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排序方式: 共有357条查询结果,搜索用时 15 毫秒
91.
This paper demonstrates the special potential of vibrational NIR FT Raman microspectroscopy for the study of fennel fruits, chamomile inflorescence and curcuma roots to obtain detailed information about their microstructure and chemical composition. Microscopic Raman maps of fennel fruits demonstrate that anethole, which is the main essential oil component, is present in the whole mericarp with highest concentration at the top of the fruit. In situ measurements obtained of the essential oil cells are dominated by two bands observed at 1657 cm(-1) and 1609 cm(-1) which are characteristic for anethole. Raman images of chamomile inflorescence show that spiroethers, identified by significant bands between 2150 and 2250 cm(-1), are accumulated in the middle part of the flower head. Due to the intense curcumin bands in the Raman spectrum of curcuma root, the distribution of this dyeing substance can be clearly determined; highest concentration of curcumin was observed on the core of the root. 相似文献
92.
Molecular simulations for simple fluids in narrow slit-shaped carbon pores exhibit crystal-hexatic and hexatic-liquid transitions that are consistent with Kosterlitz-Thouless-Halperin-Nelson-Young theory. The temperature range over which the hexatic phase is stable is dramatically widened under confinement. Remarkably, the transitions, which are continuous for a single adsorbed layer, become weakly first order when the pore can accommodate two molecular layers. Nonlinear dielectric effect measurements for CCl4 and aniline in activated carbon fibers (pore width 1.4 nm) show divergence at these transitions, confirming the hexatic phase. 相似文献
93.
E. Baydaş Ó. Söğüt E. Büyükkasap Y. Şahin 《Journal of Radioanalytical and Nuclear Chemistry》2001,247(3):487-489
L X-ray intensity ratios of Ba, La, Ce, Gd, Er, Yb, Ta, Au, Hg, Pb, Bi have been measured. The L shell elctrons are excited by 59.5 keV gamma-rays from 241 Am and the L X-rays from samples are measured with a Si(Li) detector. The experimental values are compared with the theoretical values of the pure elements. 相似文献
94.
Sebastian Reitzenstein Petra Rsch Marion A. Strehle Dorothea Berg Malgorzata Baranska Hartwig Schulz Eicke Rudloff Jürgen Popp 《Journal of Raman spectroscopy : JRS》2007,38(3):301-308
The value of different vegetable oils can be correlated with the content of polyunsaturated fatty acids, especially omega‐3‐fatty acids such as linolenic acid, because of their contribution to healthy nutrition. One expression for the degree of unsaturation is the iodine value normally measured with gas chromatography. The use of Raman spectroscopy allows a rapid calculation of the iodine value and, in addition, only in a minimal sample volume. Therefore, this method can be used in single rapeseeds in order to predict the iodine value before harvesting. Additionally, the method can also be used for breeding investigations. Here, the lipid content and composition of a plant can be predicted by measuring the seedling without destruction. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
95.
In the literature, most known sequence transformations can be written as a ratio of two determinants. But, it is not always this case. One exception is that the sequence transformation proposed by Brezinski, Durbin, and Redivo-Zaglia cannot be expressed as a ratio of two determinants. Motivated by this, we will introduce a new algebraic tool—pfaffians, instead of determinants in the paper. It turns out that Brezinski–Durbin–Redivo-Zaglia’s transformation can be expressed as a ratio of two pfaffians. To the best of our knowledge, this is the first time to introduce pfaffians in the expressions of sequence transformations. Furthermore, an extended transformation of high order is presented in terms of pfaffians and a new convergence acceleration algorithm for implementing the transformation is constructed. Then, the Lax pair of the recursive algorithm is obtained which implies that the algorithm is integrable. Numerical examples with applications of the algorithm are also presented. 相似文献
96.
97.
Malgorzata Geszke-Moritz Gilles Clavier Janina Lulek Raphaël Schneider 《Journal of luminescence》2012,132(4):987-991
3-Mercaptopropionic acid-capped core/shell ZnS:Cu/ZnS and ZnS:Mn/ZnS doped quantum dots (QDs) prepared through hydrothermal methods exhibit high photoluminescence intensity as well as good photostability. These water-dispersible nanoparticles exhibit high fluorescence sensitivity to folic acid due to the high affinity of the carboxylate groups and nitrogen atoms of folic acid towards the Zn surface atoms of the doped dots. Quenching of the fluorescence intensity of the QDs allows the detection of folic acid concentrations as low as 11 μM, thus affording a very sensitive system for the sensing of this biologically active molecule in aqueous solution. The possible quenching mechanism is discussed. 相似文献
98.
99.
Biodegradable polycarbonates containing side carboxyl groups—synthesis,properties, and degradation study
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Joanna Jaworska Michal Kawalec Malgorzata Pastusiak Katarzyna Reczynska Henryk Janeczek Kamila Lewicka Elzbieta Pamula Piotr Dobrzynski 《Journal of polymer science. Part A, Polymer chemistry》2017,55(17):2756-2769
The main objective of the presented research was to synthesise biodegradable aliphatic polycarbonates containing reactive carboxyl pendant groups and to examine the influence of the copolymer chain microstructure and composition on the process of their hydrolytic degradation and cytocompatibility. The work describes copolymerization of cyclic trimethylene carbonate derivative containing benzyl‐ester pendant group (benzyl 5‐methyl‐2‐oxo‐1,3‐dioxane‐5‐carboxylate) with trimethylene carbonate. The copolymerization was conducted with the use of zinc (II) and lanthanum (III) acetylacetonates as ring‐opening polymerization coordination initiators. Detailed NMR analysis allowed to define the microstructure of the obtained copolymers, which depended on the composition and type of used initiator. The final tapered chain microstructure of the obtained copolymers was related to huge differences in comonomers reactivity and evidenced low level of transesterification of the main copolymer backbone. Chosen copolymers, with unprotected carbonyl groups, were subjected to in vitro degradation test and cytocompatibility studies. It was found that high concentration of carboxyl groups resulted in copolymers which formed hydrogels and were very prone to hydrolytic degradation; they were also cytotoxic toward osteoblast‐like MG 63 cells. Copolymers with lower content of carboxyl groups were found less susceptible to degradation and cytocompatible with studied cells. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2756–2769 相似文献
100.
Raman imaging is shown to be a highly selective and sensitive method of studying in situ and in vivo astaxanthin distribution, concentration and molecular structure in the cyst form of the unicellular microalgae Haematococcus pluvialis. 相似文献