全文获取类型
收费全文 | 124887篇 |
免费 | 1527篇 |
国内免费 | 456篇 |
专业分类
化学 | 68533篇 |
晶体学 | 2035篇 |
力学 | 4955篇 |
综合类 | 5篇 |
数学 | 12104篇 |
物理学 | 39238篇 |
出版年
2016年 | 1272篇 |
2015年 | 982篇 |
2014年 | 1319篇 |
2013年 | 4781篇 |
2012年 | 3376篇 |
2011年 | 4383篇 |
2010年 | 2733篇 |
2009年 | 2513篇 |
2008年 | 3922篇 |
2007年 | 3977篇 |
2006年 | 4036篇 |
2005年 | 3962篇 |
2004年 | 3453篇 |
2003年 | 3151篇 |
2002年 | 3053篇 |
2001年 | 3570篇 |
2000年 | 2674篇 |
1999年 | 2196篇 |
1998年 | 1884篇 |
1997年 | 1872篇 |
1996年 | 1802篇 |
1995年 | 1774篇 |
1994年 | 1545篇 |
1993年 | 1533篇 |
1992年 | 1755篇 |
1991年 | 1746篇 |
1990年 | 1677篇 |
1989年 | 1683篇 |
1988年 | 1684篇 |
1987年 | 1674篇 |
1986年 | 1591篇 |
1985年 | 2136篇 |
1984年 | 2272篇 |
1983年 | 1899篇 |
1982年 | 2218篇 |
1981年 | 2027篇 |
1980年 | 2078篇 |
1979年 | 2058篇 |
1978年 | 2191篇 |
1977年 | 2092篇 |
1976年 | 2119篇 |
1975年 | 2054篇 |
1974年 | 1901篇 |
1973年 | 2104篇 |
1972年 | 1284篇 |
1971年 | 975篇 |
1970年 | 912篇 |
1969年 | 923篇 |
1968年 | 1050篇 |
1967年 | 1101篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
Jeroen J. L. M. Cornelissen W. Sander Graswinckel Alan E. Rowan Nico A. J. M. Sommerdijk Roeland J. M. Nolte 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1725-1736
The conformational properties of polymers derived from isocyanodipeptides have been investigated with a combination of model calculations, X‐ray diffraction, and circular dichroism spectroscopy. Depending on the configuration of the side chains, defined arrays of hydrogen bonds along the polymeric backbone are formed. This leads to a well‐defined conformation as, for example, expressed in the formation of lyotropic liquid‐crystalline phases and increased helical stability. Upon the disruption of the hydrogen bonds by a strong acid, a less well‐defined macromolecular conformation is observed. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1725–1736, 2003 相似文献
72.
M Lepère R Gobeille V.Malathy Devi M.A.H Smith B Aoaeh A.W Mantz 《Journal of Molecular Spectroscopy》2004,224(1):7-12
We have analyzed the methyl fluoride RQ(J,0)Q branch lines located near 1475 cm−1 using a simultaneous multi-spectrum fitting technique. In this analysis we have used previously recorded diode-laser data in which we collected many data points covering only one or two Q branch lines in a particular run. The analysis consists of simultaneously fitting 57 spectra collected with numerous pressure and path length conditions for all absorption lines. The data are concatenated to create one continuous spectrum of the Q branch. We have determined the intensity and self-broadened widths at 296 K for 23 RQ(J,0) lines. 相似文献
73.
M. Stangl V. Dittel J. Acker V. Hoffmann W. Gruner S. Strehle K. Wetzig 《Applied Surface Science》2005,252(1):158-161
At room temperature electroplated copper layers exhibit changes in resistivity, residual stress, and microstructure. This process, known as self-annealing, is intimately linked to the release of organic impurities, which stem from the incorporation of organic additives into the Cu layer in the course of the electroplating process. The behavior of these impurities during self-annealing, represented by the carbon content, could be detected by analytical radio frequency glow discharge optical emission spectrometry (GD-OES) and carrier gas hot extraction (CGHE). The precondition of a quantitative determination is a surface cleaning procedure to remove adsorbed organics from the copper surface. It was observed that at first almost all impurities have to leave the Cu metallization before an accelerated abnormal grain growth can start. The small amount of remaining organic species after self-annealing could be quantified by both examination techniques, GD-OES and CGHE. 相似文献
74.
W. Hampe 《Fresenius' Journal of Analytical Chemistry》1885,24(1):588-590
Ohne Zusammenfassung 相似文献
75.
76.
Blood serum samples were irradiated by monochromatic synchrotron radiation (15 keV) and by 2.4-MeV protons to compare their performance for the detection of trace elements by x-ray fluorescence (XRF) spectrometry. Absolute concentration assignment was based on the addition of an internal standard and on a method which uses the incoherent and coherent radiation as a flux monitor of the incoming beam. Preliminary experiments with a synchrotron XRF microprobe are reported. 相似文献
77.
In this paper we obtain a number of Maharam-type slice integral representations, with respect to scalar measures, for positive
projections in Dedekind complete vector lattices and f-algebras.
AMS Classification: 47B65, 46A40, 06F25 相似文献
78.
H E Cline W E Lorensen R J Herfkens G A Johnson G H Glover 《Magnetic resonance imaging》1989,7(1):45-54
A three-dimensional examination of blood vessels is provided using MR data from seven cases. The vascular surfaces are constructed with an algorithm that automatically follows the selected artery or vein and generates a projected three-dimensional gradient shaded image. Fast 3DFT pulse sequences were optimized to enhance the time-of-flight contrast of the intravascular region. By increasing the surface threshold value in a three-dimensional head study, the flesh of a patient's face was peeled away to demonstrate the superfacial temporal artery. Gated cardiac images show the great vessels and cardiac chambers. A three-dimensional view of the aorta shows an irregular surface in the vicinity of an adrenal tumor. 3D MR exams provide a non-invasive technique for assessing vascular morphology in a clinical setting. 相似文献
79.
Michael T. Jury David W. Kribs 《Proceedings of the American Mathematical Society》2005,133(1):213-222
Given a row contraction of operators on a Hilbert space and a family of projections on the space that stabilizes the operators, we show there is a unique minimal joint dilation to a row contraction of partial isometries that satisfy natural relations. For a fixed row contraction the set of all dilations forms a partially ordered set with a largest and smallest element. A key technical device in our analysis is a connection with directed graphs. We use a Wold decomposition for partial isometries to describe the models for these dilations, and we discuss how the basic properties of a dilation depend on the row contraction.
80.
Catalytic properties of silica-supported heteropolyacids (HPA) in a mechanical mixture with reduced Me-Ce oxides (Me = Ni,
Pd) in n-hexane isomerization are studied. The role of each component of the mixed oxides (Ce and, typically, Ni and Pd) and their
optimum content has been illuminated: cerium is not only beneficial for eliminating or preventing coke deposition but is also
effective for maintaining the Keggin structure of the highly-organized HPA during the reaction and probably allows a better
dispersion of the second metal species. Nickel and palladium, present as Ni0 and Pd0, reinforce the activation of the alkane, which is difficult to obtain by means of a direct attack by an acid, and, thus,
enhance noticeably the activity of the catalyst. The best mechanical mixtures are obtained with 30–70 wt % NiCeO-HPW/SiO2 and 50–50 wt % Pd0.1CeO-HPW/SiO2. These mixtures have the highest efficiency for a Ni/(Ni + W) atomic ratio of 0.66 and a Pd/(Pd + W) ratio of 0.40, respectively.
Finally, the conversion of n-hexane is in the order HPW > HSiW > HBW, which seems to be consistent with the order of their acid strength as per the literature,
but the isomerization selectivity appears to be slightly higher on HSiW.
Published in Russian in Kinetika i Kataliz, 2006, Vol. 47, No. 1, pp. 24–28.
The text was submitted by the authors in English. 相似文献