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381.
Saturated Red‐Light‐Emitting Gold(III) Triphenylamine Dendrimers for Solution‐Processable Organic Light‐Emitting Devices 下载免费PDF全文
Man‐Chung Tang Dr. Carmen Ka‐Man Chan Dr. Daniel Ping‐Kuen Tsang Yi‐Chun Wong Dr. Maggie Mei‐Yee Chan Dr. Keith Man‐Chung Wong Prof. Vivian Wing‐Wah Yam 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(46):15233-15241
A novel isoquinoline‐containing C^N^C ligand and its phosphorescent triphenylamine‐based alkynylgold(III) dendrimers have been synthesized. These alkynylgold(III) dendrimers serve as phosphorescent dopants in the fabrication of efficient solution‐processable organic light‐emitting devices (OLEDs). The photophysical, electrochemical, and electroluminescence properties were studied. A saturated red emission with CIE coordinates of (0.64, 0.36) and a high EQE value of 3.62 % were achieved. Unlike other red‐light‐emitting iridium(III) dendrimers, a low turn‐on voltage of less than 3 V and a reduced efficiency roll‐off at high current densities were observed; this can be accounted for by the enhanced carrier transporting ability and the relatively short lifetimes in the high‐generation dendrimers. This class of alkynylgold(III) dendrimers are promising candidates as phosphorescent dopants in the fabrication of solution‐processable OLEDs. 相似文献
382.
César A. Urbina-Blanco Safia Z. Jilani Isaiah R. Speight Michael J. Bojdys Tomislav Friščić J. Fraser Stoddart Toby L. Nelson James Mack Renã A. S. Robinson Emanuel A. Waddell Jodie L. Lutkenhaus Murrell Godfrey Martine I. Abboud Stephen O. Aderinto Damilola Aderohunmu Lučka Bibič João Borges Vy M. Dong Lori Ferrins Fun Man Fung Torsten John Felicia P. L. Lim Sarah L. Masters Dickson Mambwe Pall Thordarson Maria-Magdalena Titirici Gabriela D. Tormet-González Miriam M. Unterlass Austin Wadle Vivian W.-W. Yam Ying-Wei Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(42):18462-18466
383.
Derek P. Gates Chi-Wing Tsang Vincent A. Wright Mandy Yam 《Macromolecular Symposia》2003,196(1):271-278
The C=C bond plays numerous roles in polymer science. This moiety is used as a precursor to polymers by addition polymerization and has been incorporated into π-conjugated polymers. The addition polymerization reaction has been extended to P=C bonds and the first example of a poly(methylenephosphine) has been prepared. The new macromolecule is of moderate molecular weight (ca. 104 g/mol) and the oxidized polymers are air-stable. Poly(p-phenylenephosphaalkene), the first π-conjugated polymer containing P=C bonds in the backbone, has been prepared. The UV/Vis spectrum of this polymer shows a red shift in λmax when compared with molecular model systems. 相似文献