首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   931篇
  免费   18篇
  国内免费   1篇
化学   521篇
晶体学   1篇
力学   23篇
数学   198篇
物理学   207篇
  2024年   8篇
  2023年   20篇
  2022年   16篇
  2021年   29篇
  2020年   40篇
  2019年   31篇
  2018年   13篇
  2017年   23篇
  2016年   40篇
  2015年   26篇
  2014年   37篇
  2013年   61篇
  2012年   51篇
  2011年   57篇
  2010年   42篇
  2009年   35篇
  2008年   37篇
  2007年   38篇
  2006年   28篇
  2005年   29篇
  2004年   25篇
  2003年   28篇
  2002年   9篇
  2001年   13篇
  2000年   10篇
  1999年   9篇
  1998年   8篇
  1997年   5篇
  1996年   13篇
  1995年   7篇
  1994年   14篇
  1993年   12篇
  1992年   8篇
  1991年   8篇
  1990年   5篇
  1989年   5篇
  1988年   3篇
  1987年   3篇
  1985年   10篇
  1984年   5篇
  1983年   8篇
  1981年   9篇
  1980年   3篇
  1979年   5篇
  1976年   7篇
  1970年   3篇
  1969年   3篇
  1968年   4篇
  1957年   3篇
  1956年   3篇
排序方式: 共有950条查询结果,搜索用时 0 毫秒
101.
Second order elliptic operators and their parabolic counterparts are studied in the case of complete boundary degeneration of the leading order coefficients in the presence of a strong outward pointing drift. It is shown that the problem generates a positive analytic \(C_0\)-semigroup with maximal \(L_p\)-regularity in \(L_q\)-spaces. This result is based on hard analysis estimates for integral operators in combination with modern functional analytic tools like \({\mathcal R}\)-boundedness and the operator-valued functional calculus.  相似文献   
102.
Vorwort     
Ohne Zusammenfassung  相似文献   
103.
104.
Ohne Zusammenfassung  相似文献   
105.
    
Dielectrophoresis (DEP) is an AC electrokinetic effect that is proven to be effective for the immobilization of not only cells, but also of macromolecules, for example, antibodies and enzyme molecules. In our previous work, we have already demonstrated the high catalytic activity of immobilized horseradish peroxidase after DEP. To evaluate the suitability of the immobilization method for sensing or research in general, we want to test it for other enzymes, too. In this study, glucose oxidase (GOX) from Aspergillus niger was immobilized on TiN nanoelectrode arrays by DEP. Fluorescence microscopy showed the intrinsic fluorescence of the immobilized enzymes flavin cofactor on the electrodes. The catalytic activity of immobilized GOX was detectable, but a fraction of less than 1.3% of the maximum activity that was expected for a full monolayer of immobilized enzymes on all electrodes was stable for multiple measurement cycles. Therefore, the effect of DEP immobilization on the catalytic activity strongly depends on the used enzyme.  相似文献   
106.
107.
108.
    
Facing the challenge of lignin valorization is one of the unsolved key steps for a sustainable and economically feasible biorefinery. Several processes were developed with the aim of producing value-added compounds from lignin. Thermal, enzymatic, and catalytic processes represent common techniques for lignin valorization. However, expensive catalysts or enzymes and harsh conditions hampered the implementation of these methodologies on an industrial scale. Here, we propose the utilization of a simple “swiss-roll” electrochemical reactor for the production of valuable carboxylic acids. We showcase that production of phenolic compounds, such as vanillin, is hindered by the electrochemical mechanism. Additionally, electrochemical stability experiments of possible products showed high reactivity of vanillin against the low reactivity of mono- and dicarboxylic acids. Simultaneously, the electrochemical process leads to stable carboxylic acids with high yields of 6.4, 26.8, and 4.2 % for oxalic, formic, and acetic acids, respectively, thus representing a competitive alternative to the catalytic and hydrothermal degradation process for the production of carboxylic acids.  相似文献   
109.
    
A series of metal‐mediated cages, having multiple cavities, was synthesized from PdII cations and tris‐ or tetrakis‐monodentate bridging ligands and characterized by NMR spectroscopy, mass spectrometry, and X‐ray methods. The peanut‐shaped [Pd3L14] cage deriving from the tris‐monodentate ligand L1 could be quantitatively converted into its interpenetrated [5Cl@Pd6L18] dimer featuring a linear {[Pd‐Cl‐]5Pd} stack as an unprecedented structural motif upon addition of chloride anions. Small‐angle neutron scattering (SANS) experiments showed that the cigar‐shaped assembly with a length of 3.7 nm aggregates into mono‐layered discs of 14 nm diameter via solvophobic interactions between the hexyl sidechains. The hepta‐cationic [5Cl@Pd6L18] cage was found to interact with polyanionic oligonucleotide double‐strands under dissolution of the aggregates in water, rendering the compound class interesting for applications based on non‐covalent DNA binding.  相似文献   
110.
    
The behavior of a fishing fleet and its impact onto the biomass of fish can be described by a nonlinear parabolic diffusion–reaction equation. Looking for an optimal fishing strategy leads to a non-convex optimal control problem with a bilinear control action. In this work, we present such an optimal control formulation, prove its well-posedness and derive first- and second-order optimality conditions. These results provide a basis for tailored finite element discretization as well as for Newton type optimization algorithms. First numerical test problems show typical features as so-called No-Take-Zones and maximal fishing quota (total allowable catches) as parts of an optimal fishing strategy.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号