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51.
Dr. Goutam Kumar Kole Dr. Abdul Malik Puthan Peedikakkal Belinda Mei Fang Toh Prof. Dr. Jagadese J. Vittal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(12):3962-3968
An attempt has been made to design double‐stranded ladder‐like coordination polymers (CPs) of hemidirected PbII. Four CPs, [Pb(μ‐bpe)(O2C‐C6H5)2] ? 2H2O ( 1 ), [Pb2(μ‐bpe)2(μ‐O2C‐C6H5)2(O2C‐C6H5)2] ( 2 ), [Pb2(μ‐bpe)2(μ‐O2C‐p‐Tol)2(O2C‐p‐Tol)2] ? 1.5 H2O ( 3 ) and [Pb2(μ‐bpe)2(μ‐O2C‐m‐Tol)2(O2C‐m‐Tol)2] ( 4 ) (bpe=1,2‐bis(4′‐pyridyl)ethylene), have been synthesised and investigated for their solid‐state photoreactivity. CPs 2 – 4 , having a parallel orientation of bpe molecules in their ladder structures and being bridged by carboxylates, were found to be photoreactive, whereas CP 1 is a linear one‐dimensional (1D) CP with guest water molecules aggregating to form a hydrogen‐bonded 1D structure. The linear strands of 1 were found to pair up upon eliminating lattice water molecules by heating, which led to the solid‐state structural transformation of photostable linear 1D CP 1 into photoreactive ladder CP 2 . In the construction of the double‐stranded ladder‐like structures, the parallel alignment of C?C bonds in 2 – 4 is dictated by the chelating and μ2‐η2:η1 bridging modes of the benzoate and toluate ligands. The role of solvents in the formation of such double‐stranded ladder‐like structures has also been investigated. A single‐crystal‐to‐single‐crystal transformation occurred when 4 was irradiated under UV light to form [Pb2(rctt‐tpcb)(μ‐O2C‐m‐Tol)2(O2C‐m‐Tol)2] ( 5 ). 相似文献
52.
Malik Abdul Rub Dileep Kumar Naved Azum Farah Khan Abdullah M. Asiri 《Journal of solution chemistry》2014,43(5):930-949
In the present paper, the micellization of an amphiphilic drug, promazine hydrochloride, and gemini surfactants (16-s-16) with s = 4–6 and the monomeric hexadecyltrimethylammonium bromide (CTAB) counterparts has been examined conductometrically in the pure and mixed states in aqueous solutions at different compositions and temperatures (298.15–308.15 K). Dicationic gemini surfactants provide much better environment for the micellization behavior than the corresponding monocationic counterpart CTAB. The critical micelle concentration (cmc) values are lower than the cmc for ideal mixing, cmc id, suggesting attractive interactions between the two components in mixed micelles. The micellar mole fractions of surfactants, evaluated by different models, show greater contributions of surfactants in mixed micelles and increase with increasing concentrations of these surfactants. The negative values of β suggest synergism in the mixtures, which is highly beneficial as it reduces the total amount of surfactants required in a particular application, leading to reductions of cost and environmental impact. Activity coefficients (f 1 and f 2) are always less than unity showing nonideality in the systems. The data have been also used for evaluation of thermodynamic parameters. 相似文献
53.
Muhammad Imran Malik Tooba Mahboob Shakil Ahmed 《Analytical and bioanalytical chemistry》2014,406(25):6311-6317
Poly(2-vinylpyridine)s (P2VPs) are important polymers with extensive applications in modern day material science. P2VP is an exceptional case for liquid chromatography because of certain polar interactions with most of the stationary phases. In the present study, we established the critical adsorption point (CAP) of P2VP for the first time. The effectiveness of the method is demonstrated by analyses of blends and block copolymers of P2VP and PMMA. The CAP of PMMA is established for determination of molar mass of P2VP component of above mentioned blends and block copolymers. The methods successfully demonstrate the separation of both types of homopolymers from the rest of the samples in conjunction with the determination of molar mass distribution of noncritical block or component. Graphical Abstract
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54.
Ullah Malik Zaka Muhammad Taseer Mallawi Fouad 《Journal of Thermal Analysis and Calorimetry》2021,143(3):2411-2418
Journal of Thermal Analysis and Calorimetry - This paper provides a theoretical study of 3D nanofluid flow with zero nanoparticles mass and constant heat fluxes conditions. An incompressible... 相似文献
55.
Darolia Poonam Jangra Malik Sunita Sharma Dimple Kumar Manish Garg Sapana Sharma V. K. 《Journal of solution chemistry》2021,50(11-12):1391-1431
Journal of Solution Chemistry - Excess molar volumes, $$V_{{}}^{{\text{E}}}$$ , excess isentropic compressibilities, $$\kappa_{{\text{S}}}^{{\text{E}}}$$ of binary 1-butyl-2,3-dimethylimidazolium... 相似文献
56.
57.
Naved Azum Malik Abdul Rub Abdullah M. Asiri Mohd. Akram 《Russian Journal of Physical Chemistry B, Focus on Physics》2015,9(6):940-945
Aggregation behavior of cationic gemini (hexanediyl-1,5-bis(dimethylcettylammonium bromide) (16-5-16)) surfactant with conventional single chain surfactants cetyltrimethylammonium bromide (CTAB) and tetradecyltrimethylammonium bromide (TTAB) were studied with the help of fluorescence measurements. Fluorescence probe is a proficient technique for examining the surfactant-surfactant interaction and aggregation. The micelle aggregation number (N agg) was measured using steady-state fluorescence quenching method. The micelle aggregation numbers of binary combinations fall between those of constituent surfactants. The micropolarity (I 1/I 3), binding constant (K sv) and dielectric constant (D exp) of mixed systems were determined from the ratio of peaks intensity in the pyrene fluorescence spectrum. The I 1/I 3 values were found to be more than >1, showing more polar environment around pyrene in the mixed micelle as compared to the pure micelles. 相似文献
58.
Inside Back Cover: In Situ Synthesis of Self‐Assembled Gold Nanoparticles on Glass or Silicon Substrates through Reactive Inkjet Printing (Angew. Chem. Int. Ed. 2/2014) 下载免费PDF全文
59.
Shielded sliding discharges are nanosecond streamer discharges which develop along a dielectric between metal foil electrodes, with one of the foils extended over the entire rear of the dielectric layer. The electrode configuration not only allowed rearranging discharges in parallel due to the decoupling effect of the metal layer, but also to modify the electric field distribution in such a way that components normal to the surface are enhanced, leading to an increased energy density in the discharge plasma. By varying the electrode gap, the applied voltage, and the repetition rate, it is shown that by keeping the average electric field constant, the discharge voltage can be reduced from tens of kV to values on the order of a few kV, but only at the expense of a reduced energy density of the plasma. Varying the repetition rate from 20 to 500 Hz resulted in a slightly reduced energy per pulse, likely caused by residual charges on the dielectric surface. Measurements of the NO conversion to NO2 and ozone synthesis in dry air showed that the conversion is only dependent on the energy density of the discharge plasma. Although reducing the pulse voltage from the tens of kV range to that of few kV, and possibly even lower, causes a reduction in energy density, this loss can be compensated for by increasing the electrode gap area. This and the possibility to form discharge arrays allows generating large volume discharge reactors for environmental applications, at modest pulsed voltages. 相似文献
60.
Syed Sheik Mansoor Krishnamoorthy Aswin Kuppan Logaiya Prasanna Nithiya Sudhan Saleem Malik 《Research on Chemical Intermediates》2014,40(2):871-885
A convenient approach to the synthesis of 2-amino-4,6-diphenylnicotinonitriles via four-component reaction of aromatic aldehydes, acetophenone derivatives, malononitrile and ammonium acetate is described. The reactions were done in water as solvent using cellulose sulfuric acid as catalyst. This simple protocol offer advantages such as shorter reaction times, simple work-up procedure, excellent yields and catalyst recovery. 相似文献