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The hydrogen-bond interaction can be studied using a variety of spectroscopic and crystallographic techniques, as well as
theoretical studies based on quantum chemical principles, semi-empirical procedures, and statistical interpretations. A degree
of specificity, along with flexibility, provides H-bonded systems with a variety of unusual and interesting physical, chemical
and biological properties. Neutron diffraction is the method of choice for obtaining high-precision data on hydrogen-atom
positions and hydrogen-bond stereo-chemistry in crystals. Neutron inelastic scattering can provide information on the dynamics
of H-bonded systems. High-precision neutron diffraction studies on a variety of crystal hydrates, amino acids and small peptides,
development of semi-empirical potential functions for bent-hydrogen bonds, and statistical analysis of H-bond populations
associated with various donor and acceptor groups are some of the investigations on hydrogen bonding, carried out at Trombay
during the past three decades. 相似文献
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Ganesh KS Baskaran L Rajasekaran S Sumathi K Chidambaram AL Sundaramoorthy P 《Colloids and surfaces. B, Biointerfaces》2008,63(2):159-163
Water is seriously polluted by the discharge of various industrial wastewater containing heavy metals. Among them, chromium is considered to be toxic to living organisms and it is released mostly from tanneries. The chromium-contaminated water is discharged into nearby water bodies and it affects both aquatic and terrestrial plants. So the present experiment was conducted with an aquatic plant, water lettuce (Pistia stratiotes L.) and a terrestrial plant soybean (Glycine max L. Merr.). They were treated with different concentrations (0, 5, 10, 25, 50, 100 and 200mg/L) of potassium dichromate solution. The biochemical parameters such as total chlorophyll, carotenoid, protein and amino acid content and the enzymatic activities like catalase and peroxidase were estimated. The accumulation of chromium was also analysed in both the plants. All the biochemical contents and enzyme activities of water lettuce and soybean seedlings showed a great variation with respect to the increase in chromium concentrations. The accumulation of chromium increased gradually with the increase of chromium concentrations. Total inhibition of all the parameters were observed at 300 mg/L chromium concentration. The terrestrial plant soybean was sensitive than the aquatic plant water lettuce towards chromium stress. 相似文献
36.
Synthesis,characterization and optical properties of graphene oxide–polystyrene nanocomposites
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Kattimuttathu Suresh I. Krishnappan Chidambaram Vellorathekkaepadil Vinod Nutenki Rajender Reddy Mandapati Venkateswara Černík Miroslav 《先进技术聚合物》2015,26(3):214-222
The synthesis of graphene oxide (GO)–polystyrene (PS) Pickering emulsions, as environment‐friendly nanostructures suitable for novel applications, has received significant attention in recent years. In this work, the synthesis and characterization of GO–PS nanocomposites through seeded emulsion polymerization and the selective light reflection properties of dry films have been reported. Amphiphilic molecule sulfonated 3‐pentadecyl phenol was used as a co‐surfactant to stabilize GO dispersions during the emulsion polymerization process. The particle size of the dispersions as measured by dynamic light scattering decreases from 540 nm, for PS without any GO, to 88 nm with 1 wt% GO content. Scanning electron microscopy studies show a uniform size distribution of the composite particles prepared with GO. The dried films show a structural color that varies with the GO content. The self‐assembly behavior of the dried film was further studied using reflectance spectroscopy, which shows a red shift of the reflectance maximum from 440 to 538 nm as the GO loading was increased from 0.2 to 0.5 wt%, respectively, indicating a different microstructure. X‐ray diffraction, transmission electron microscopy (TEM) and atomic force microscopy (AFM) were used to study the morphology and structure of the composite particles on drying. The AFM study confirms the non‐spherical shape of the particles. Thermogravimetric analysis shows improved thermal decomposition characteristics of the nanocomposite films. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
37.
Abstract Most pressure induced phase transitions are diffusionless. Because of this, there exists a one-to-one correspondence between the positions of atoms in the parent and the product phases, which, therefore, show interesting symmetry relationships. In this paper, we have used these for discussing a symmetry classification of pressure induced phase transitions into four categories: iso-symmetric, group-subgroup, intersection group, and order-disorder transitions. Various examples illustrating this classification scheme are discussed. The importance of this classification is in understanding the mechanism of pressure indbced phase transitions, where both theoretical calculations and experimental measurements are employed to analyse related phenomena like softening of phonon modes, elastic instabilities, diffraction patterns, and orientation relations. 相似文献
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S. R. Mandan 《Acta Mathematica Hungarica》1962,13(1-2):25-34
Umbilical projection ([12], [14]) is a process suggested to derive results rather quickly in regard to four intersecting spheres [17] andn+1 intersecting hyperspheres in ann-space [18]. The same has been used with an advantage to deduce a porism on 2n+5 hyperspheres in ann-space [23]. The purpose of this paper is to concentrate on mutually orthogonal hyperspheres only and to illustrate simultaneously once again the utility and facility of this tool to arrive at a number of new and interesting results as follows:The 2(n+1) intersections ofn+1 mutually orthogonal hyperspheres in ann-space, takenn at a time, give rise to 2
n
pairs ofsemi-inverse [22] simplexes, perspective from their radical centreH, such that the 2
n
primes of perspectivity coincide with their 2
n
hyperplanes of similitude and form anS-configuration (S-C) [15] with theircentral simplex S(A) as itsdiagonal simplex. Everysimplex of intersection introduced here isisodynamic [25] such that itstangential simplex, circumscribed to it along circumhypersphere, is perspective to it from itsLemoine point L. ItsLemoine hyperplane l, as the polar prime ofL w. r. t. it, is the same as that of itscomplementary simplex of intersection and coincides whith their prime of perspectivity such that their 2(n+1) altitudes are met by their commonBrocard diameter through their Lemoine points. The 2
n
Brocard diameters of the 2
n
pairs of complementary simplexes of intersection concur atH. The
hyperspheres of antisimilitude of the given hyperspheres, having centres in a prime of similitude, form the commonNeuberg hyperspheres of the pair of semi-inverse simplexes, having this prime as their common Lemoine hyperplane, are consequently orthogonal to their cirumhyperspheres whose radical hyperplane, too, coincides whith this prime, and therefore belong to acoaxal net [15] passing through the pair of their commonNeuberg points on their common Brocard diameter. The second centres of similitude of the 2
n
pairs ofcomplementary hyperspheres of intersection form the 2
n
vertices of the dual [15] of the (S-C), whithS(A) as common diagonal simplex, as its polar reciprocal w. r. t. the common orthogonal hypersphere of then+1 hyperspheres, the first centres of similitude coinciding atH.Due inspiration is derived from the works ofCourt ([2]–[9]) on mutually orthogonal circles and spheres.
Presented by G. Hajós 相似文献