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111.
Evan W. Muller Alfred A. Burney-Allen Jessica Shaw David L. Wheeler Volodimyr Duzhko Malika Jeffries-EL 《Journal of polymer science. Part A, Polymer chemistry》2020,58(9):1299-1310
The use of direct C H arylation cross-coupling polymerization was evaluated for the synthesis of donor–acceptor conjugated co-polymers using the novel donor 1,6-didecylnaphtho[1,2-b:5,6-b']difuran and either thieno[3,4-c]pyrrole-4,6-dione (TPD) or 1,4-diketopyrrolo[3,4-c]pyrrole (DPP) as the acceptor. Thiophene and furan moieties were used to flank the DPP group and the impact of these heterocycles on the polymers' properties was evaluated. The alkyl chains on the diketopyrrolopyrrole monomers were varied to engineer the solubility and morphology of the materials. All of the polymers have similar optoelectronic properties with narrow optical band gaps around 1.3 eV, which is ideal for solar energy harvesting. Unfortunately, these polymers also had high-lying highest occupied molecular orbital levels of −4.8 to −5.1, and as a result bulk-heterojunction photovoltaic cells fabricated using the soluble fullerene derivative PC71BM as the electron-acceptor and these polymers as donor materials exhibited poor performance due to limited Voc values. An examination of the films from these blends indicates that film-thickness and morphology were also a major hindrance to performance and a potential point of improvement for future materials. 相似文献
112.
Dr. Arianna Pina Malika Kadri Dr. Daniela Arosio Dr. Alberto Dal Corso Dr. Jean-Luc Coll Prof. Dr. Cesare Gennari Dr. Didier Boturyn 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(33):7492-7496
The use of multimeric ligands is considered as a promising strategy to improve tumor targeting for diagnosis and therapy. Herein, tetrameric RGD (Arg-Gly-Asp) peptidomimetics were designed to target αvβ3 integrin-expressing tumor cells. These compounds were prepared by an oxime chemoselective assembly of cyclo(DKP-RGD) ligands and a cyclodecapeptide scaffold, which allows a tetrameric presentation. The resulting tetrameric RGD peptidomimetics were shown to improve αvβ3 integrin binding compared with the monomeric form. Interestingly, these compounds were also able to enhance tumor cell endocytosis in the same way as tetrameric RGD peptides. Altogether, the results show the potential of the tetrameric cyclo(DKP-RGD) ligands for in vivo imaging and drug delivery. 相似文献
113.
Amadou Thierno Diallo Malika Tlemçani Memona Khan Jolanda Spadavecchia Nadia Djaker 《Particle & Particle Systems Characterization》2020,37(12):2000255
Complex-shaped nanoparticles as gold nanourchins (GNU) and nanorods (GNR) are very suitable agents in the case of photothermal therapy due to their photon-heat conversion ability in the red and near-infrared region (NIR). The quantification in heat generation of complex shaped nanostructures is an important key to predict the therapeutic effect of these nanoparticles. For that, the determination of the nanoparticles absorption cross section (σAbs) responsible for the heat generation is one of the important steps before any application. Although it is obvious to determine σAbs for spheres via Mie's theory, in the case of complex structures like GNU or GNR, this parameter is difficult to model. In this work, a new methodology is used to determine experimentally σAbs for both GNU and GNR. Experimental measurements of the photothermal properties of 100 nm size GNU and two different sizes of GNRs are studied regarding different parameters such as concentration, laser excitation wavelength, and exposure time. By using the heat transfer theory, the temperature elevation in the nanoparticles solutions is converted to temperature elevation at the nanoparticles surface and σAbs values are then calculated for both GNU and GNR in the NIR spectral region. 相似文献
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115.
On the dissociation constants of successive acidities of the diacid 7-para carboxy anilino-4-nitrobenzofurazane. The first dissociation constant of the 7-para carboxy anilino-4-nitrobenzofurazane noted 4H,COOH, in dimethylsulfoxyde was estimated using an NMR method. Diacid 4H,COOH was prepared by simple reaction of aromatic nucleophilic substitution (SNAr) and monopotassium salt and was precipitated by chloroform addition to a solution of 4H,COOH in Me2SO, after neutralisation of an acid function by one equivalent of solid potassium bicarbonate. Initially, a titration NMR 1H of two acidities of 4H,COOH was carried out in Me2SO-d6 by the strong base potassium tert-butoxide. After, we showed that ionization NH/N− is carried out completely before that of function COOH. We could estimate the first dissociation constant (7.5) of 4H,COOH in dimethylsulfoxyde by using the 9-cyano fluorene as a reference compound. 相似文献
116.
An arbitrary policy of fixing the number of outpatient appointments specifying the dates (and not the exact times) of appointments created long queues and large waiting times in some departments of the Ibn-Rochd health centre, but considerable idle time for the consulting doctors in others. After narrating in detail these circumstances and examining a number of possible options, this paper describes the scientific approaches made to determine the number of appointments, the corresponding parameters of the queue and the system and the service per cent occupation.Finite source size, a random number of initial patients, group arrivals, non-exponential service time distribution, late start-up of the servicing unit and many other factors combined to render available theoretical results difficult to apply and results obtained by applying approximately equivalent theoretical models unreliable as compared with those observed in real life. It is shown that simulation could be more profitably applied in such situations. 相似文献
117.
Arabi Malika Elias Abdelhamid Kamel Ziane Ait younes Yasmine Mansouri Belkacem Toumert Idir 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(2):1095-1106
Journal of Radioanalytical and Nuclear Chemistry - Gamma irradiation was applied to olive mill wastewater and synthetic samples prepared from Gallic acid. The effects, generated on the... 相似文献
118.
A selective and sensitive derivative method has been proposed for the simultaneous determination of trace amounts of Co(II) and Ni(II) with morpholinedithiocarbamate (MDTC) in the presence of sodium lauryl sulphate (SLS). The molar absorption coefficients of the 1:2 complex of Co(II) and Ni(II) at 326 nm and 322 nm are 2.248 × 104 and 2.505 × 104 L mol?1 cm?1 for zero order. The analytical sensitivity for the second derivative of Co(II) and Ni(II) complexes are 0.0044 μg mL?1 and 0.0060 μg mL?1. The developed derivative procedure, using the zero‐crossing technique, has been successfully applied for the analysis of Co(II) and Ni(II) simultaneously in different alloy samples. 相似文献
119.
Ueng SH Brahmi MM Derat E Fensterbank L Lacôte E Malacria M Curran DP 《Journal of the American Chemical Society》2008,130(31):10082-10083
Calculations suggest that complexes of borane with N-heterocyclic carbenes (NHC) have B-H bond dissocation energies more then 20 kcal/mol less than free borane, diborane, borane-THF, and related complexes. Values are in the range of popular radical hydrogen atom donors like tin hydrides (70-80 kcal/mol). The resulting prediction that NHC borane complexes could be used as radical hydrogen atom donors was verified by radical deoxygenations of xanthates by using either AIBN or triethylborane as initiator. 相似文献
120.
Yb3+-doped monoclinic yttrium polyphosphate Y(PO3)3 powder compounds were synthesized and were characterized by X-ray diffraction, IR absorption spectroscopy and Raman scattering spectroscopy.An attempt to use Yb3+ ion as structural probe is carried out to investigate the site occupation. Yb3+ emission and fluorescence decay studies were carried out both at low and room temperatures. The interpretation of electronic energy level positions has been done by using the comparison of emission spectra with those of vibronic sideband energy positions from Raman scattering spectroscopy.The spectroscopic results are discussed and correlated with the data of the already known monoclinic structure of Y(PO3)3 where four slightly different octahedral sites are available for the trivalent rare earth ion. 相似文献