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81.
The stability of electrochemically formed NiF2 film in 1.0 M perchloric acid containing monovalent fluorides namely, NH4F, HF, NaF, KF and LiF, is investigated using cyclic voltammetry, chronoamperometry, atomic absorption spectroscopy and scanning
electron microscopy. In addition to direct dissolution of nickel and dissolution through the oxide layer, a new mode of dissolution
of NiF2 film as NiF3
− and NiF4
2− through complex formation is proposed. This process is significantly influenced by the alkali metal fluorides. On a comparative
basis the stability of NiF2 decreases in the order NH4F > HF > KF > LiF.
Received: 29 July 1998 / Accepted: 3 November 1998 相似文献
82.
Gounder Thangamani J. Deshmukh Kalim Sadasivuni Kishor Kumar Ponnamma Deepalekshmi Goutham Solleti Venkateswara Rao K. Chidambaram K. Basheer Ahamed M. Nirmala Grace A. Faisal Muhammad Khadheer Pasha S. K. 《Mikrochimica acta》2017,184(10):3977-3987
Microchimica Acta - The authors describe the preparation of PVA/WPPy/hBNNP nanocomposite films by solution casting method from poly(vinyl alcohol) (PVA), water soluble polypyrrole (WPPy), and using... 相似文献
83.
Ida Malarselvi Rajkumar Deepika Asaithambi Ramachandra Raja Chidambaram Priscilla Rajkumar 《合成通讯》2020,50(17):2617-2628
Abstract This enhancement in the activity may be efficient on the basis that ligands mainly possess CH=N bond. The use of a structure-based drug design approach (SBDD) provides a way for investigation as well as to understand the molecular basis of the target protein and ligand molecule interactions at the atomic level. Structure-based drug design is the design and optimization of a chemical structure to identify a compound suitable for clinical testing the drug candidates. Chitosan is a polysaccharide with recognized biological activities for improving the functionality of polysaccharide 5-Fluorosalicylaldehyde aniline system. The used for selectively oxidized chitosan to produce tailored derivatives. C-2-5-Fluorosalicylaldehyde-C-6 aniline double Schiff base derivatives of chitosan were synthesized. The structure and properties of the newly synthesized product were characterized by FT-IR, 1H-NMR, 13C-NMR, GC-Mass spectroscopy, and thermal analysis (DSC/TGA). An exothermic process discusses a DSC and TGA analysis of thermal behavior of this polymer was shown to be a possible thermal polymerization of the double bonds in the polymer chains and thermo-oxidation of the polymer. 相似文献
84.
C. Thivya S. Chidambaram R. Thilagavathi K. Tirumalesh M. Nepolian M. V. Prasanna 《Journal of Radioanalytical and Nuclear Chemistry》2017,313(3):603-609
Radon (222Rn) and other radionuclides in groundwater can lead to health problems if present in higher concentrations. A study was carried out in Madurai district of Tamilnadu by collecting groundwater samples for four different seasons and aims to identify the regions with higher 222Rn concentration along with their spatial and seasonal variations. 222Rn has been compared with field parameters, log pCO2, major ions and uranium to detect the factors responsible for the higher concentration in groundwater. The weathering process induces the release of higher uranium ions from the granitic terrain from the rock matrix which enhances the 222Rn levels in groundwater. 相似文献
85.
86.
Proceedings - Mathematical Sciences - 相似文献
87.
Chidambaram Prakash Govindan Ramakrishnan Chandramouli Venkatraman Koushik 《Journal of Thermal Analysis and Calorimetry》2012,110(3):1173-1177
In this study, the thermal properties of 100% cotton, 50/50 cotton/bamboo and 100% bamboo single jersey fabrics with differing yarn linear density are evaluated and analysed. The linear densities of the yarns composing the fabrics are 20s, 25s, 30s Nec and the twist level in the yarns is kept the same. An increasing the presence of bamboo fibre in the fabric causes a reduction in fabric thickness and GSM for all linear densities of yarn. Air permeability and water-vapour permeability also increase with increase in bamboo fibre content while both thermal conductivity and thermal resistance show a decreasing trend. As the constituent yarn gets finer, fabric air and water-vapour permeability both increase in value while the thermal conductivity falls. 相似文献
88.
C Gunanathan M Hölscher F Pan W Leitner 《Journal of the American Chemical Society》2012,134(35):14349-14352
The nonclassical ruthenium hydride pincer complex [Ru(PNP)(H)(2)(H(2))] 1 (PNP = 1,3-bis(di-tert-butyl-phosphinomethyl)pyridine) catalyzes the anti-Markovnikov addition of pinacolborane to terminal alkynes yielding Z-vinylboronates at mild conditions. The complex [Ru(PNP)(H)(2)(HBpin)] 2 (HBpin = pinacolborane), which was identified at the end of the reaction and prepared independently, is proposed as the direct precursor to the catalytic cycle involving rearrangement of coordinated alkyne to Z-vinylidene as a key step for the apparent trans-hydroboration. 相似文献
89.
90.
Sengodagounder Muthusamy Chidambaram Gunanathan Eringathodi Suresh 《Tetrahedron》2004,60(36):7885-7897
Regioselective intermolecular 1,3-dipolar cycloaddition reactions of rhodium generated carbonyl ylides with indoles are reported in this paper. Intermolecular 1,3-dipolar cycloaddition reactions of five-membered-ring cyclic carbonyl ylides with indole and substituted indoles afforded hexahydro-2H-carbazol-2-ones in a regioselective manner. Similarly, reactions of cyclic carbonyl ylides were carried out to afford decahydrobenzo[c]carbazoles or decahydrocyclopenta[c]carbazoles with high regioselectivity. Interestingly, the other possible regioisomer decahydrobenzo[a]carbazoles were also obtained by the reaction of cyclic carbonyl ylides and indoles having electron withdrawing substituents. The structure and stereochemistry of regioisomers 6,11c-epoxy-1,2,3,4,4a,5,6,6a,11b,11c-decahydro-4a-methyl-5-oxo-7H-benzo[c]carbazole and 11-benzenesulfonyl-6,11b-epoxy-2,3,4,4a,5,6,6a,11,11a,11b-decahydro-4a-methyl-5-oxo-1H-benzo[a]carbazole were unequivocally corroborated by single-crystal X-ray analyses. To advance this study, regioselective double 1,3-dipolar cycloaddition reaction of five-membered-ring cyclic carbonyl ylides has been demonstrated for the first time with biindoles having various aryl and alkyl spacers. This process constructed up to eight stereocenters, four carbon-carbon and two carbon-oxygen bonds in a single step with an excellent molecular complexity and stereoselectivity. 相似文献