gollapalli Venkateswara Rao Santhosh R. Pindi Bollikolla Hari Babu Bala Murali Krishna Khandapu 《Journal of heterocyclic chemistry》2024,61(2):341-346
The present work describes the synthesis and characterization of six related compounds of cloxacillin sodium ( 1 ) viz penicilloic acid of cloxacillin (2) , (3-(2-chlorophenyl)-5-methylisoxazole-4-carbonyl) glycine (Glycine analogue of cloxacillin) (3), CMICAA adduct of cloxacillin (4) , (4S)-2-(carboxy(3-(2-chlorophenyl)-5-methylisoxazole-4-carboxamido) methyl)-3-(2-ethylhexanoyl)-5,5-dimethylthiazolidine-4-carboxylic acid (N-2-ethylhexanoyl penicilloic acid of cloxacillin) ( 5 ), N-Acetylated penicilloic acid of cloxacillin ( 6 ), and Cloxacillin Penicillamide (7) . These related compounds are very essential in the process development of cloxacillin sodium and are used as reference standards to determine the quality of the drug substance. 相似文献
79.
Cappillino PJ Miecznikowski JR Tyler LA Tarves PC McNally JS Lo W Kasibhatla BS Krzyaniak MD McCracken J Wang F Armstrong WH Caradonna JP 《Dalton transactions (Cambridge, England : 2003)》2012,41(18):5662-5677
Enzymes in the oxygen-activating class of mononuclear non-heme iron oxygenases (MNOs) contain a highly conserved iron center facially ligated by two histidine nitrogen atoms and one carboxylate oxygen atom that leave one face of the metal center (three binding sites) open for coordination to cofactor, substrate, and/or dioxygen. A comparative family of [Fe(II/III)(N(2)O(n))(L)(4-n))](±x), n = 1-3, L = solvent or Cl(-), model complexes, based on a ligand series that supports a facially ligated N,N,O core that is then modified to contain either one or two additional carboxylate chelate arms, has been structurally and spectroscopically characterized. EPR studies demonstrate that the high-spin d(5) Fe(III)g = 4.3 signal becomes more symmetrical as the number of carboxylate ligands decreases across the series Fe(N(2)O(3)), Fe(N(2)O(2)), and Fe(N(2)O(1)), reflecting an increase in the E/D strain of these complexes as the number of exchangeable/solvent coordination sites increases, paralleling the enhanced distribution of electronic structures that contribute to the spectral line shape. The observed systematic variations in the Fe(II)-Fe(III) oxidation-reduction potentials illustrate the fundamental influence of differential carboxylate ligation. The trend towards lower reduction potential for the iron center across the [Fe(III)(N(2)O(1))Cl(3)](-), [Fe(III)(N(2)O(2))Cl(2)](-) and [Fe(III)(N(2)O(3))Cl](-) series is consistent with replacement of the chloride anions with the more strongly donating anionic O-donor carboxylate ligands that are expected to stabilize the oxidized ferric state. This electrochemical trend parallels the observed dioxygen sensitivity of the three ferrous complexes (Fe(II)(N(2)O(1)) < Fe(II)(N(2)O(2)) < Fe(II)(N(2)O(3))), which form μ-oxo bridged ferric species upon exposure to air or oxygen atom donor (OAD) molecules. The observed oxygen sensitivity is particularly interesting and discussed in the context of α-ketoglutarate-dependent MNO enzyme mechanisms. 相似文献
80.
Polycrystalline ceramic samples of Bi2Sn2−xTixO7 (x=0.00, 0.2, 0.4, 0.6 and 0.8) have been synthesized by standard high temperature solid state reaction method. The effect of homovalent cation (titanium) substitution on the Sn-site on the structural and electrical properties of the pure Bi2Sn2O7 ceramic have been studied by X-ray diffraction followed by SEM, dielectric and dc conductivity studies. The structural analysis indicates that the increase of titanium contents do not lead to any secondary phase. The frequency and temperature dependent dielectric studies have been carried out. It is found that the Ti doping reduces the material particle size. The size of the particles are strongly influenced by the addition of titanium to the system. The substitution of Ti for Sn ions affected the degree of disorder and modified the dielectric properties leading to more resistive ceramic compounds. The activation energies of all the compounds were calculated using the relation σ=σ0exp(−Ea/kT). 相似文献