首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   279篇
  免费   25篇
化学   207篇
力学   5篇
数学   41篇
物理学   51篇
  2023年   6篇
  2022年   4篇
  2021年   14篇
  2020年   23篇
  2019年   18篇
  2018年   1篇
  2017年   4篇
  2016年   22篇
  2015年   11篇
  2014年   21篇
  2013年   17篇
  2012年   22篇
  2011年   27篇
  2010年   20篇
  2009年   10篇
  2008年   16篇
  2007年   17篇
  2006年   8篇
  2005年   7篇
  2004年   3篇
  2003年   2篇
  2002年   2篇
  2000年   2篇
  1999年   1篇
  1998年   1篇
  1997年   2篇
  1995年   1篇
  1994年   1篇
  1993年   3篇
  1992年   2篇
  1991年   2篇
  1990年   2篇
  1988年   1篇
  1986年   1篇
  1985年   1篇
  1984年   1篇
  1976年   3篇
  1971年   2篇
  1970年   2篇
  1968年   1篇
排序方式: 共有304条查询结果,搜索用时 171 毫秒
81.
Manufacturers in a wide range of industries nowadays face the challenge of providing a rich product variety at a very low cost. This typically requires the implementation of cost efficient, flexible production systems. Often, so called mixed-model assembly lines are employed, where setup operations are reduced to such an extent that various models of a common base product can be manufactured in intermixed sequences. However, the observed diversity of mixed-model lines makes a thorough sequence planning essential for exploiting the benefits of assembly line production. This paper reviews and discusses the three major planning approaches presented in the literature, mixed-model sequencing, car sequencing and level scheduling, and provides a hierarchical classification scheme to systematically record the academic efforts in each field and to deduce future research issues.  相似文献   
82.
83.
In a mixed-model assembly line, varying models of the same basic product are to be produced in a facultative sequence. This results to a short-term planning problem where a sequence of models is sought which minimizes station overloads. In practice – e.g. the final assembly of cars – special sequencing rules are enforced which restrict the number of models possessing a certain optional feature k to rk within a subsequence of sk successive models. This problem is known as car sequencing. So far, employed solution techniques stem mainly from the field of Logic and Constraint Logic Programming. In this work, a special Branch & Bound algorithm is developed, which exploits the problem structure in order to reduce combinatorial complexity.  相似文献   
84.
1,4‐Di(isopropyl)‐1,4‐diazabutadiene as a Reagent for the Trapping of Monomeric Fragments of the Tetragalliumcluster Ga4[C(SiMe3)3]4 – Formation of an Unsaturated GaN2C2 Heterocycle and an Oxidation Product Containing a Ga‐O‐O‐Ga Group The tetrahedral tetragallium cluster Ga4[C(SiMe3)3]4 ( 1 ) dissociates upon dissolution to yield the monomeric fragments Ga‐R [R = C(SiMe3)3]. These monomers could be trapped now by the treatment of their solutions with 1,4‐di(isopropyl)‐1,4‐diazabutadiene. The product of the cycloaddition reaction ( 2 ) possesses a five‐membered GaN2C2 heterocycle with a coordinatively unsaturated gallium atom and an endocyclic C=C double bond. 2 is rather sensitive towards oxidation by traces of air. The contact with oxygen yielded a digallium peroxide [(C2N2iPr2)RGa‐O‐O‐GaR(C2N2iPr2)] ( 3 ) which was isolated in a very low yield only and which has a gallium atom attached to each oxygen atom of the inner peroxo group. Both chelating ligands of 3 possess an unpaired electron.  相似文献   
85.
The reaction of the titanium imido complex 1b with 2-butyne leads to the formation of the titanium azadiene complex 2a at ambient temperature instead of yielding the archetypical [2 + 2] cycloaddition product (titanaazacyclobutene) which is usually obtained by combining titanium imido complexes and internal alkynes. The formation of 2a is presumably caused by an initial propargylic C(sp3)–H activation step and quantum chemical calculations suggest that the outcome of this unexpected reactivity is thermodynamically favored. The previously reported titanaazacyclobutene I (which is obtained by reacting 1b with 1-phenyl-1-propyne) undergoes a rearrangement reaction at elevated temperature to give the corresponding five-membered titanium azadiene complex 2b.

An unexpected reactivity between a titanium imido complex and internal alkynes was unveiled yielding titanaazacyclobutenes instead of the expected [2 + 2] cycloaddition products.  相似文献   
86.
87.
88.
89.
90.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号