Fuzzy Hausdorff topological spaces

We introduce the notion of a fuzzy Hausdorff topological space and make a few observations to establish the appropriateness of this notion.     

Multiphonon relaxations in Ho3+:LaF3 single crystal

The mulliphonon transition rates in Ho³⁺:LaF₃ are estimated from the observed fluorescence decay rates of the states ⁵F₃ and (⁵F₄, ⁵S₂), in the temperature interval 80–675°K. The data is analyzed in terms of the existing theoretical models. The analysis indicates that the high energy phonons play a dominant role in these multiphonon transitions.     

Interplay of Anion-π+ and π+-π+ Interactions in Novel Pyrido[2,1-a]isoquinolinium-Based AIEgens - Substituent- and Counterion-Dependent Fluorescence Modulation and Applications in Live Cell Mitochondrial Imaging**

Recently, the concept of anion-π⁺ interactions has witnessed unique applications in the field of AIEgen development. In this contribution, we disclose a consolidated study of a library of N-doped ionic AIEgens accessed through silver-mediated cyclization of pyridino-alkynes. A thorough photophysical, computational and crystallographic study has been conducted to rationalize the observed substituent- and counterion-dependent fluorescence properties of these luminogens. We further elucidate the prominent role of anion-π⁺ interactions, π⁺-π⁺ interactions and other non-covalent interactions, in inhibiting the undesired ACQ effect. Finally, we have also demonstrated the application of selected AIEgens for imaging of mitochondria in live cells.     

Kinetics and mechanism of the oxidation of α-amino acids by n-bromoacetamide

The kinetics of the oxidation of eight α-amino adds by N-bromoacltanude have been studied in aqueous perchloric acid solution. The main products of the oxidation are the corresponding carbonyl compounds. The reaction is of first order with respect to the oxidant and the amino acid. The rate of oxidation decreases linearly with an increase in hydrogen ion concentration. The rate is decreased by the addition of acetamide. The oxidation of deuteriated glycine indicated the absence of a primary kinetic isotope effect. The reaction rate has been determined at different temperatures and activation parameters have been calculated. Hypobromous add has been postulated as the reactive oxidizing species. A rate-determining reaction of the neutral amino add and hypobromous add to give an N-bromo derivative has been proposed. The slow step is followed by a fast decomposition of the N-bromo derivative to yield the ultimate product.     

Role of photoadduct of K4Fe(CN)6 and C3H4N2 in improving thermal stability of polyaniline composite

This paper involves the synthesis of polyaniline composite with photoadduct of potassium hexacyanoferrate and imidazole via photochemical route by oxidative polymerization technique by ammonium persulphate. The photoadduct has been synthesized by photoirradiation followed by substitution with imidazole ligand. The photoaquation, substitution and successful synthesis has been proved by recording pH, UV visible spectra before and after irradiation and XRD of photoadduct. The as synthesized composite has been subjected to various characterizations like elemental analysis, UV–Visible spectra, FTIR, XRD, SEM, and TG/DTG. XRD of photoadduct shows crystalline structure which has been retained in the composite, changing the amorphous structure of polyaniline into the crystalline one, hence proving the insertion of photoadduct in the polymer chain. Various parameters like crystallite size (L), interplanar distance (d), micro strain (ε), dislocation density (δ) and distortion parameters (g) were calculated from XRD data. Thermal analysis shows the high thermal stability of composite which can be due to strong interaction between polymer chain and the photoadduct which restricts the thermal motion of polyaniline and thus enhances the thermal stability of composite.     

Stochastic nonlinear bending response of laminated composite plates with system randomness under lateral pressure and thermal loading

In this paper, the effect of sensitivity of randomness in system parameters on the nonlinear transverse central deflection response of laminated composite plates subjected to transverse uniform lateral pressure and thermal loading is examined. System parameters such as the lamina material properties, expansion of thermal coefficients, lamina plate thickness and lateral load are modelled as basic random variables. A higher order shear deformation theory in the von-Karman sense is used to model the system behavior of the laminated plate. A direct iterative-based C ⁰ nonlinear finite element method in conjunction with the first-order perturbation technique developed by the authors is extended for thermal problem to obtain the second-order response statistics, i.e., mean and variance of the nonlinear transverse deflection of the plate. Typical numerical results of composite plates with temperature independent and dependent material properties subjected to uniform temperature and combination of uniform and transverse temperature are obtained for various combinations of geometric parameters, uniform lateral pressures, staking sequences and boundary conditions. The results have been compared with those available in the literature and an independent Monte Carlo simulation.     

New three-component condensation reaction: synthesis of 1-[(alkylthio)(phenyl)methyl]-naphthalene-2-ol catalyzed by bromodimethylsulfonium bromide (BDMS)

Bromodimethylsulfonium bromide acts as an efficient catalyst for one pot three component condensation reactions of aldehydes, 2-naphthol, and thiols in acetonitrile at room temperature. Various aliphatic and aromatic thiols undergo conjugate addition with in situ generated enone in acetonitrile and provide good yields. The main features of this procedure are mild reaction conditions, good yields, and operational simplicity.     

CuBr(PPh3)3] for azide-alkyne cycloaddition reactions under strict Click conditions

A careful methodological study revealed a true Click catalytic system based on commercially available [CuBr(PPh(3))(3)]. This system is active at room temperature, with 0.5 mol % [Cu] (or less), in the absence of any additive, and it does not require any purification step to isolate pure triazoles.     

XPS and some surface characterizations of electrodeposited MgO nanostructure

Growth conditions, structural, and optical properties of MgO nanostructure have been investigated. Surface composition and shift in binding energy of Mg at 50.8 eV due to oxidation were examined by core‐level spectroscopy. The SEM showed that the film is dense, and grain growth and crystallinity are enhanced by post‐deposition annealing. Grain distribution was appraised within the confinement of 24.51 µm² from the selected scan areas. X‐ray diffraction studies indicated prominent peaks, which are attributed to (111), (200), and (220) reflections from fairly crystallized and randomly oriented MgO thin film. Plane (111) is found to be the preferred orientation of the film. The film transmitted well across the visible spectrum and the estimated energy band gap is 5.41 eV. Absence of catalyst in the electrolyte solution aided the purity of the sample. Copyright © 2014 John Wiley & Sons, Ltd.     

Novel aziridination of α-halo ketones: an efficient nucleophile-induced cyclization of phosphoramidates to functionalized aziridines

A novel and efficient aziridination of α-halo ketones is reported. The reaction of α-halo ketones with diethyl N-arylphosphoramidates affords diethyl N-aryl-N-(2-oxoalkyl)phosphoramidates which undergo reductive (H⁻-induced) cyclization with sodium borohydride followed by sodium hydride to give 1,2-disubstituted and 1,2,3-trisubstituted aziridines. The cyclization induced by NCS⁻ or PhS⁻ affords substituted aziridines functionalized at C-2. The reactions give excellent yields and are highly diastereoselective in favour of cis aziridines.