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61.
Cationic chiral palladium(ii) complexes are shown to catalyze the asymmetric coupling reaction of aryl boronates and aryl halides within a short period of time in good yield and enantioselectivity. 相似文献
62.
The spin-state-dependent reactivity, singlet versus triplet, of the 2-spiroepoxy-1,3-cyclopentane-1,3-diyl DR2 has been assessed through alcohol-trapping reactions for which the effect of solvent acidity on the product distribution of the alcohol trapping products 2 versus 3 + 4 and stereochemical deuterium-labeling studies have been performed. The proposed mechanism for the solvent effect on the product ratio (2/3 + 4) reveals the importance of the hydrogen-bonded intermediates I1 and I2 in the trapping reactions; the stereochemical deuterium-labeling results clarify the dipole structure trapped by the alcohol. The dipoles DP1 and DP2, in which the configuration between the epoxide oxygen and the deuterium atoms is retained, are inferred for the direct photodenitrogenation reactions (singlet state), whereas for the benzophenone-sensitized photoreactions (triplet state), after ISC, the ring-opened dipole DP3 is implied as the intermediate that is trapped by the alcohol. 相似文献
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64.
Kanai M Yasumoto M Kuriyama Y Inomiya K Katsuhara Y Higashiyama K Ishii A 《Organic letters》2003,5(7):1007-1010
[reaction: see text] The highly regioselective hydrogenolysis of bis(alpha-methylbenzyl)amine derivatives proceeded with influence not from the electronic effect but from the steric effect of the trifluoromethyl substituent on the aromatic ring to provide a practical asymmetric synthesis of trifluoromethyl-substituted alpha-phenylethylamines. 相似文献
65.
We have developed the mechanically controllable break junction setup with an electrochemical cell (EC-MCBJ) to measure the electric conductance of metal nanowires under electrochemical potential control. The electric conductance of Au nanowires was investigated in 0.1 M Na2SO4 solution using EC-MCBJ. The conductance of the Au nanowires was quantized in units of G0 (=2e2/h), showing clear features in the conductance histogram. The atomic contact with a specific conductance value was kept for >5 s, indicating the relatively high stability of the present EC-MCBJ system. 相似文献
66.
We propose and demonstrate an OCT optical probe using eccentric optics. This probe enabled both forward imaging and side imaging by dividing a circular scanning area into two semicircular scanning areas using an external motor to rotate the flexible tube. The outer diameter of the probe was 2.6 mm, and its rigid portion length was 10 mm. The lateral resolution was 23 μm, and the eccentric radius was 1.1 mm. The circumferential length in scanning was 6.9 mm, and the working distance was 5 mm. OCT images of 1.5 mm × 6.9 mm (in tissue, axial × circumference), including forward image and side image, were measured with the axial resolution of 19 μm in air and a frame rate of one frame per second. The epidermis, dermis, and sweat gland of in vivo human ventral finger tips were observed. 相似文献
67.
Manabu Nakazono Yasuyuki Sato Shigeo Hasegawa Norimasa Arisuda Aiko Miyamoto Kiyoshi Zaitsu 《Chromatographia》2009,70(5-6):933-937
Rapid separation of hydrophobic compounds such as bisindolylmaleimides, indolocarbazoles or fullerene C60 derivatives by ultra performance liquid chromatography was developed. Bisindolylmaleimides and indolocarbazoles were separated within 7 and 5 min, respectively. The linear ranges for the determination of bisindolylmaleimides and indolocarbazoles were 1.25?500 pmol and 0.5?50 pmol per injection (r > 0.99), respectively. Fullerene C60 derivatives were separated within 9 min, and the linear range for the determination of fullerene C60 derivatives was 0.1?10 pmol per injection (r > 0.99). 相似文献
68.
Koji Nuida Satoshi Fujitsu Manabu Hagiwara Takashi Kitagawa Hajime Watanabe Kazuto Ogawa Hideki Imai 《Designs, Codes and Cryptography》2009,52(3):339-362
It has been proven that the code lengths of Tardos’s collusion-secure fingerprinting codes are of theoretically minimal order
with respect to the number of adversarial users (pirates). However, the code lengths can be further reduced as some preceding
studies have revealed. In this article we improve a recent discrete variant of Tardos’s codes, and give a security proof of
our codes under an assumption weaker than the original Marking Assumption. Our analysis shows that our codes have significantly
shorter lengths than Tardos’s codes. For example, when c = 8, our code length is about 4.94% of Tardos’s code in a practical setting and about 4.62% in a certain limit case. Our
code lengths for large c are asymptotically about 5.35% of Tardos’s codes.
A part of this work was presented at 17th Applied Algebra, Algebraic Algorithms, and Error Correcting Codes (AAECC-17), Bangalore,
India, December 16–20, 2007. 相似文献
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