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161.
Takeo Tomita Mamoru Takahashi Masaki Sasaki Hiroshi Sakamoto Masahiro Takahashi Hiroshi Tamura 《Shock Waves》2009,19(3):213-228
During development tests of the LE-7A prototype engine, severe side-loads were observed. The side-load peaks appeared only
in certain limited conditions during start-up and shut-down transients. To investigate phenomena causing those severe side-loads
observed in the LE-7A prototype engine nozzle, series of cold-flow tests and hot-firing tests as well as CFD analyses were
conducted. As a result of the hot-firing tests, two different phenomena were found to cause severe side-loads in the LE-7A
prototype engine nozzle. One was a restricted shock separation (RSS) flow structure and the other was a phenomenon termed
“separation jump,” the rapid movement of the separation location in the vicinity of the step. A step was installed in the
LE-7A prototype to supply film-cooling gas. Hot-firing test results showed that RSS can occur for a limited mixture ratio.
Detailed flow structure of RSS on the nozzle surface was revealed by the cold-flow tests. Measured pressures and visualized
images of cold-flow tests clarified the mechanism causing the separation jump. The key phenomenon ruling the separation jump
was found to be the base flow behind the step. Based on the results of the present study, the latest LE-7A engine nozzle design
has been changed to eliminate the severe side-load.
相似文献
相似文献
162.
163.
α,β-Unsaturated ketones were obtained from alkylphenylketene and aroyl chloride via decarbonylation reaction in the presence of catalytic amounts of tetrakis(triphenylphosphine) palladium. 相似文献
164.
Masaru Sakai Shuji Mononobe Shusaku Akiba Akifumi Matsuda Wakana Hara Mamoru Yoshimoto Toshiharu Saiki 《Optical Review》2006,13(4):266-268
We demonstrated a contrast enhancement in a near-field scanning optical microscope (NSOM) by optical interference with an
aperture probe in reflection (illumination-collection) mode operation. We observed a NiO film deposited on a sapphire substrate
and clearly visualized 2-nm-deep nano-channel structures on the surface of the film. The reflection NSOM enhanced by optical
interference is quite a promising instrument for high-resolution optical detection and estimation of low-contrast nanostructures. 相似文献
165.
Michiharu Mitani Mamoru Tamada Shin-ichi Uehara Kikuhiko Koyama 《Tetrahedron letters》1984,25(26):2805-2808
Phenyl alkyl ketones were photo-irradiated in the presence of Cr(VI) or Mn(VII) oxidants to yield 1,4-dicarbonyl compounds regiospecifically while 2-octanone gave a regioisomeric mixture of 2,5-, 2,6-, and 2,7-octadiones. 相似文献
166.
167.
Hara M Samori S Xichen C Fujitsuka M Majima T 《The Journal of organic chemistry》2005,70(11):4370-4374
Formation and decay of radical cations of trans-stilbene and p-substituted trans-stilbenes (S.+) during the resonant two-photon ionization (TPI) of S in acetonitrile in the presence and absence of O(2) have been studied with laser flash photolysis using a XeCl excimer laser (308 nm, fwhm 25 ns). The transient absorption spectra of S.+ were observed with a peak around 470-490 nm. The formation quantum yield of S.+ (0.06-0.29) increased with decreasing oxidation potential (E(ox)) and increasing fluorescence lifetime (tau(f)) of S, except for trans-4-methoxystilbene which has the lowest E(ox) and longer tau(f) among S. The considerable low yield and fast decay in a few tens of nanoseconds time scale were observed for trans-4-methoxystilbene.+ in the presence of O(2), but not for other S.+ . It is suggested that formation of the ground-state complex between trans-4-methoxystilbene and O(2) and the distonic character of trans-4-methoxystilbene.+ with separation and localization of the positive charge on the oxygen of the p-methoxyl group and an unpaired electron on the beta-olefinic carbon are responsible for the fast reaction of trans-4-methoxystilbene.+ with O(2) or superoxide anion, leading to the considerable low yield and fast decay of trans-4-methoxystilbene.+ . The mechanism based on the transient absorption measurement of S.+ during the TPI is consistent with the relatively high oxidation efficiency of trans-4-methoxystilbene among S based on the product analysis during the photoinduced electron transfer in the presence of a photosensitizer such as 9,10-dicyanoanthracene and O(2) in acetonitrile. 相似文献
168.
Hasegawa T Kim S Tsuchida M Issiki Y Kondo S Sugibayashi K 《Chemical & pharmaceutical bulletin》2005,53(3):271-276
The inhibitory effect of poly(2-methacryloyloxyethyl phosphorylcholine-co-butylmetacrylate) (PMB) on the in vitro skin permeation of p-hydroxybenzoic acid and its esters (parabens; methylparaben, ethylparaben, n-propylparaben and n-butylparaben) as model compounds was evaluated. Solubility of the parabens in distilled water was increased by addition of PMB, and the increasing ratio was dependent on the concentration of PMB. The increment of the ratio was more marked in lipophilic parabens than hydrophilic ones. Skin permeability of parabens from their aqueous suspensions was decreased by addition of PMB, and the decreasing ratio was dependent on the PMB concentration. Then, antibacterial effect of parabens of their aqueous solutions was determined with and without PMB by measuring minimum inhibitory concentration (MIC) against E. coli and S. aureus. As results, MIC and antibacterial effect were increased and decreased, respectively, by addition of PMB. The contribution of PMB was more marked in butylparaben than methylparaben. These decreases in skin permeation and antibacterial effect of parabens by PMB are probably due to a higher solubility in water and a lower partition to the skin and bacterial membranes of parabens by addition of PMB. 相似文献
169.
Oseki Y Fujitsuka M Cho DW Sugimoto A Tojo S Majima T 《The journal of physical chemistry. B》2005,109(41):19257-19262
Photoinduced intramolecular charge separation (CS) and recombination (CR) processes of the tetrathiophene-substituted benzene dyads with an amide spacer (4T-PhR, R = 4-H (1), 4-CN (2), 3,4-(CN)2 (3), 4-NO2 (4), 3,5-(NO2)2 (5)) in solvents of different polarities were investigated using various fast spectroscopies. It was revealed that the CS rates depend on the ability of the acceptor and solvent polarity. Ultrafast CS with the rate of 5 x 10(12) s(-1) was revealed for 5 in PhCN and MeCN. The ultrafast CS can be attributed to the large electronic coupling matrix element between the donor and the acceptor despite the relative long donor-acceptor distance. The existence of the state with large electron density on the spacer between 14T*-PhR and LUMO should facilitate the CS process in the present dyad system. It was also revealed that the CR rates in these dyads were rather fast because of the enhanced superexchange interaction through the amide spacer. 相似文献
170.
Mamoru Nomura Yasunobu Minamino Kazumi Fujita Makoto Harada 《Journal of polymer science. Part A, Polymer chemistry》1982,20(5):1261-1270
The effect of chain transfer agents on the nucleation and growth of polymer particles in the emulsion polymerization of styrene were examined extensively. The chain transfer agents used are carbon tetrachloride, carbon tetrabromide, and four primary mercaptans (C2, n-C4, n-C7, and n-C12). It is shown that with an increase in the amount of chain transfer agents charged the rate of polymerization per particle decreases progressively. The number of polymer particles formed, on the other hand, increases initially then decreases. These effects can be enhanced by using a chain transfer agent with higher values of chain transfer constant and solubility in water. It is also demonstrated that with increasing radical desorption from the particles, aided by chain transfer agents, the emulsifier dependence exponent for the number of polymer particles formed increases from 0.6 to 1.0 and the initiator dependence exponent decreases from 0.4 to 0. The effect of chain transfer agents on the nucleation and growth of polymer particles in the emulsion polymerization of styrene can be explained in terms of desorption of chain-transfered radicals from the polymer particles. 相似文献